*Level IV report narratives are more detailed than other levels.

Transcription

1 Reporting Packages Brooks Applied Labs recognizes that report packages and electronic data deliverables (EDD) should be easy to read, reference, understand, and evaluate while containing all necessary information to convey scientifically accurate and precise measurements that are legally defensible and useful for regulatory, litigation, or research purposes. Our company utilizes a customized environmental laboratory information management system (LIMS) that tracks each sample from the moment it is received, through preparation, analysis, and disposal. Our analytical instrumentation is integrated with this system, providing us with powerful data evaluation capabilities and the capacity to rapidly produce highly accurate report packages and EDDs per our clients requirements. All of this equates to error free reporting which gives our clients maximum confidence in BAL s final product. We routinely produce report packages according to three levels of increasing detail (see table) depending on the specific requirements of a project, in addition to compiling entirely custom reports when necessary. All of our reports are certified NELAP compliant and our Level IV report is considered to be litigation level and CLP-like since it contains all of the required material for EPA CLP reporting. All levels of reporting include a cover letter or narrative that summarizes any relevant analytical issues that may have been encountered. Additionally, our Level IV report includes an exhaustive narrative describing the methods used and calculations performed, detailing any analytical or instrumental issues associated with the reported data. Deliverables Level II Level III Level IV Narrative* X X X Information X X X Results X X X Accuracy & Precision Summary X X X Method Blanks & Reporting Limits X X X Containers Summary X X X Shipping Containers Summary X X X Chain-of-Custody Forms X X X Waybill or Shipping Label X X X Instrument Calibration Results X X Full Sequence Information X Preparation & Bench Sheets X Instrument Printouts X *Level IV report narratives are more detailed than other levels. We also routinely produce EDDs in accordance to the specifications required by many environmental consulting firms and state/ federal regulatory agencies. Client-specific custom EDDs can also be designed to accommodate nearly any specifications. If you have any questions about our reporting capabilities please contact us today! For more information, please call or visit our website at

2 Report of Water & Sediment Analyses Trace Metals & Mercury Project: example report s Collected: July 22, 2016 Report Date: August 16, 2016 Prepared for: example report Project ID: EXA-MP1601

3 Table of Contents Case Narrative... 3 Report Information... 5 Information... 6 Batch Summary... 7 Results... 9 Accuracy & Precision Summary Method Blanks & Reporting Limits Instrument Calibration Containers Shipping Containers Chain(s) of Custody Waybill(s) Percent Total Solids Batch B Mercury Sequence Trace Metals Sequence Trace Metals Sequence

4 Case Narrative Shipping and Receiving On July 22, 2016, Brooks Applied Labs (BAL) received four water samples and one sediment sample at 9:00 AM in a cardboard box at an ambient temperature. The Chain of Custody requested mercury and various other trace metals analyses of the samples. The samples were received and stored according to BAL standard operating procedures (SOP) and EPA methodology. Preservation and Holding Time All method requirements for preservation and holding time were satisfied. Percent Total Solids by SM 2540G (BR-1501) A solid sample is homogenized and an aliquot is measured into a pre-weighed vessel, dried in an oven overnight, weighed again, and the percent of dried solid material is calculated. The results may have been evaluated using reporting limits that have been adjusted to account for sample aliquot size. Please refer to the Results page for sample-specific MDLs, MRLs, and other details. Batch B Any non-conformance, corrective actions, or the reasons for which the results of an analysis would require qualification would be explained in detail in this section. Hardness by SM 2340B (BR-1502) s are closed-vessel oven digested with nitric acid. Digests are then analyzed by Inductively Coupled Plasma - Mass Spectrometry (ICP-MS) for Calcium and Magnesium. Hardness is then calculated based on Ca and Mg concentrations. The results may have been evaluated using reporting limits that have been adjusted to account for sample aliquot size. Please refer to the Results page for sample-specific MDLs, MRLs, and other details. Sequence Any non-conformance, corrective actions, or the reasons for which the results of an analysis would require qualification would be explained in detail in this section. Total Mercury by EPA Method 1631 (BR-0006) All samples are prepared and analyzed in accordance with EPA Method s are oxidized with bromine monochloride (BrCl) and then analyzed with stannous chloride (SnCl 2 ) reduction, single gold amalgamation, and cold vapor atomic fluorescence spectroscopy (CVAFS) detection using a BAL Model III CVAFS Mercury Analyzer. The results were method blank corrected as described in the calculations section of the relevant BAL SOP(s) and may have been evaluated using reporting limits that have been adjusted to account for sample aliquot size. Please refer to the Results page for sample-specific MDLs, MRLs, and other details.

5 Sequence Any non-conformance, corrective actions, or the reasons for which the results of an analysis would require qualification would be explained in detail in this section. Trace Metals by EPA Method 1638, mod (BR-0060) Prepared samples are analyzed by inductively coupled plasma mass spectrometry (ICP-MS) according to a modification of EPA Draft Method Briefly, this method incorporates ionization of the sample in an inductively coupled RF plasma, with detection of the resulting ions by mass spectrometer on the basis of their mass-to-charge ratio. Digestates are diluted with reagent water prior to analysis, depending upon the element and concentration ranges to be determined. s are analyzed on a Perkin Elmer DRC II (in standard mode), and internal standardization in standard mode is accomplished using 6 Li 45 Sc, 74 Ge, 115 In, 169 Tm. The results were method blank corrected as described in the calculations section of the relevant BAL SOP(s) and may have been evaluated using reporting limits that have been adjusted to account for sample aliquot size. Please refer to the Results page for sample-specific MDLs, MRLs, and other details. Sequence Any non-conformance, corrective actions, or the reasons for which the results of an analysis would require qualification would be explained in detail in this section. Sequence Any non-conformance, corrective actions, or the reasons for which the results of an analysis would require qualification would be explained in detail in this section. We certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. BAL, an accredited laboratory, certifies that the reported results of all analyses for which BAL is NELAP accredited meet all NELAP requirements. For more details, please see the Report Information page in your report. Please feel free to contact us if you have any questions regarding this report. BAL PROJECT MANAGER Project Manager pm@brooksapplied.com BAL PROJECT COORDINATOR Project Coordinator pc@brooksapplied.com

6 Client Client Project: example Report Information Laboratory Accreditation BAL is accredited by the National Environmental Laboratory Accreditation Program (NELAP) through the State of Florida Department of Health, Bureau of Laboratories (E87982) and is certified to perform many environmental analyses. BAL is also certified by many other states to perform environmental analyses. For a current list of our accreditations/certifications, please visit our website at < Results reported relate only to the samples listed in the report. Field Quality Control s Please be notified that certain EPA methods require the collection of field quality control samples of an appropriate type and frequency; failure to do so is considered a deviation from some methods and for compliance purposes should only be done with the approval of regulatory authorities. Please see the specific EPA methods for details regarding required field quality control samples. AR BAL BLK BS CAL CCB CCV COC D DUP IBL ICV MDL MRL as received Brooks Applied Labs method blank blank spike calibration standard continuing calibration blank continuing calibration verification chain of custody record dissolved fraction duplicate instrument blank initial calibration verification method detection limit method reporting limit Common Abbreviations MS MSD ND NR N/C PS REC RPD SCV SOP SRM T TR matrix spike matrix spike duplicate non-detect non-reportable not calculated post preparation spike percent recovery relative percent difference secondary calibration verification standard operating procedure standard reference material total fraction total recoverable fraction Definition of Data Qualifiers (Effective 9/23/09) J Detected by the instrument, the result is > the MDL but the MRL. Result is reported and considered an estimate. E An estimated value due to the presence of interferences. A full explanation is presented in the narrative. H Holding time and/or preservation requirements not met. Result is estimated. J-1 Estimated value. A full explanation is presented in the narrative. J-M Duplicate precision (RPD) for associated QC sample was not within acceptance criteria. Result is estimated. J-N Spike recovery for associated QC sample was not within acceptance criteria. Result is estimated. M Duplicate precision (RPD) was not within acceptance criteria. Result is estimated. N Spike recovery was not within acceptance criteria. Result is estimated. R Rejected, unusable value. A full explanation is presented in the narrative. U Result is the MDL or client requested reporting limit (CRRL). Result reported as the MDL or CRRL. X Result is not BLK-corrected and is within 10x the absolute value of the highest detectable BLK in the batch. Result is estimated. These qualifiers are based on those previously utilized by Brooks Applied Labs, those found in the EPA SOW ILM03.0, Exhibit B, Section III, pg. B-18, and the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic Superfund Data Review; USEPA; January These supersede all previous qualifiers ever employed by BAL.

7 Client Information Tin & Titanium Hardness Low Level Hg (WP-174) Trace Metals Trace Metals in Soil Report Matrix Type Water QC Water QC Water QC Water QC Soil/Sediment QC d Received 07/19/ /22/ /19/ /22/ /19/ /22/ /19/ /22/ /19/ /22/2016

8 Client Batch Summary Analyte Lab Matrix Method %TS Soil/Sediment SM 2540G Al Soil/Sediment EPA Method 1638 mod. As Soil/Sediment EPA Method 1638 mod. B Soil/Sediment EPA Method 1638 mod. Ba Soil/Sediment EPA Method 1638 mod. Be Soil/Sediment EPA Method 1638 mod. Ca Soil/Sediment EPA Method 1638 mod. Cd Soil/Sediment EPA Method 1638 mod. Co Soil/Sediment EPA Method 1638 mod. Cr Soil/Sediment EPA Method 1638 mod. Cu Soil/Sediment EPA Method 1638 mod. Fe Soil/Sediment EPA Method 1638 mod. Hg Soil/Sediment EPA Method 1631, Appendix K Soil/Sediment EPA Method 1638 mod. Mg Soil/Sediment EPA Method 1638 mod. Mn Soil/Sediment EPA Method 1638 mod. Mo Soil/Sediment EPA Method 1638 mod. Na Soil/Sediment EPA Method 1638 mod. Ni Soil/Sediment EPA Method 1638 mod. Pb Soil/Sediment EPA Method 1638 mod. Se Soil/Sediment EPA Method 1638 mod. Sn Soil/Sediment EPA Method 1638 mod. Sr Soil/Sediment EPA Method 1638 mod. Ti Soil/Sediment EPA Method 1638 mod. Tl Soil/Sediment EPA Method 1638 mod. V Soil/Sediment EPA Method 1638 mod. Zn Soil/Sediment EPA Method 1638 mod. Ag Water EPA Method 1638 mod. Al Water EPA Method 1638 mod. As Water EPA Method 1638 mod. B Water EPA Method 1638 mod. Ba Water EPA Method 1638 mod. Be Water EPA Method 1638 mod. Cd Water EPA Method 1638 mod. Co Water EPA Method 1638 mod. Cr Water EPA Method 1638 mod. Cu Water EPA Method 1638 mod. Fe Water EPA Method 1638 mod. Hg Water EPA Method 1631 Mn Water EPA Method 1638 mod. Mo Water EPA Method 1638 mod. Prepared Analyzed Batch Sequence 07/29/ /31/2016 B N/A 09/02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /25/ /26/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /02/ /03/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /30/ /31/2016 B /20/ /24/2016 B /20/ /24/2016 B

9 Client Batch Summary Analyte Ni Pb Sb Se Sn Sr Ti Tl V Zn Lab Matrix Water Water Water Water Water Water Water Water Water Water Method EPA Method 1638 mod. EPA Method 1638 mod. EPA Method 1638 mod. EPA Method 1638 mod. EPA Method 1638 mod. EPA Method 1638 mod. EPA Method 1638 mod. EPA Method 1638 mod. EPA Method 1638 mod. EPA Method 1638 mod. Prepared Analyzed Batch Sequence 08/20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B /20/ /24/2016 B

10 Client Results Hardness Analyte Report Matrix Fraction Result Qualifier MDL MRL Unit Hardness Water T mg eq CaCO3/L Batch [CALC] Sequence Low Level Hg (WP-174) Hg Water T ng/l B Tin & Titanium Sn Water T Ti Water T Trace Metals Ag Water T Al Water T As Water T B Water T Ba Water T Be Water T Cd Water T Co Water T Cr Water T Cu Water T Fe Water T Mn Water T Mo Water T Ni Water T Pb Water T Sb Water T Se Water T Sr Water T Tl Water T V Water T Zn Water T N/A B B B B B B B B B B B B B B B B B B B B B B B

11 Client Results Analyte Report Matrix Fraction Result Qualifier MDL MRL Unit Batch Sequence Trace Metals in Soil %TS Soil/Sediment N/A % B N/A Al Soil/Sediment N/A dry B As Soil/Sediment N/A dry B B Soil/Sediment N/A dry B Ba Soil/Sediment N/A dry B Be Soil/Sediment N/A dry B Ca Soil/Sediment N/A dry B Cd Soil/Sediment N/A dry B Co Soil/Sediment N/A dry B Cr Soil/Sediment N/A dry B Cu Soil/Sediment N/A dry B Fe Soil/Sediment N/A dry B Hg Soil/Sediment N/A ng/g dry B K Soil/Sediment N/A dry B Mg Soil/Sediment N/A dry B Mn Soil/Sediment N/A dry B Mo Soil/Sediment N/A dry B Na Soil/Sediment N/A dry B Ni Soil/Sediment N/A dry B Pb Soil/Sediment N/A dry B Se Soil/Sediment N/A dry B Sn Soil/Sediment N/A dry B Sr Soil/Sediment N/A dry B Ti Soil/Sediment N/A dry B Tl Soil/Sediment N/A dry B V Soil/Sediment N/A dry B Zn Soil/Sediment N/A dry B

12 Client Accuracy & Precision Summary Batch: B Lab Matrix: Soil/Sediment Method: EPA Method 1631, Appendix Analyte Native Spike Result Units REC & Limits RPD & Limits B SRM1 Certified Reference Material ( , MESS-3) Hg ng/g 105% B SRM2 B SRM3 Certified Reference Material ( , MESS-3) Hg ng/g 105% Certified Reference Material ( , SOIL-61) Hg ng/g 119% B DUP1 Duplicate ( ) Hg ng/g dry 8% 30 B MSD1 Matrix Spike Duplicate ( ) Hg ng/g dry 107% % 30 B DUP2 Duplicate ( ) Hg ng/g dry 3% 30 B MSD2 Matrix Spike Duplicate ( ) Hg ng/g dry 108% % 30 B PS1 Post Spike ( ) Hg ng/g dry 114% B DUP3 Duplicate ( ) Hg ng/g dry 2% 30 B MSD3 Matrix Spike Duplicate ( ) Hg ng/g dry 107% % 30 B PS2 Post Spike ( ) Hg ng/g dry 116%

13 Client Accuracy & Precision Summary Batch: B Lab Matrix: Soil/Sediment Method: SM 2540G Analyte Native Spike Result Units REC & Limits RPD & Limits B DUP2 Duplicate ( ) %TS % 0.09% 15 B DUP3 Duplicate ( ) %TS % 1% 15 B DUP4 Duplicate ( ) %TS % 0.4% 15 B DUP1 Duplicate ( ) %TS % 0.2% 15

14 Client Accuracy & Precision Summary Batch: B Lab Matrix: Water Method: EPA Method 1631 Analyte Native Spike Result Units B SRM1 Certified Reference Material ( , NIST 1641d) Hg ng/l REC & Limits 105% RPD & Limits B MS2 Matrix Spike ( ) Hg ng/l 105% B MSD2 Matrix Spike Duplicate ( ) Hg ng/l 106% % 24 B MS3 Matrix Spike ( ) Hg ng/l 109% B MSD3 Matrix Spike Duplicate ( ) Hg ng/l 106% % 24 B MS4 Matrix Spike ( ) Hg ng/l 105% B MSD4 Matrix Spike Duplicate ( ) Hg ng/l 101% % 24 B MS1 Matrix Spike ( ) Hg ng/l 104% B MSD1 Matrix Spike Duplicate ( ) Hg ng/l 91% % 24 B DUP1 Duplicate ( ) Hg ng/l 9% 24 B MS5 Matrix Spike ( ) Hg ng/l 104% B MSD5 Matrix Spike Duplicate ( ) Hg ng/l 106% % 24

15 Client Accuracy & Precision Summary Batch: B Lab Matrix: Soil/Sediment B SRM1 Analyte Native Spike Result Units REC & Limits RPD & Limits Certified Reference Material ( , SOIL-65) Al % As % B % Ba % Be % Ca % Cd % Co % Cr % Cu % Fe % K % Mg % Mn % Mo % Na % Ni % Pb % Se % Sn % Sr % Ti % Tl % V % Zn %

16 Client Accuracy & Precision Summary Batch: B Lab Matrix: Soil/Sediment Analyte Native Spike Result Units REC & Limits RPD & Limits B DUP1 Duplicate ( ) Al dry 0.4% 30 As dry 3% 30 B dry 3% 30 Ba dry 4% 30 Be dry 1% 30 Ca dry 2% 30 Cd dry 3% 30 Co dry 3% 30 Cr dry 2% 30 Cu dry 1% 30 Fe dry 6% 30 K dry 4% 30 Mg dry 2% 30 Mn dry 4% 30 Mo dry 6% 30 Na dry 1% 30 Ni dry 4% 30 Pb dry 0.2% 30 Se dry 0.7% 30 Sn dry 8% 30 Sr dry 7% 30 Ti dry 9% 30 Tl dry 1% 30 V dry 3% 30 Zn dry 6% 30

17 Client Accuracy & Precision Summary Batch: B Lab Matrix: Soil/Sediment Analyte Native Spike Result Units REC & Limits RPD & Limits B DUP2 Duplicate ( ) Al dry 0.9% 30 As dry 2% 30 B dry 3% 30 Ba dry 2% 30 Be dry 2% 30 Ca dry 0.9% 30 Cd dry 5% 30 Co dry 6% 30 Cr dry 3% 30 Cu dry 0.4% 30 Fe dry 4% 30 K dry 5% 30 Mg dry 1% 30 Mn dry 0.02% 30 Mo dry 3% 30 Na dry 3% 30 Ni dry 5% 30 Pb dry 3% 30 Se dry 3% 30 Sn dry 4% 30 Sr dry 4% 30 Ti dry 1% 30 Tl dry 2% 30 V dry 4% 30 Zn dry 2% 30

18 Client Accuracy & Precision Summary Batch: B Lab Matrix: Soil/Sediment Method: EPA Method 1631, Appendix B SRM1 Analyte Native Spike Result Units REC & Limits Certified Reference Material ( , SOIL-65) Hg ng/g 105% RPD & Limits B DUP1 Duplicate ( ) Hg ng/g dry 4% 30 B MS1 Matrix Spike ( ) Hg ng/g dry 111% B MSD1 Matrix Spike Duplicate ( ) Hg ng/g dry 109% % 30

19 Client Accuracy & Precision Summary Batch: B Lab Matrix: Water Analyte Native Spike Result Units REC & Limits RPD & Limits B SRM1 Certified Reference Material ( , NIST 1643e) Ag % Al % As % B % Ba % Be % Cd % Co % Cr % Cu % Fe % Mn % Mo % Ni % Pb % Sb % Se % Sr % Tl % V % Zn %

20 Client Accuracy & Precision Summary Batch: B Lab Matrix: Water Analyte Native Spike Result Units REC & Limits RPD & Limits B DUP1 Duplicate ( ) Ag % 25 Al % 25 As % 25 B % 25 Ba % 25 Be % 25 Cd % 25 Co % 25 Cr % 25 Cu % 25 Fe % 25 Mn % 25 Mo % 25 Ni % 25 Pb % 25 Sb % 25 Se % 25 Sr % 25 Tl % 25 V % 25 Zn % 25

21 Client Accuracy & Precision Summary Batch: B Lab Matrix: Water B MS1 Analyte Native Spike Result Units REC & Limits RPD & Limits Matrix Spike ( ) Ag % Al % As % B % Ba % Be % Cd % Co % Cr % Cu % Fe % Mn % Mo % Ni % Pb % Sb % Se % Sr % Tl % V % Zn %

22 Client Accuracy & Precision Summary Batch: B Lab Matrix: Water Analyte Native Spike Result Units REC & Limits RPD & Limits B MSD1 Matrix Spike Duplicate ( ) Ag % % 25 Al % % 25 As % % 25 B % % 25 Ba % % 25 Be % % 25 Cd % % 25 Co % % 25 Cr % % 25 Cu % % 25 Fe % % 25 Mn % % 25 Mo % % 25 Ni % % 25 Pb % % 25 Sb % % 25 Se % % 25 Sr % % 25 Tl % % 25 V % % 25 Zn % % 25

23 Client Accuracy & Precision Summary Batch: B Lab Matrix: Water Analyte Native Spike Result Units REC & Limits RPD & Limits B DUP1 Duplicate ( ) Sn % 25 Ti % 25 B MS1 Matrix Spike ( ) Sn % Ti % B MSD1 Matrix Spike Duplicate ( ) Sn % % 25 Ti % % 25

24 Client Method Blanks & Reporting Limits Batch: B Matrix: Soil/Sediment Method: SM 2540G Analyte: %TS Result B BLK B BLK Average: 0.07 Limit: 0.33 Units % % MDL: 0.10 % MRL: 0.33 % Batch: B Matrix: Water 31 Method: EPA Method 1631 Analyte: Hg Result B BLK B BLK B BLK B BLK Average: 0.13 Limit: 0.50 Units ng/l ng/l ng/l ng/l Standard Deviation: 0.03 Limit: 0.10 MDL: 0.15 ng/l MRL: 0.40 ng/l

25 Client Method Blanks & Reporting Limits Batch: B Matrix: Soil/Sediment Method: EPA Method 1638 mod Analyte: Al Result Units B BLK B BLK B BLK3 B BLK mg/k g Average: Limit: 7.00 Standard Deviation: 0.02 Limit: 2.30 MDL: 2.30 MRL: 7.00 Analyte: As Result Units B BLK B BLK B BLK3 B BLK Average: Limit: 1.20 Standard Deviation: 0.03 Limit: 0.40 MDL: 0.40 MRL: 1.20 Analyte: B Result Units B BLK B BLK B BLK3 B BLK Average: Limit: 5.00 Standard Deviation: 0.41 Limit: 1.00 MDL: 0.02 MRL: 0.10 Analyte: Ba Result Units B BLK B BLK B BLK3 B BLK Average: 0.00 Limit: 1.00 Standard Deviation: 0.01 Limit: 0.30 MDL: 0.30 MRL: 1.00

26 Client Method Blanks & Reporting Limits Batch: B Matrix: Soil/Sediment Analyte: Be B BLK1 B BLK2 B BLK3 B BLK4 Average: Limit: 0.30 Result Units Standard Deviation: 0.01 Limit: 0.11 MDL: 0.11 MRL: 0.30 Analyte: Ca B BLK1 B BLK2 B BLK3 B BLK4 Average: Limit: Result Units Standard Deviation: 4.40 Limit: MDL: 30.0 MRL: 150 Analyte: Cd B BLK1 B BLK2 B BLK3 B BLK4 Average: Limit: Result Units Standard Deviation: Limit: MDL: MRL: Analyte: Co B BLK1 B BLK2 B BLK3 B BLK4 Average: 0.01 Limit: 0.15 Result Units Standard Deviation: 0.01 Limit: 0.05 MDL: 0.05 MRL: 0.15

27 Client Method Blanks & Reporting Limits Batch: B Matrix: Soil/Sediment Analyte: Cr B BLK1 B BLK2 B BLK3 B BLK4 Average: 0.28 Limit: 2.00 Result Units Standard Deviation: 0.05 Limit: 0.63 MDL: 0.63 MRL: 2.00 Analyte: Cu B BLK1 B BLK2 B BLK3 B BLK4 Average: Limit: 1.00 Result Units Standard Deviation: 0.01 Limit: 0.12 MDL: 0.12 MRL: 1.00 Analyte: Fe B BLK1 B BLK2 B BLK3 B BLK4 Result Units Average: 7.8 Limit: 25.0 Standard Deviation: 0.6 Limit: 5.6 MDL: 5.6 MRL: 25.0 Analyte: K B BLK1 B BLK2 B BLK3 B BLK4 Result Units Average: 5 Limit: 40 Standard Deviation: 2 Limit: 13 MDL: 13 MRL: 40

28 Client Method Blanks & Reporting Limits Batch: B Matrix: Soil/Sediment Analyte: Mg B BLK1 B BLK2 B BLK3 B BLK4 Result Units Average: -0.7 Limit: 15.0 Standard Deviation: 0.2 Limit: 1.5 MDL: 1.5 MRL: 15.0 Analyte: Mn B BLK1 B BLK2 B BLK3 B BLK4 Average: Limit: 0.25 Result Units Standard Deviation: 0.01 Limit: 0.05 MDL: 0.05 MRL: 0.25 Analyte: Mo B BLK1 B BLK2 B BLK3 B BLK4 Result Units Average: 0.07 Limit: 1.00 Standard Deviation: 0.03 Limit: 0.10 MDL: 0.10 MRL: 1.00 Analyte: Na B BLK1 B BLK2 B BLK3 B BLK4 Result Units Average: -8 Limit: 75 Standard Deviation: 1 Limit: 15 MDL: 15 MRL: 75

29 Client Method Blanks & Reporting Limits Batch: B Matrix: Soil/Sediment Analyte: Ni B BLK1 B BLK2 B BLK3 B BLK4 Average: 0.01 Limit: 1.00 Result Units Standard Deviation: 0.01 Limit: 0.20 MDL: 0.20 MRL: 1.00 Analyte: Pb B BLK1 B BLK2 B BLK3 B BLK4 Average: 0.00 Limit: 0.25 Result Units Standard Deviation: 0.00 Limit: 0.05 MDL: 0.05 MRL: 0.25 Analyte: Se B BLK1 B BLK2 B BLK3 B BLK4 Average: 0.27 Limit: 1.00 Result Units Standard Deviation: 0.15 Limit: 0.31 MDL: 0.31 MRL: 1.00 Analyte: Sn B BLK1 B BLK2 B BLK3 B BLK4 Average: 0.13 Limit: 0.15 Result Units Standard Deviation: 0.02 Limit: 0.04 MDL: 0.04 MRL: 0.15

30 Client Batch: B Matrix: Soil/Sediment Analyte: Sr Method Blanks & Reporting Limits Result Units B BLK B BLK B BLK3 B BLK Average: 0.01 Limit: 0.03 Standard Deviation: 0.01 Limit: 0.01 MDL: 0.01 MRL: 0.03 Analyte: Ti B BLK1 B BLK2 B BLK3 B BLK4 Average: Limit: 1.00 Result Units Standard Deviation: 0.03 Limit: 0.03 MDL: 0.03 MRL: 1.00 Analyte: Tl B BLK1 B BLK2 B BLK3 B BLK4 Average: Limit: Result Units mg/k g Standard Deviation: Limit: MDL: MRL: Analyte: V B BLK1 B BLK2 B BLK3 B BLK4 Average: 0.09 Limit: 9.00 Result Units Standard Deviation: 0.03 Limit: 3.00 MDL: 3.00 MRL: 9.00

31 Client Method Blanks & Reporting Limits Batch: B Matrix: Soil/Sediment Analyte: Zn Result Units B BLK B BLK B BLK B BLK Average: Limit: 1.00 Standard Deviation: 0.01 Limit: 0.25 MDL: 0.25 MRL: 1.00 Batch: B Matrix: Soil/Sediment Method: EPA Method 1631, Appendix Analyte: Hg Result B BLK B BLK B BLK B BLK Average: 0.01 Limit: 0.10 Units ng/g ng/g ng/g ng/g Standard Deviation: 0.01 Limit: 0.03 MDL: 0.05 ng/g MRL: 0.15 ng/g

32 Client Method Blanks & Reporting Limits Batch: B Matrix: Water Analyte: Ag B BLK1 B BLK2 B BLK3 B BLK4 Result Average: Limit: Units Standard Deviation: Limit: MDL: MRL: Analyte: Al B BLK1 B BLK2 B BLK3 B BLK4 Result Average: 0.05 Limit: 1.00 Units Standard Deviation: 0.04 Limit: 0.13 MDL: 0.13 MRL: 1.01 Analyte: As B BLK1 B BLK2 B BLK3 B BLK4 Result Average: Limit: 0.20 Units Standard Deviation: 0.00 Limit: 0.04 MDL: 0.04 MRL: 0.20 Analyte: B B BLK1 B BLK2 B BLK3 B BLK4 Result Average: Limit: 1.00 Units Standard Deviation: 0.08 Limit: 0.30 MDL: 0.30 MRL: 1.01

33 Client Batch: B Matrix: Water Analyte: Ba Method Blanks & Reporting Limits B BLK1 B BLK2 B BLK3 B BLK4 Result Average: 0.00 Limit: 0.05 Units Standard Deviation: 0.00 Limit: 0.01 MDL: 0.01 MRL: 0.05 Analyte: Be B BLK1 B BLK2 B BLK3 B BLK4 Result Average: Limit: Units Standard Deviation: Limit: MDL: MRL: Analyte: Cd B BLK1 B BLK2 B BLK3 B BLK4 Result Average: Limit: Units Standard Deviation: Limit: MDL: MRL: Analyte: Co B BLK1 B BLK2 B BLK3 B BLK4 Result Average: 0.00 Limit: 0.10 Units Standard Deviation: 0.00 Limit: 0.02 MDL: 0.02 MRL: 0.10

34 Client Method Blanks & Reporting Limits Batch: B Matrix: Water Analyte: Cr B BLK1 B BLK2 B BLK3 B BLK4 Result Average: 0.00 Limit: 0.15 Units Standard Deviation: 0.02 Limit: 0.07 MDL: 0.07 MRL: 0.15 Analyte: Cu B BLK1 B BLK2 B BLK3 B BLK4 Result Average: Limit: 0.20 Units Standard Deviation: 0.00 Limit: 0.04 MDL: 0.04 MRL: 0.20 Analyte: Fe B BLK1 B BLK2 B BLK3 B BLK4 Result Average: -0.5 Limit: 5.0 Units Standard Deviation: 0.1 Limit: 1.4 MDL: 1.4 MRL: 5.1 Analyte: Mn B BLK1 B BLK2 B BLK3 B BLK4 Result Average: Limit: Units Standard Deviation: Limit: MDL: MRL: 0.051

35 Client Method Blanks & Reporting Limits Batch: B Matrix: Water Analyte: Mo B BLK1 B BLK2 B BLK3 B BLK4 Result Average: Limit: Units Standard Deviation: Limit: MDL: MRL: Analyte: Ni B BLK1 B BLK2 B BLK3 B BLK4 Result Average: 0.00 Limit: 0.20 Units Standard Deviation: 0.00 Limit: 0.04 MDL: 0.04 MRL: 0.20 Analyte: Pb B BLK1 B BLK2 B BLK3 B BLK4 Result Average: Limit: Units Standard Deviation: Limit: MDL: MRL: Analyte: Sb Result B BLK B BLK B BLK B BLK Average: Limit: Units Standard Deviation: Limit: MDL: MRL: 0.020

36 Client Batch: B Matrix: Water Analyte: Se Method Blanks & Reporting Limits Result B BLK B BLK B BLK B BLK Average: Limit: 0.30 Units Standard Deviation: 0.01 Limit: 0.11 MDL: 0.11 MRL: 0.30 Analyte: Sr Result B BLK B BLK B BLK B BLK Average: Limit: Units Standard Deviation: Limit: MDL: MRL: Analyte: Tl Result B BLK B BLK B BLK B BLK Average: Limit: Units Standard Deviation: Limit: MDL: MRL: Analyte: V Result B BLK B BLK B BLK B BLK Average: 0.01 Limit: 0.15 Units Standard Deviation: 0.00 Limit: 0.03 MDL: 0.03 MRL: 0.15

37 Client Method Blanks & Reporting Limits Batch: B Matrix: Water Analyte: Zn Result B BLK B BLK B BLK B BLK Average: Limit: 0.20 Units Standard Deviation: 0.01 Limit: 0.05 MDL: 0.05 MRL: 0.20 Batch: B Matrix: Water Analyte: Sn Result B BLK B BLK B BLK B BLK Average: Limit: Units Standard Deviation: Limit: SOP: BR-0065 MDL: MRL: Analyte: Ti Result B BLK B BLK B BLK B BLK Average: 0.01 Limit: 0.20 Units Standard Deviation: 0.01 Limit: 0.04 MDL: 0.04 MRL: 0.20

38 Client Instrument Calibration Sequence: Instrument: THG-05 Date: 07/31/2016 Analyte: Hg Total Mercury and Mercury Speciation by CVAFS Method: EPA Method CAL pg of Hg 93% CAL pg of Hg 101% CAL pg of Hg 101% CAL pg of Hg 104% CAL pg of Hg 102% ICV pg of Hg 105% CCV pg of Hg 104% CCV pg of Hg 99%

39 Client Instrument Calibration Sequence: Instrument: THG-05 Date: 08/04/2016 Analyte: Hg Total Mercury and Mercury Speciation by CVAFS Method: EPA Method 1631, Appendix CAL pg of Hg 92% CAL pg of Hg 100% CAL pg of Hg 98% CAL pg of Hg 103% CAL pg of Hg 107% ICV pg of Hg 106% CCV pg of Hg 90% CCV pg of Hg 105% CCV pg of Hg 104%

40 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: Ag 107 Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV % Analyte: Al CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV % CCV % CCV %

41 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: As 75 Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % CCV % ICV % CCV % CCV % CCV % CCV % Analyte: B CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % CCV % ICV % CCV % CCV %

42 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: Ba Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV % Analyte: Be CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV %

43 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: Ca Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV % CCV % CCV % Analyte: Cd CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV %

44 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: Co Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV % Analyte: Cr CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV %

45 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: Cu 63 Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV % Analyte: Fe CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV % CCV % CCV %

46 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: Mg Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV % Analyte: Mn CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV % CCV % CCV %

47 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: Mo Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % CCV % ICV % CCV % CCV % Analyte: Ni CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV %

48 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: Pb Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % CCV % ICV % CCV % CCV % Analyte: Sb CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV %

49 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: Se 77 Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV % Analyte: Sr CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV %

50 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: Tl Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV % Analyte: V CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV %

51 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/19/2016 Analyte: Zn 66 Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % ICV % CCV % CCV %

52 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/24/2016 Analyte: Al Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % Analyte: As CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV %

53 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/24/2016 Analyte: B Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % Analyte: Ba CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV %

54 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/24/2016 Analyte: Be Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % Analyte: Cd CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV %

55 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/24/2016 Analyte: Co Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % Analyte: Cr CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV %

56 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/24/2016 Analyte: Cu 63 Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % Analyte: Fe CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV %

57 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/24/2016 Analyte: Mn Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % Analyte: Mo CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV %

58 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/24/2016 Analyte: Ni 60 Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % Analyte: Pb CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV %

59 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/24/2016 Analyte: Sb Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % Analyte: Se CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV %

60 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/24/2016 Analyte: Sn Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % Analyte: Sr CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV %

61 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/24/2016 Analyte: Ti 47 Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % Analyte: Tl CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV %

62 Client Instrument Calibration Sequence: Instrument: ICP-MS-2 Date: 08/24/2016 Analyte: V Trace Metals by ICP-MS CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % ICV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % Analyte: Zn CAL % CAL % CAL % CAL % CAL % CAL % CAL % CAL % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV % CCV %

63 Client Containers : : Tin & Titanium Des Container A Bottle HDPE ICP-W Size Vial Lot Report Matrix: Water Type: QC Preservation P-Lot Collected: unknown Received: 07/22/2016 ph Ship. Cont. Comments Cardboard Box : : Hardness Des Container A Bottle HDPE ICP-W Size 125 ml Lot Report Matrix: Water Collected: 07/22/2016 Type: QC Received: 07/22/2016 Preservation P-Lot ph Ship. Cont. Comments Cardboard Box : : Low Level Hg (WP-174) Des Container A Bottle FLPE Hg-T Size Lot Report Matrix: Water Collected: 07/22/2016 Type: QC Received: 07/22/2016 Preservation P-Lot ph Ship. Cont. Comments Cardboard Box : : Trace Metals Des Container A Bottle HDPE ICP-W Size 40-mL Lot Report Matrix: Water Type: QC Preservation None P-Lot n/a Collected: 07/22/2016 Received: 07/22/2016 ph Ship. Cont. Comments Cardboard Box : : Trace Metals in Soil Comments: Prep by both RAR and nitric only prep Des Container A Jar Glass Size Lot Report Matrix: Soil/Sediment Type: QC Preservation P-Lot Collected: 07/22/2016 Received: 07/22/2016 ph Ship. Cont. Comments Cardboard Box : : CrVI in Soil Des Container A Jar Glass Size Lot Report Matrix: Soil/Sediment Collected: 07/22/2016 Type: QC Received: 07/22/2016 Preservation P-Lot ph Ship. Cont. Comments Cardboard Box

64 Client Containers : : Hardness (TSS split) Des Container A Bottle HDPE ICP-W Size 500 ml Lot Report Matrix: Water Collected: 07/22/2016 Type: QC Received: 07/22/2016 Preservation P-Lot ph Ship. Cont. Comments Cardboard Box Shipping Containers Cardboard Box Received: July 22, :00 Tracking No: via FedEx Coolant Type: None Temperature: ambient Description: Cardboard Box Damaged in transit? No Returned to client? No Custody seals present? No Custody seals intact? No COC present? Yes