SUPPORTING INFORMATION

Transcription

1 1 SUPPORTING INFORMATION Thermodynamic Properties of trans-1 Chloro 3,3,3 trifluoropropene (R1233zd(E)): Vapor Pressure, (p, ρ, T) Behavior, and Speed of Sound Measurements, and Equation of State 1 María E. Mondéjar 2, Mark O. McLinden 3, and Eric W. Lemmon Applied Chemicals and Materials Division, National Institute of Standards and Technology 325 Broadway, Mailstop , Boulder, Colorado USA Extended Tables of Experimental Data Presented in this Supplemental Information are complete tabulations of all of the measured data and additional details on experimental uncertainties and conditions. The tables are presented in tab-delimited ASCII text format to facilitate import into spreadsheets or data analysis programs. The quantities tabulated are defined below. Table S1. Experimental vapor pressure data for R1233zd(E). Table S2. Experimental (p, ρ, T) data for R1233zd(E). Table S3. Experimental speed of sound data for R1233zd(E). 1 Contribution of the National Institute of Standards and Technology. Not subject to copyright in the United States. 2 Present address: Dpto. Ingenieria Energetica y Fluidomecanica, Universidad de Valladolid, Paseo del Cauce, 59, E Valladolid, Spain 3 Corresponding author; markm@boulder.nist.gov; tel: ; fax:

2 2 Table S1. Experimental vapor pressure data for R1233zd(E). Nomenclature for table: T p temperature T/K pressure p/mpa (p p_eos) relative deviation between experimental vapor pressure and value calculated with the present equation of state: ( ) p sat,eos 100 p sat,exp p sat,eos sigma_t sigma_p u(t) u(p_tran) u(p_head) u(p) U_c standard deviation in the 8 temperature readings taken over the course of a single vapor pressure determination; this is a measure of the steadiness of the experimental conditions standard deviation in the 8 pressure readings taken over the course of a single vapor pressure determination standard (k = 1) uncertainty in temperature standard uncertainty in pressure due to the pressure transducer standard uncertainty in pressure due to the hydrostatic head correction combined standard uncertainty in pressure, including transducer and hydrostatic head effects relative, combined, expanded (k = 2), uncertainty in vapor pressure: (p- p_eos) U_c p_trans U C ( p sat ) = 2 u 2 p transducer ( ) + σ ( p) p + g( ρ max ρ min )u( h) + sat T u( T ) ratio of (deviation between experimental vapor pressure and value calculated with the present equation of state) to the combined expanded uncertainty pressure transducer used: 2 = mid-range 6.9 MPa full scale 3 = low-range 2.8 MPa full scale 1 2 date time in format: yyyy mm dd hh:mm 2

3 3 Table S2. Experimental (p-ρ-t) data for R1233zd(E). Nomenclature for table: T p temperature T/K pressure p/mpa rho density ρ/kg m 3 (D D_EOS) relative deviation in density with present EOS: 100 ρ ρ EOS ρ EOS a p following the value indicates a deviation in pressure (applicable for states in the extended critical region): 100 p p EOS p EOS sigma_t sigma_p sigma_rho u(t) u(p_tran) u(p_head) uc(p) u(rho) U_c standard deviation in the 9 temperature readings taken over the course of a single density determination; this is a measure of the steadiness of the experimental conditions standard deviation in the 9 pressure readings taken over the course of a single density determination standard deviation in the weighings comprising a single density determination converted to their equivalent effect on density standard (k = 1) uncertainty in temperature standard uncertainty in pressure due to the pressure transducer standard uncertainty in pressure due to the hydrostatic head correction combined standard uncertainty in pressure, including transducer and hydrostatic head effects standard uncertainty in density expanded, combined uncertainty as defined by: U C 2 ρ ( ρ) = 2 u( ρ) + p T ( ) u p ρ + T p ( ) u T (D D_EOS)/U_c ratio of the deviation from the EOS to the experimental uncertainty: ρ ρ EOS ρ or u C ( ) p p EOS p u C ( ) p_trans pressure transducer used: 1 = high-range 41.4 MPa full scale 2 = mid-range 6.89 MPa full scale 3 = low-range 1.38 MPa full scale date time in format: yyyy mm dd hh:mm 3

4 4 Table S3. Experimental speed of sound data for R1233zd(E). Nomenclature for table: year mo dy time T(K) p(kpa) f(hz) w(m/s) mode date in format: yyyy mm dd time in format: hh:mm temperature T/K pressure p/kpa, including hydrostatic head correction frequency (Hz) of the resonance peak, including boundary layer, shell resonance, and dispersion corrections speed of sound w/m s 1, including boundary layer, shell resonance, and dispersion corrections resonance mode; + indicates scan over increasing frequencies, indicates scan over decreasing frequencies Uc(k=2) combined, expanded (k = 2) uncertainty in speed of sound w/m s 1 for each resonance mode Uc_avg combined, expanded (k = 2) uncertainty in speed of sound w/m s 1 for the average taken over the different resonance modes Uc/% relative combined, expanded (k = 2) uncertainty in speed of sound for the average taken over the different resonance modes (expressed as a percentage) s_modes standard deviation of the mean of the speed of sound w/m s 1 for the different resonance modes sigma_t u(t) standard deviation in the temperature readings (K) taken before, during, and after a given radial mode; this is a measure of the steadiness of the experimental conditions standard (k = 1) uncertainty in temperature (K), including effect of temperature gradients in the cell u(w_t) standard uncertainty in sound speed w/m s 1 resulting from temperature uncertainties (i.e., state point uncertainty) p_trans sigma_p p_head u(p) pressure transducer used: 1 = high-range 41 MPa full scale 2 = mid-range 6.2 MPa full scale 3 = low-range 0.7 MPa full scale standard deviation in the pressure readings (kpa) taken before, during, and after a given radial mode; this is a measure of the steadiness of the experimental conditions hydrostatic head correction for p/kpa; the pressure transducers are located 0.46 m above the center of the resonator sphere standard uncertainty in pressure p/kpa, including effects of pressure transducer calibration and stability and uncertainty in hydrostatic head correction 4

5 5 u(w_p) standard uncertainty in sound speed w/m s 1 resulting from pressure uncertainties (i.e., state point uncertainty) BW half-power bandwidth (Hz) of the resonance peak u(w_bw) standard uncertainty in sound speed w/m s 1 resulting from the bandwidth df_bl frequency correction (Hz) for the resonance peak due to thermal and viscous boundary layer u(w_bl) standard uncertainty in sound speed w/m s 1 resulting from the boundary layer correction df_sh frequency correction (Hz) for the resonance peak due to resonance of the spherical shell u(w_sh) standard uncertainty in sound speed w/m s 1 resulting from the resonance of the spherical shell D(T,p) u(d0) u(d[t]) u(d[p]) u(d[t]) calculated sphere diameter D/mm, including temperature and pressure effects standard uncertainty in sphere diameter D/mm at zero pressure and reference temperature of 300 K standard uncertainty in sphere diameter D/mm resulting from temperature difference from reference temperature of 300 K standard uncertainty in sphere diameter D/mm resulting from pressure standard uncertainty in sphere diameter D/mm due to long-term mechanical stability u(w_d) standard uncertainty in sound speed w/m s 1 resulting from uncertainties in the sphere diameter; includes D0, temperature, pressure, and time effects u(w_x) standard uncertainty in sound speed w/m s 1 resulting from impurities in the fluid sample tau df_disp vibrational relaxation time τ/ns of the molecule frequency correction (Hz) for the resonance peak due to dispersion effects u(w_bw) standard uncertainty in sound speed w/m s 1 resulting from dispersion effects 5

6 Table S1. Experimental vapor pressure data for R1233zd(E). component: R1233zd(E) mole frac: molar mass: Uncertainty factors [all for standard (k = 1) errors]: state point: standard uncertainty in T/K: zero offset in p/kpa (p_high): relative uncertainty in p/ppm (p_high): 26.0 zero offset in p/kpa (p_med): relative uncertainty in p/ppm (p_med): 20.0 zero offset in p/kpa (p_low): relative uncertainty in p/ppm (p_low): 20.0 hydrostatic head, uncertainty in L/V height (m): 0.050! T! p! (p - p_eos)!sigma_t! sigma_p! u(t)! u(p_tran)! u(p_head)! u(p)! U_c/%! (p - p_eos)!p_trans!year!mo!dy!time (K) (MPa) (%) (K) (kpa) (K) (kpa) (kpa) (k=2) U_c # filling 1 (main vapor pressure test)! ! ! ! ! ! ! ! ! ! 1.969! 0.469! 3!2012!06!14!17:43! ! ! ! ! ! ! ! ! ! 1.969! 0.469! 3!2012!06!14!17:53! ! ! ! ! ! ! ! ! ! 1.969! 0.468! 3!2012!06!14!18:02! ! ! ! ! ! ! ! ! ! 1.969! 0.466! 3!2012!06!14!18:11! ! ! ! ! ! ! ! ! ! 1.969! 0.467! 3!2012!06!14!18:20! ! ! ! ! ! ! ! ! ! 1.303! 0.359! 3!2012!06!14!22:51! ! ! ! ! ! ! ! ! ! 1.303! 0.357! 3!2012!06!14!23:00! ! ! ! ! ! ! ! ! ! 1.303! 0.356! 3!2012!06!14!23:09! ! ! ! ! ! ! ! ! ! 1.303! 0.356! 3!2012!06!14!23:18! ! ! ! ! ! ! ! ! ! 1.303! 0.355! 3!2012!06!14!23:27! ! ! ! ! ! ! ! ! ! 1.303! 0.355! 3!2012!06!14!23:36! ! ! ! ! ! ! ! ! ! 0.887! 0.285! 3!2012!06!15!17:00! ! ! ! ! ! ! ! ! ! 0.886! 0.272! 3!2012!06!15!17:09! ! ! ! ! ! ! ! ! ! 0.886! 0.274! 3!2012!06!15!17:18! ! ! ! ! ! ! ! ! ! 0.886! 0.282! 3!2012!06!15!17:27! ! ! ! ! ! ! ! ! ! 0.886! 0.281! 3!2012!06!15!17:36! ! ! ! ! ! ! ! ! ! 0.886! 0.277! 3!2012!06!15!17:45! ! ! ! ! ! ! ! ! ! 0.652! 0.044! 3!2012!06!15!23:19! ! ! ! ! ! ! ! ! ! 0.761! 0.131! 3!2012!06!15!23:28! ! ! ! ! ! ! ! ! ! 0.733! 0.091! 3!2012!06!15!23:37! ! ! ! ! ! ! ! ! ! 0.631! ! 3!2012!06!15!23:55! ! ! ! ! ! ! ! ! ! 0.672! 0.102! 3!2012!06!16!00:04! ! ! ! ! ! ! ! ! ! 0.030! 0.670! 3!2012!06!16!05:38! ! ! ! ! ! ! ! ! ! 0.030! 0.699! 3!2012!06!16!05:48! ! ! ! ! ! ! ! ! ! 0.030! 0.751! 3!2012!06!16!05:57! ! ! ! ! ! ! ! ! ! 0.030! 0.769! 3!2012!06!16!06:06! ! ! ! ! ! ! ! ! ! 0.028! ! 3!2012!06!16!11:03! ! ! ! ! ! ! ! ! ! 0.027! ! 3!2012!06!16!11:20! ! ! ! ! ! ! ! ! ! 0.028! ! 3!2012!06!16!11:30! ! ! ! ! ! ! ! ! ! 0.028! ! 3!2012!06!16!11:39! ! ! ! ! ! ! ! ! ! 0.026! ! 3!2012!06!16!19:36! ! ! ! ! ! ! ! ! ! 0.026! ! 3!2012!06!16!19:55! ! ! ! ! ! ! ! ! ! 0.026! ! 3!2012!06!16!20:05! ! ! ! ! ! ! ! ! ! 0.026! ! 3!2012!06!16!20:14! ! ! ! ! ! ! ! ! ! 0.026! ! 3!2012!06!16!20:23! ! ! ! ! ! ! ! ! ! 0.025! ! 3!2012!06!17!00:48! ! ! ! ! ! ! ! ! ! 0.025! ! 3!2012!06!17!00:57! ! ! ! ! ! ! ! ! ! 0.025! ! 3!2012!06!17!01:06! ! ! ! ! ! ! ! ! ! 0.025! ! 3!2012!06!17!01:15! ! ! ! ! ! ! ! ! ! 0.025! ! 3!2012!06!17!01:36! ! ! ! ! ! ! ! ! ! 0.025! ! 3!2012!06!17!01:45! ! ! ! ! ! ! ! ! ! 0.024! ! 3!2012!06!17!06:09! ! ! ! ! ! ! ! ! ! 0.024! ! 3!2012!06!17!06:19! ! ! ! ! ! ! ! ! ! 0.024! ! 3!2012!06!17!06:53! ! ! ! ! ! ! ! ! ! 0.024! ! 3!2012!06!17!07:02! ! ! ! ! ! ! ! ! ! 0.024! ! 3!2012!06!17!07:34! ! ! ! ! ! ! ! ! ! 0.023! 0.033! 3!2012!06!17!11:54! ! ! ! ! ! ! ! ! ! 0.023! ! 3!2012!06!17!12:03! ! ! ! ! ! ! ! ! ! 0.023! ! 3!2012!06!17!12:12! ! ! ! ! ! ! ! ! ! 0.023! ! 3!2012!06!17!12:21! ! ! ! ! ! ! ! ! ! 0.023! ! 3!2012!06!17!12:30! ! ! ! ! ! ! ! ! ! 0.023! 0.001! 3!2012!06!17!12:42! ! ! ! ! ! ! ! ! ! 0.022! 0.796! 3!2012!06!17!17:07! ! ! ! ! ! ! ! ! ! 0.022! 0.795! 3!2012!06!17!17:16! ! ! ! ! ! ! ! ! ! 0.022! 0.777! 3!2012!06!17!17:25! ! ! ! ! ! ! ! ! ! 0.022! 0.755! 3!2012!06!17!17:34! ! ! ! ! ! ! ! ! ! 0.022! 0.711! 3!2012!06!17!17:43! ! ! ! ! ! ! ! ! ! 0.022! 0.696! 3!2012!06!17!17:52! ! ! ! ! ! ! ! ! ! 0.029! ! 2!2012!06!17!22:18! ! ! ! ! ! ! ! ! ! 0.029! ! 2!2012!06!17!22:27! ! ! ! ! ! ! ! ! ! 0.029! ! 2!2012!06!17!22:36! ! ! ! ! ! ! ! ! ! 0.029! ! 2!2012!06!17!22:45! ! ! ! ! ! ! ! ! ! 0.029! ! 2!2012!06!17!22:54! ! ! ! ! ! ! ! ! ! 0.026! ! 2!2012!06!18!02:35! ! ! ! ! ! ! ! ! ! 0.026! ! 2!2012!06!18!02:48! ! ! ! ! ! ! ! ! ! 0.026! ! 2!2012!06!18!02:57! ! ! ! ! ! ! ! ! ! 0.026! ! 2!2012!06!18!03:06! ! ! ! ! ! ! ! ! ! 0.026! ! 2!2012!06!18!03:15! ! ! ! ! ! ! ! ! ! 0.024! ! 2!2012!06!18!07:21! ! ! ! ! ! ! ! ! ! 0.024! ! 2!2012!06!18!07:31! ! ! ! ! ! ! ! ! ! 0.024! ! 2!2012!06!18!08:03! ! ! ! ! ! ! ! ! ! 0.024! ! 2!2012!06!18!08:12! ! ! ! ! ! ! ! ! ! 0.024! ! 2!2012!06!18!08:21! ! ! ! ! ! ! ! ! ! 0.023! ! 2!2012!06!18!12:42! ! ! ! ! ! ! ! ! ! 0.023! ! 2!2012!06!18!13:15! ! ! ! ! ! ! ! ! ! 0.023! ! 2!2012!06!18!13:24! ! ! ! ! ! ! ! ! ! 0.023! ! 2!2012!06!18!13:33

7 ! ! ! ! ! ! ! ! ! ! 0.023! ! 2!2012!06!18!13:56! ! ! ! ! ! ! ! ! ! 0.023! ! 2!2012!06!18!14:05! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!18!18:33! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!18!18:58! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!18!19:07! ! ! ! ! ! ! ! ! ! 0.023! ! 2!2012!06!18!19:16! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!18!19:25! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!18!19:42! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!00:01! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!00:10! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!00:21! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!00:30! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!00:39! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!04:41! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!04:50! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!05:10! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!05:20! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!09:14! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!09:24! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!09:43! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!06!19!09:52! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!13:42! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!13:51! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!14:00! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!14:09! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!14:18! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!14:27! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!18:08! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!18:27! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!18:37! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!18:47! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!21:42! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!21:51! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!22:00! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!22:09! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!22:18! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!10!22:27! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!11!01:54! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!11!02:04! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!11!02:13! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!11!02:22! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!11!02:31! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!11!02:40 # filling 1 (replicates following main vapor pressure test)! ! ! ! ! ! ! ! ! ! 0.639! ! 2!2012!07!12!17:35! ! ! ! ! ! ! ! ! ! 0.639! ! 2!2012!07!12!17:44! ! ! ! ! ! ! ! ! ! 0.639! ! 2!2012!07!12!17:53! ! ! ! ! ! ! ! ! ! 0.639! ! 2!2012!07!12!18:02! ! ! ! ! ! ! ! ! ! 0.639! ! 2!2012!07!12!18:11! ! ! ! ! ! ! ! ! ! 0.639! ! 2!2012!07!12!18:20! ! ! ! ! ! ! ! ! ! 0.134! ! 2!2012!07!12!23:17! ! ! ! ! ! ! ! ! ! 0.136! ! 2!2012!07!12!23:26! ! ! ! ! ! ! ! ! ! 0.134! ! 2!2012!07!12!23:35! ! ! ! ! ! ! ! ! ! 0.134! ! 2!2012!07!12!23:44! ! ! ! ! ! ! ! ! ! 0.134! ! 2!2012!07!12!23:53! ! ! ! ! ! ! ! ! ! 0.115! ! 2!2012!07!13!04:58! ! ! ! ! ! ! ! ! ! 0.115! ! 2!2012!07!13!05:07! ! ! ! ! ! ! ! ! ! 0.115! ! 2!2012!07!13!05:16! ! ! ! ! ! ! ! ! ! 0.115! ! 2!2012!07!13!05:25! ! ! ! ! ! ! ! ! ! 0.115! ! 2!2012!07!13!05:34! ! ! ! ! ! ! ! ! ! 0.115! ! 2!2012!07!13!05:43! ! ! ! ! ! ! ! ! ! 0.029! ! 2!2012!07!13!23:45! ! ! ! ! ! ! ! ! ! 0.029! ! 2!2012!07!14!00:16! ! ! ! ! ! ! ! ! ! 0.029! ! 2!2012!07!14!00:25! ! ! ! ! ! ! ! ! ! 0.029! ! 2!2012!07!14!00:34! ! ! ! ! ! ! ! ! ! 0.029! ! 2!2012!07!14!01:02! ! ! ! ! ! ! ! ! ! 0.029! ! 2!2012!07!14!01:11! ! ! ! ! ! ! ! ! ! 0.024! ! 2!2012!07!14!05:58! ! ! ! ! ! ! ! ! ! 0.024! ! 2!2012!07!14!06:07! ! ! ! ! ! ! ! ! ! 0.024! ! 2!2012!07!14!06:16! ! ! ! ! ! ! ! ! ! 0.024! ! 2!2012!07!14!06:29! ! ! ! ! ! ! ! ! ! 0.024! ! 2!2012!07!14!06:38! ! ! ! ! ! ! ! ! ! 0.024! ! 2!2012!07!14!06:47! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!11:35! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!11:44! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!11:58! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!12:07! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!12:16! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!12:25! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!16:00! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!16:16! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!16:25! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!16:34! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!16:43! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!16:52! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!19:48! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!19:57! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!20:07! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!20:17! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!23:40! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!23:49! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!14!23:58! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!15!00:07! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!15!00:16! ! ! ! ! ! ! ! ! ! 0.022! ! 2!2012!07!15!00:25

8 # filling 2 (sample used for liquid-phase density measurements)! ! ! ! ! ! ! ! ! ! 0.558! 0.770! 1!2012!08!08!15:34! ! ! ! ! ! ! ! ! ! 0.559! 0.785! 1!2012!08!08!15:43! ! ! ! ! ! ! ! ! ! 0.561! 0.770! 1!2012!08!08!15:52! ! ! ! ! ! ! ! ! ! 0.558! 0.756! 1!2012!08!08!16:01! ! ! ! ! ! ! ! ! ! 0.559! 0.770! 1!2012!08!08!16:10! ! ! ! ! ! ! ! ! ! 0.559! 0.757! 1!2012!08!08!16:19! ! ! ! ! ! ! ! ! ! 0.426! 0.741! 1!2012!08!08!21:34! ! ! ! ! ! ! ! ! ! 0.426! 0.749! 1!2012!08!08!21:43! ! ! ! ! ! ! ! ! ! 0.427! 0.772! 1!2012!08!08!21:52! ! ! ! ! ! ! ! ! ! 0.426! 0.733! 1!2012!08!08!22:01! ! ! ! ! ! ! ! ! ! 0.427! 0.762! 1!2012!08!08!22:10! ! ! ! ! ! ! ! ! ! 0.426! 0.744! 1!2012!08!08!22:19! ! ! ! ! ! ! ! ! ! 0.331! 0.731! 1!2012!08!09!03:28! ! ! ! ! ! ! ! ! ! 0.330! 0.752! 1!2012!08!09!03:48! ! ! ! ! ! ! ! ! ! 0.329! 0.789! 1!2012!08!09!03:57! ! ! ! ! ! ! ! ! ! 0.330! 0.743! 1!2012!08!09!04:06! ! ! ! ! ! ! ! ! ! 0.330! 0.721! 1!2012!08!09!04:15! ! ! ! ! ! ! ! ! ! 0.260! 0.732! 1!2012!08!09!09:38! ! ! ! ! ! ! ! ! ! 0.259! 0.769! 1!2012!08!09!09:47! ! ! ! ! ! ! ! ! ! 0.259! 0.773! 1!2012!08!09!09:56! ! ! ! ! ! ! ! ! ! 0.260! 0.745! 1!2012!08!09!10:05! ! ! ! ! ! ! ! ! ! 0.260! 0.748! 1!2012!08!09!10:14 # filling 3 (sample used for vapor-phase density measurements)! ! ! ! ! ! ! ! ! ! 0.890! ! 3!2012!09!12!13:56! ! ! ! ! ! ! ! ! ! 0.890! ! 3!2012!09!12!14:05! ! ! ! ! ! ! ! ! ! 0.890! ! 3!2012!09!12!14:14! ! ! ! ! ! ! ! ! ! 0.890! ! 3!2012!09!12!14:23! ! ! ! ! ! ! ! ! ! 0.889! ! 3!2012!09!12!14:32! ! ! ! ! ! ! ! ! ! 0.890! ! 3!2012!09!12!14:41! ! ! ! ! ! ! ! ! ! 0.753! ! 3!2012!09!12!19:46! ! ! ! ! ! ! ! ! ! 0.765! ! 3!2012!09!12!19:55! ! ! ! ! ! ! ! ! ! 1.074! 0.073! 3!2012!09!12!20:04! ! ! ! ! ! ! ! ! ! 0.877! ! 3!2012!09!12!20:13! ! ! ! ! ! ! ! ! ! 0.759! ! 3!2012!09!12!20:22! ! ! ! ! ! ! ! ! ! 1.115! ! 3!2012!09!12!20:31! ! ! ! ! ! ! ! ! ! 0.931! 0.029! 3!2012!09!13!01:26! ! ! ! ! ! ! ! ! ! 0.809! ! 3!2012!09!13!01:36! ! ! ! ! ! ! ! ! ! 0.840! 0.165! 3!2012!09!13!01:45! ! ! ! ! ! ! ! ! ! 0.656! ! 3!2012!09!13!01:54! ! ! ! ! ! ! ! ! ! 1.237! 0.141! 3!2012!09!13!02:03 # filling 4 (sample used for liquid-phase and supercritical density measurements)! ! ! ! ! ! ! ! ! ! 0.095! ! 1!2012!09!25!17:14! ! ! ! ! ! ! ! ! ! 0.095! ! 1!2012!09!25!17:23! ! ! ! ! ! ! ! ! ! 0.095! ! 1!2012!09!25!17:32! ! ! ! ! ! ! ! ! ! 0.095! ! 1!2012!09!25!17:42! ! ! ! ! ! ! ! ! ! 0.095! ! 1!2012!09!25!17:51! ! ! ! ! ! ! ! ! ! 0.095! ! 1!2012!09!25!18:00! ! ! ! ! ! ! ! ! ! 0.080! ! 1!2012!09!25!22:13! ! ! ! ! ! ! ! ! ! 0.080! ! 1!2012!09!25!22:22! ! ! ! ! ! ! ! ! ! 0.080! ! 1!2012!09!25!22:32! ! ! ! ! ! ! ! ! ! 0.080! ! 1!2012!09!25!22:42

9 Table S2. Experimental (p, rho, T) data for R1233zd(E). component: R1233zd(E) mole frac: molar mass: Uncertainty factors [all for standard (k = 1) errors]: state point: standard uncertainty in T/K: zero offset in p/kpa (p_high): relative uncertainty in p/ppm (p_high): 26.0 zero offset in p/kpa (p_med): relative uncertainty in p/ppm (p_med): 20.0 zero offset in p/kpa (p_low): relative uncertainty in p/ppm (p_low): 20.0 hydrostatic head, uncertainty in L/V height (m): sinker volume u(v_sinker)/ppm at Tref 28.0 u(v_sinker)_temperature coeff [ppm/k] u(v_sinker)_pressure coeff [ppm/mpa] density [except for V_sinker] u_rho/[kg/m^3] ! T! p! rho! (D - D_EOS)!p!sigma_T! sigma_p! sigma_rho! u(t)! u(p_tran)!u(p_head)! uc(p)! u(rho)! U_c/%! (D - D_EOS)!p_trans!year!mo!dy!time (K) (MPa) (kg.m-3) (%)? (K) (kpa) (kg.m-3) (K) (kpa) (kpa) (kpa) (kg.m-3) (k=2) U_c # filling 2, compressed-liquid densities! ! ! ! !! ! ! ! ! 1.001! 0.108! 1.865! ! ! ! 1!2012!07!19!21:13! ! ! ! !! ! ! ! ! 1.001! 0.108! 1.395! ! ! ! 1!2012!07!19!21:25! ! ! ! !! ! ! ! ! 1.001! 0.108! 1.196! ! ! ! 1!2012!07!19!21:37! ! ! ! !! ! ! ! ! 1.001! 0.108! 1.948! ! ! ! 1!2012!07!19!21:49! ! ! ! !! ! ! ! ! 1.001! 0.108! 1.555! ! ! ! 1!2012!07!19!22:13! ! ! ! !! ! ! ! ! 1.023! 0.097! 1.184! ! ! 0.243! 1!2012!07!20!11:28! ! ! ! !! ! ! ! ! 1.023! 0.097! 1.376! ! ! 0.254! 1!2012!07!20!11:40! ! ! ! !! ! ! ! ! 1.023! 0.097! 1.206! ! ! 0.262! 1!2012!07!20!11:52! ! ! ! !! ! ! ! ! 1.001! 0.103! 1.365! ! ! 0.074! 1!2012!07!20!15:52! ! ! ! !! ! ! ! ! 1.001! 0.103! 1.179! ! ! 0.084! 1!2012!07!20!16:04! ! ! ! !! ! ! ! ! 1.001! 0.103! 1.402! ! ! 0.074! 1!2012!07!20!16:16! ! ! ! !! ! ! ! ! 1.001! 0.103! 1.472! ! ! 0.117! 1!2012!07!20!16:28! ! ! ! !! ! ! ! ! 1.023! 0.092! 1.544! ! ! 0.231! 1!2012!07!20!21:22! ! ! ! !! ! ! ! ! 1.023! 0.092! 1.331! ! ! 0.226! 1!2012!07!20!21:34! ! ! ! !! ! ! ! ! 1.023! 0.092! 1.577! ! ! 0.256! 1!2012!07!20!21:46! ! ! ! !! ! ! ! ! 1.069! 0.083! 1.231! ! ! 0.306! 1!2012!07!21!13:08! ! ! ! !! ! ! ! ! 1.069! 0.083! 1.549! ! ! 0.297! 1!2012!07!21!13:20! ! ! ! !! ! ! ! ! 1.069! 0.083! 1.235! ! ! 0.302! 1!2012!07!21!13:32! ! ! ! !! ! ! ! ! 1.069! 0.083! 1.602! ! ! 0.300! 1!2012!07!21!13:44! ! ! ! !! ! ! ! ! 1.137! 0.075! 1.292! ! ! 0.293! 1!2012!07!21!19:13! ! ! ! !! ! ! ! ! 1.137! 0.075! 1.332! ! ! 0.323! 1!2012!07!21!19:25! ! ! ! !! ! ! ! ! 1.137! 0.075! 1.250! ! ! 0.333! 1!2012!07!21!19:37! ! ! ! !! ! ! ! ! 1.137! 0.075! 1.373! ! ! 0.312! 1!2012!07!21!19:49! ! ! ! !! ! ! ! ! 1.075! 0.078! 1.278! ! ! 0.260! 1!2012!07!21!22:08! ! ! ! !! ! ! ! ! 1.075! 0.078! 1.145! ! ! 0.288! 1!2012!07!21!22:20! ! ! ! !! ! ! ! ! 1.075! 0.078! 1.364! ! ! 0.306! 1!2012!07!21!22:32! ! ! ! !! ! ! ! ! 1.075! 0.078! 1.322! ! ! 0.269! 1!2012!07!21!22:44! ! ! ! !! ! ! ! ! 1.034! 0.081! 1.335! ! ! 0.193! 1!2012!07!22!01:03! ! ! ! !! ! ! ! ! 1.034! 0.081! 1.106! ! ! 0.176! 1!2012!07!22!01:16! ! ! ! !! ! ! ! ! 1.009! 0.085! 1.099! ! ! 0.092! 1!2012!07!22!03:37! ! ! ! !! ! ! ! ! 1.009! 0.085! 1.187! ! ! 0.079! 1!2012!07!22!03:49! ! ! ! !! ! ! ! ! 1.009! 0.085! 1.118! ! ! 0.087! 1!2012!07!22!04:01! ! ! ! !! ! ! ! ! 1.009! 0.085! 1.300! ! ! 0.101! 1!2012!07!22!04:13! ! ! ! !! ! ! ! ! 1.001! 0.088! 1.416! ! ! ! 1!2012!07!22!06:32! ! ! ! !! ! ! ! ! 1.001! 0.088! 1.144! ! ! ! 1!2012!07!22!06:44! ! ! ! !! ! ! ! ! 1.001! 0.088! 1.117! ! ! ! 1!2012!07!22!06:56! ! ! ! !! ! ! ! ! 1.001! 0.088! 1.191! ! ! 0.004! 1!2012!07!22!07:08! ! ! ! !! ! ! ! ! 1.017! 0.078! 1.111! ! ! 0.053! 1!2012!07!22!20:12! ! ! ! !! ! ! ! ! 1.017! 0.078! 1.666! ! ! 0.162! 1!2012!07!22!20:24! ! ! ! !! ! ! ! ! 1.017! 0.078! 1.359! ! ! 0.071! 1!2012!07!22!20:36! ! ! ! !! ! ! ! ! 1.017! 0.078! 1.107! ! ! 0.091! 1!2012!07!22!20:48

10 ! ! ! ! !! ! ! ! ! 1.054! 0.069! 1.469! ! ! 0.112! 1!2012!07!23!11:56! ! ! ! !! ! ! ! ! 1.054! 0.069! 1.267! ! ! 0.122! 1!2012!07!23!12:08! ! ! ! !! ! ! ! ! 1.054! 0.069! 1.287! ! ! 0.136! 1!2012!07!23!12:20! ! ! ! !! ! ! ! ! 1.054! 0.069! 1.894! ! ! 0.053! 1!2012!07!23!12:32! ! ! ! !! ! ! ! ! 1.109! 0.062! 1.314! ! ! 0.089! 1!2012!07!23!17:12! ! ! ! !! ! ! ! ! 1.109! 0.062! 1.177! ! ! 0.100! 1!2012!07!23!17:24! ! ! ! !! ! ! ! ! 1.109! 0.062! 1.770! ! ! 0.106! 1!2012!07!23!17:36! ! ! ! !! ! ! ! ! 1.109! 0.062! 1.498! ! ! 0.108! 1!2012!07!23!17:48! ! ! ! !! ! ! ! ! 1.180! 0.055! 1.517! ! ! 0.082! 1!2012!07!23!21:54! ! ! ! !! ! ! ! ! 1.180! 0.055! 1.326! ! ! 0.053! 1!2012!07!23!22:10! ! ! ! !! ! ! ! ! 1.141! 0.056! 1.334! ! ! 0.035! 1!2012!07!24!14:58! ! ! ! !! ! ! ! ! 1.141! 0.056! 1.507! ! ! 0.040! 1!2012!07!24!15:10! ! ! ! !! ! ! ! ! 1.141! 0.056! 1.783! ! ! 0.039! 1!2012!07!24!15:22! ! ! ! !! ! ! ! ! 1.141! 0.056! 1.381! ! ! 0.055! 1!2012!07!24!15:34! ! ! ! !! ! ! ! ! 1.077! 0.058! 1.227! ! ! 0.031! 1!2012!07!24!18:00! ! ! ! !! ! ! ! ! 1.077! 0.058! 1.545! ! ! 0.005! 1!2012!07!24!18:12! ! ! ! !! ! ! ! ! 1.077! 0.058! 1.769! ! ! 0.035! 1!2012!07!24!18:24! ! ! ! !! ! ! ! ! 1.077! 0.058! 1.645! ! ! 0.033! 1!2012!07!24!18:36! ! ! ! !! ! ! ! ! 1.036! 0.061! 1.319! ! ! ! 1!2012!07!24!20:56! ! ! ! !! ! ! ! ! 1.036! 0.061! 1.715! ! ! ! 1!2012!07!24!21:08! ! ! ! !! ! ! ! ! 1.036! 0.061! 1.107! ! ! ! 1!2012!07!24!21:20! ! ! ! !! ! ! ! ! 1.036! 0.061! 1.371! ! ! ! 1!2012!07!24!21:32! ! ! ! !! ! ! ! ! 1.009! 0.064! 1.593! ! ! ! 1!2012!07!24!23:53! ! ! ! !! ! ! ! ! 1.009! 0.064! 1.160! ! ! ! 1!2012!07!25!00:06! ! ! ! !! ! ! ! ! 1.009! 0.064! 1.226! ! ! ! 1!2012!07!25!00:18! ! ! ! !! ! ! ! ! 1.009! 0.064! 1.187! ! ! ! 1!2012!07!25!00:30! ! ! ! !! ! ! ! ! 1.000! 0.067! 1.429! ! ! ! 1!2012!07!25!02:51! ! ! ! !! ! ! ! ! 1.000! 0.067! 1.290! ! ! ! 1!2012!07!25!03:04! ! ! ! !! ! ! ! ! 1.013! 0.058! 1.363! ! ! ! 1!2012!07!25!11:30! ! ! ! !! ! ! ! ! 1.013! 0.058! 1.252! ! ! ! 1!2012!07!25!13:17! ! ! ! !! ! ! ! ! 1.013! 0.058! 1.282! ! ! ! 1!2012!07!25!13:29! ! ! ! !! ! ! ! ! 1.013! 0.058! 1.291! ! ! ! 1!2012!07!25!13:41! ! ! ! !! ! ! ! ! 1.013! 0.058! 1.312! ! ! ! 1!2012!07!25!13:53! ! ! ! !! ! ! ! ! 1.041! 0.051! 2.142! ! ! ! 1!2012!07!25!18:16! ! ! ! !! ! ! ! ! 1.041! 0.051! 1.237! ! ! ! 1!2012!07!25!18:28! ! ! ! !! ! ! ! ! 1.041! 0.051! 1.394! ! ! ! 1!2012!07!25!18:40! ! ! ! !! ! ! ! ! 1.041! 0.051! 1.187! ! ! ! 1!2012!07!25!18:52! ! ! ! !! ! ! ! ! 1.084! 0.044! 1.214! ! ! ! 1!2012!07!26!00:49! ! ! ! !! ! ! ! ! 1.084! 0.044! 1.207! ! ! ! 1!2012!07!26!01:01! ! ! ! !! ! ! ! ! 1.084! 0.044! 1.139! ! ! ! 1!2012!07!26!01:13! ! ! ! !! ! ! ! ! 1.140! 0.037! 1.191! ! ! ! 1!2012!07!26!13:49! ! ! ! !! ! ! ! ! 1.140! 0.037! 1.769! ! ! ! 1!2012!07!26!14:01! ! ! ! !! ! ! ! ! 1.140! 0.037! 1.372! ! ! ! 1!2012!07!26!14:13! ! ! ! !! ! ! ! ! 1.140! 0.037! 1.326! ! ! ! 1!2012!07!26!14:25! ! ! ! !! ! ! ! ! 1.074! 0.039! 1.139! ! ! ! 1!2012!07!26!16:49! ! ! ! !! ! ! ! ! 1.074! 0.039! 1.210! ! ! ! 1!2012!07!26!17:01! ! ! ! !! ! ! ! ! 1.074! 0.039! 1.145! ! ! ! 1!2012!07!26!17:13! ! ! ! !! ! ! ! ! 1.074! 0.039! 1.241! ! ! ! 1!2012!07!26!17:25! ! ! ! !! ! ! ! ! 1.034! 0.041! 1.180! ! ! ! 1!2012!07!26!19:49! ! ! ! !! ! ! ! ! 1.034! 0.041! 1.141! ! ! ! 1!2012!07!26!20:01! ! ! ! !! ! ! ! ! 1.034! 0.041! 1.165! ! ! ! 1!2012!07!26!20:13! ! ! ! !! ! ! ! ! 1.034! 0.041! 1.310! ! ! ! 1!2012!07!26!20:25! ! ! ! !! ! ! ! ! 1.008! 0.043! 1.170! ! ! ! 1!2012!07!26!22:54! ! ! ! !! ! ! ! ! 1.008! 0.043! 1.157! ! ! ! 1!2012!07!26!23:06! ! ! ! !! ! ! ! ! 1.008! 0.043! 1.149! ! ! ! 1!2012!07!26!23:18! ! ! ! !! ! ! ! ! 1.008! 0.043! 1.230! ! ! ! 1!2012!07!26!23:30! ! ! ! !! ! ! ! ! 1.001! 0.046! 1.237! ! ! ! 1!2012!07!27!01:52! ! ! ! !! ! ! ! ! 1.001! 0.046! 1.120! ! ! ! 1!2012!07!27!02:04! ! ! ! !! ! ! ! ! 1.001! 0.046! 1.107! ! ! ! 1!2012!07!27!02:16! ! ! ! !! ! ! ! ! 1.001! 0.046! 1.187! ! ! ! 1!2012!07!27!02:28! ! ! ! !! ! ! ! ! 1.011! 0.038! 1.147! ! ! ! 1!2012!07!27!10:59! ! ! ! !! ! ! ! ! 1.011! 0.038! 1.133! ! ! ! 1!2012!07!27!11:11! ! ! ! !! ! ! ! ! 1.011! 0.038! 1.063! ! ! ! 1!2012!07!27!11:23! ! ! ! !! ! ! ! ! 1.011! 0.038! 1.244! ! ! ! 1!2012!07!27!11:35! ! ! ! !! ! ! ! ! 1.033! 0.031! 1.218! ! ! ! 1!2012!07!27!15:26! ! ! ! !! ! ! ! ! 1.033! 0.031! 1.152! ! ! ! 1!2012!07!27!15:38! ! ! ! !! ! ! ! ! 1.033! 0.031! 1.199! ! ! ! 1!2012!07!27!15:51! ! ! ! !! ! ! ! ! 1.067! 0.025! 1.324! ! ! ! 1!2012!07!27!19:54! ! ! ! !! ! ! ! ! 1.067! 0.025! 1.305! ! ! ! 1!2012!07!27!20:13

11 ! ! ! ! !! ! ! ! ! 1.067! 0.025! 1.136! ! ! ! 1!2012!07!27!20:25! ! ! ! !! ! ! ! ! 1.067! 0.025! 1.329! ! ! ! 1!2012!07!27!20:37! ! ! ! !! ! ! ! ! 1.111! 0.019! 1.459! ! ! ! 1!2012!07!28!00:29! ! ! ! !! ! ! ! ! 1.111! 0.019! 1.329! ! ! ! 1!2012!07!28!00:41! ! ! ! !! ! ! ! ! 1.111! 0.019! 1.238! ! ! ! 1!2012!07!28!00:53! ! ! ! !! ! ! ! ! 1.111! 0.019! 1.350! ! ! ! 1!2012!07!28!01:05! ! ! ! !! ! ! ! ! 1.070! 0.020! 1.167! ! ! ! 1!2012!07!28!03:27! ! ! ! !! ! ! ! ! 1.071! 0.020! 1.187! ! ! ! 1!2012!07!28!03:39! ! ! ! !! ! ! ! ! 1.071! 0.020! 1.202! ! ! ! 1!2012!07!28!03:51! ! ! ! !! ! ! ! ! 1.071! 0.020! 1.172! ! ! ! 1!2012!07!28!04:03! ! ! ! !! ! ! ! ! 1.033! 0.021! 1.248! ! ! ! 1!2012!07!28!06:29! ! ! ! !! ! ! ! ! 1.033! 0.021! 1.213! ! ! ! 1!2012!07!28!06:41! ! ! ! !! ! ! ! ! 1.033! 0.021! 1.232! ! ! ! 1!2012!07!28!06:53! ! ! ! !! ! ! ! ! 1.033! 0.021! 1.169! ! ! ! 1!2012!07!28!07:05! ! ! ! !! ! ! ! ! 1.009! 0.022! 1.240! ! ! ! 1!2012!07!28!09:32! ! ! ! !! ! ! ! ! 1.009! 0.022! 1.037! ! ! ! 1!2012!07!28!09:44! ! ! ! !! ! ! ! ! 1.009! 0.022! 1.297! ! ! ! 1!2012!07!28!09:56! ! ! ! !! ! ! ! ! 1.009! 0.022! 1.158! ! ! ! 1!2012!07!28!10:08! ! ! ! !! ! ! ! ! 1.000! 0.023! 1.089! ! ! ! 1!2012!07!28!12:35! ! ! ! !! ! ! ! ! 1.000! 0.023! 1.201! ! ! ! 1!2012!07!28!12:48! ! ! ! !! ! ! ! ! 1.000! 0.023! 1.203! ! ! ! 1!2012!07!28!13:00! ! ! ! !! ! ! ! ! 1.000! 0.023! 1.083! ! ! ! 1!2012!07!28!13:12! ! ! ! !! ! ! ! ! 1.008! 0.016! 1.060! ! ! ! 1!2012!07!29!16:20! ! ! ! !! ! ! ! ! 1.008! 0.016! 1.091! ! ! ! 1!2012!07!29!16:32! ! ! ! !! ! ! ! ! 1.008! 0.016! 1.081! ! ! ! 1!2012!07!29!16:44! ! ! ! !! ! ! ! ! 1.008! 0.016! 1.121! ! ! ! 1!2012!07!29!16:56! ! ! ! !! ! ! ! ! 1.025! 0.010! 1.087! ! ! ! 1!2012!07!29!21:47! ! ! ! !! ! ! ! ! 1.025! 0.010! 1.154! ! ! ! 1!2012!07!29!21:59! ! ! ! !! ! ! ! ! 1.025! 0.010! 1.047! ! ! ! 1!2012!07!29!22:11! ! ! ! !! ! ! ! ! 1.025! 0.010! 1.066! ! ! ! 1!2012!07!29!22:23! ! ! ! !! ! ! ! ! 1.051! 0.004! 1.094! ! ! ! 1!2012!07!30!03:09! ! ! ! !! ! ! ! ! 1.051! 0.004! 1.114! ! ! ! 1!2012!07!30!03:22! ! ! ! !! ! ! ! ! 1.085! 0.002! 1.135! ! ! ! 1!2012!07!30!08:06! ! ! ! !! ! ! ! ! 1.085! 0.002! 1.642! ! ! ! 1!2012!07!30!08:24! ! ! ! !! ! ! ! ! 1.085! 0.002! 1.107! ! ! ! 1!2012!07!30!08:36! ! ! ! !! ! ! ! ! 1.085! 0.002! 1.130! ! ! ! 1!2012!07!30!08:48! ! ! ! !! ! ! ! ! 1.047! 0.002! 1.227! ! ! ! 1!2012!07!30!11:14! ! ! ! !! ! ! ! ! 1.047! 0.002! 1.159! ! ! ! 1!2012!07!30!11:27! ! ! ! !! ! ! ! ! 1.047! 0.002! 1.125! ! ! ! 1!2012!07!30!11:39! ! ! ! !! ! ! ! ! 1.047! 0.002! 1.100! ! ! ! 1!2012!07!30!11:51! ! ! ! !! ! ! ! ! 1.022! 0.002! 1.090! ! ! ! 1!2012!07!30!21:40! ! ! ! !! ! ! ! ! 1.022! 0.002! 1.224! ! ! 0.009! 1!2012!07!30!21:52! ! ! ! !! ! ! ! ! 1.022! 0.002! 1.133! ! ! ! 1!2012!07!30!22:04! ! ! ! !! ! ! ! ! 1.022! 0.002! 1.062! ! ! 0.010! 1!2012!07!30!22:24! ! ! ! !! ! ! ! ! 1.006! 0.002! 1.034! ! ! 0.048! 1!2012!07!31!00:50! ! ! ! !! ! ! ! ! 1.006! 0.002! 1.069! ! ! 0.037! 1!2012!07!31!01:03! ! ! ! !! ! ! ! ! 1.006! 0.002! 1.040! ! ! 0.058! 1!2012!07!31!01:15! ! ! ! !! ! ! ! ! 1.000! 0.002! 1.135! ! ! 0.081! 1!2012!07!31!03:40! ! ! ! !! ! ! ! ! 1.000! 0.002! 1.031! ! ! 0.075! 1!2012!07!31!03:53! ! ! ! !! ! ! ! ! 1.000! 0.002! 1.017! ! ! 0.087! 1!2012!07!31!04:05! ! ! ! !! ! ! ! ! 1.007! 0.008! 1.023! ! ! 0.128! 1!2012!07!31!08:51! ! ! ! !! ! ! ! ! 1.007! 0.008! 1.387! ! ! 0.097! 1!2012!07!31!09:03! ! ! ! !! ! ! ! ! 1.007! 0.008! 1.112! ! ! 0.115! 1!2012!07!31!09:15! ! ! ! !! ! ! ! ! 1.007! 0.008! 1.043! ! ! 0.123! 1!2012!07!31!09:27! ! ! ! !! ! ! ! ! 1.020! 0.013! 1.090! ! ! 0.147! 1!2012!07!31!14:15! ! ! ! !! ! ! ! ! 1.020! 0.013! 1.081! ! ! 0.135! 1!2012!07!31!14:27! ! ! ! !! ! ! ! ! 1.020! 0.013! 1.055! ! ! 0.133! 1!2012!07!31!14:39! ! ! ! !! ! ! ! ! 1.020! 0.013! 1.053! ! ! 0.157! 1!2012!07!31!14:51! ! ! ! !! ! ! ! ! 1.039! 0.018! 1.074! ! ! 0.172! 1!2012!07!31!19:45! ! ! ! !! ! ! ! ! 1.039! 0.018! 1.188! ! ! 0.151! 1!2012!07!31!19:57! ! ! ! !! ! ! ! ! 1.039! 0.018! 1.166! ! ! 0.172! 1!2012!07!31!20:09! ! ! ! !! ! ! ! ! 1.039! 0.018! 1.133! ! ! 0.175! 1!2012!07!31!20:36! ! ! ! !! ! ! ! ! 1.065! 0.023! 1.153! ! ! 0.198! 1!2012!08!01!01:41! ! ! ! !! ! ! ! ! 1.065! 0.023! 1.234! ! ! 0.232! 1!2012!08!01!01:53! ! ! ! !! ! ! ! ! 1.065! 0.023! 1.096! ! ! 0.234! 1!2012!08!01!02:05! ! ! ! !! ! ! ! ! 1.065! 0.023! 1.133! ! ! 0.226! 1!2012!08!01!02:28! ! ! ! !! ! ! ! ! 1.047! 0.024! 1.204! ! ! 0.241! 1!2012!08!01!04:56! ! ! ! !! ! ! ! ! 1.047! 0.024! 1.082! ! ! 0.226! 1!2012!08!01!05:20! ! ! ! !! ! ! ! ! 1.047! 0.024! 1.157! ! ! 0.216! 1!2012!08!01!05:32