Aromatic Integration

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1

2 romatic Integration

3 Wine aromas light white Unstructured wine

4 Wine aromas light white IG RED Unstructured wine

5 Wine aromas light white IG RED Unstructured wine tannin/pigment oligomers Structured wine

6 Wine aromas light white Unstructured wine tannin/pigment oligomers Structured wine

7 Refining Structure

8 hocolate Making cocoa dark chocolate milk chocolate butterfat & oxygen milk protein & vanilla harsh bitter nasty hard bitter profound refined plush visceral

9 abernet Elevage raw abernet structured abernet mature abernet color & oxygen lees protein & sweet oak harsh bitter nasty hard bitter profound refined plush visceral

10 Tannin Terminology

11 green Tannin Nomenclature

12 Without Micro-Ox green dry

13 With Micro-Ox HRD green

14 With Micro-Ox HRD

15 With Micro-Ox HRD melted

16 With Micro-Ox HRD melted

17 Wood Pictures : Patrick VUHOT

18 Tannin Nomenclature HRD melted green Parching / numbing (oak) dry

19 Structural Elevage

20 and Related Elevage Techniques

21 Elevage Goals for Serious Reds uild and refine structure Stabilize color Enhance body & finesse ontrol sulfides romatic Integration Prevent color loss, Enhance longevity, Prevent dryness Refine mouthfeel, Eliminate fining alance reductive strength, Eliminate copper oak, rett viscerality

22 Fundamental Principles ontrolled O 2 => novel structures. Timing is crucial to the wine s capacity for O 2 uptake: Day 1: pre-ml color stabilization ( arrel doses) Month 3: post-so 2 structuring (1 10 arrel doses) Year 2: harmonization & refinement ( arrel doses). ctive color = safety net (prevents dryness)--avoid over-ripeness Narrow temperature window: o F. Not designed as a way to accelerate ageing!

23 ldehyde Harmonization? O 2 dose Three Phases of Reduction Management ML F uild reductive strength, arrel down SP 6 20 months stabilize color Phase I Phase II Phase III Quick clarification ompletion of alcoholic fermentation

24 Principal omponent nalysis for Micro-Ox Treated Wines Oxidation Off roma 3 1 Veg aroma Tannin-Green Tannin-Grit 2 T2 Tannin- Plushness T1 T3 Fruity T Trials: 1 entral Valley Merlot 2 Solano abernet 3 Napa Merlot 4 Rutherford abernet

25 Different phases during Micro-oxygenation Fermentation aromas Varietal aromas Oxydative aromas omlexity Drying Increase of tannins Softening uilding phase Refinement Over oxygenation

26 uilding locks of Red Wine Structure nthocyanin (color) ontains no vicinal diphenol (terminates polymer) Flavanol (tannin) ontains a vicinal diphenol (can oxidatively polymerize)

27 Non-oxidative direct polymerization 4 8

28 ompact structure of direct polymerization 4 8

29 ompact structure of direct polymerization

30 nthocyanin termination of direct polymerization

31 Interpretation of principle of oxydation of di-phenols Singleton, H 0H H 2 0 2

32 Example of polymerative regeneration (Singleton, 1986)

33 Example of polymerative regeneration (Singleton, 1986)

34 Simplified interpretation of oxydative polymerization O 2

35 Simplified interpretation of oxydative polymerization

36 Simplified interpretation of oxidative polymerization

37 Simplified interpretation of oxidative polymerization O 2

38 Simplified interpretation of oxydative polymerization

39 Simplified interpretation of oxydative polymerization

40 Simplified interpretation of oxydative polymerization

41 Simplified interpretation of oxydative polymerization

42 Simplified interpretation of oxydative polymerization

43 Simplified interpretation of oxydative polymerization

44 Simplified interpretation of oxydative polymerization

45 Simplified interpretation of oxydative polymerization

46 Simplified interpretation of oxydative polymerization

47 Simplified interpretation of oxydative polymerization

48 Simplified interpretation of oxydative polymerization

49 Simplified interpretation of oxydative polymerization

50 Simplified interpretation of oxydative polymerization

51 Simplified interpretation of oxydative polymerization

52 Simplified interpretation of oxydative polymerization

53 Simplified interpretation of oxydative polymerization

54 Simplified example of oxydative polymerization

55 Simplified example of oxydative polymerization Same constitutive monomers yet ompletely different behaviour

56 Lees Pictures : Patrick VUHOT

57 Influence of late batonnage on extraction of oak compounds ROMTI ONENTRTION STRINGENY % of LEES

58 Influence of early turbidity on finished wine characteristics NTHOYNIN DSORPTION & DEGRDTION DRYNESS % of LEES

59 Take Home Messages olor is the key to structure Optimum Ripeness (RO) o-extraction strategies, fermenter blends EVERY DEGREE of cellar temperature is critical

60

Timing of Treatment O 2 Dosage Typical Duration During Fermentation mg/l Total Daily. Between AF - MLF 1 3 mg/l/day 4 10 Days

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