Analytical Reference Materials ASTM D6042 Calibration Mixture Catalog # 31628 Lot # A073321 & A066644 110 Benner Circle Bellefonte, PA 16823-8812 (814) 353-1300 FOR LABORATORY USE ONLY. READ MSDS PRIOR TO USE. RAW MATERIAL TEST INFORMATION AVAILABLE UPON REQUEST MANUFACTURED UNDER RESTEK'S ISO 9001 REGISTERED QUALITY SYSTEM
Certificate of Analysis 110 Benner Circle Bellefonte, PA 16823-8812 Tel: (800)356-1688 Fax: (814)353-1309 FOR LABORATORY USE ONLY-READ MSDS PRIOR TO USE. Catalog No. : 31628 Lot No.: A066644 Description : ASTM D6042 Calibration Mixture Expiration Date : April 2016 Storage: Refrigerate Elution Order CAS # Percent Purity 2 Concentration (weight/volume) 1 2,6-Di-tert-butyl-4-methylphenol (BHT) 128-37-0 99% 2 Erucamide 112-84-5 90% 49.950 ug/ml 3 Irganox 3114 27676-62-6 98% 4 Irganox 1010 6683-19-8 99% 5 Vitamin E 59-02-9 99% 6 Irganox 1076 2082-79-3 99% 7 Irgafos 168 31570-04-4 99% 3 % Uncertainty (95% C.L.; K=2) 4 Solvent: Isopropanol 67-63-0 99% Column: 150 mm x 4.6 mm Ultra C8 (cat.# 9103565) Flow Rate: 1.5 ml/min. Mobile Phase A: H2O Mobile Phase B: Acetonitrile Mobile Phase 0 min.-75%b; 5 min.-100%b; 25 min. Det. Type: Wavelength: 200 nm Date Passed: 04/09/2009 Balance: 1128342314 1 Expiration date of the unopened ampule stored at recommended temperature. 2A Purity was determined by one or more of the following techniques: GC/FID, HPLC, GC/ECD, GC/MS. Value rounded to the nearest whole number. In addition to detectors listed above, chemical identity and purity are confirmed using one or more of the following: MS, DSC, solid probe MS, GC/FPD, GC/NPD, GC/TC, FTIR, melting point, refractive index, and Karl Fisher. See data pack or contact Restek for further details. 2B s with a listed purity of less than 99% have been weight corrected to compensate for impurities. 2C s with a listed purity of less than 99% may be salts, derivatives, or hydrates. The listed purity is actually a correction factor that was used to calculate the amount of compound necessary to acheive the desired concentration of the parent compound. 3 Based upon gravimetric preparation with balance calibration verified using NIST traceable weights (seven mass levels). 4 Uncertainties determined using repeatability and reproducibility data for balances and glassware from measurement systems analysis methodology, balance and glassware tolerances, raw material purity, and, where applicable, eccentricity and linearity values from an accredited calibration laboratory. Manufactured under Restek's ISO 9001-2000 Registered Quality System Certificate #FMB0397
Catalog #: 31628 Target: 50 ug/ml Description: ASTM D6042 Calibration Mixture Solvent: Isopropanol Solvent Lot: 48111 Chemical Standard Batch Sheet Lot #:A066644 Final Volume: 200 ml Made by: Joe Tallon Date: 3/25/2009 10:43:28AM Tested by: Diane Shaffer Pass Date: 3/25/2009 2:23:37PM By: Diane Shaffer Date: 4/9/2009 11:52:25AM Packaged by: Jessie Emel / Marty Rockey Date: 3/25/2009 1:08:48PM No. Units: 62 Pkg Size: 1 ml Balance Used: ARMBALPC2 XP205 Serial #: 1128342314 CAS Vitamin E 59-02-9 Erucamide 112-84-5 Irganox 3114 27676-62-6 Irganox 1010 6683-19-8 Irganox 1076 2082-79-3 Irgafos 168 31570-04-4 2,6-Di-tert-butyl-4-methylphenol (BHT) 128-37-0 Storage Target Location Lot # Purity Conc(ug/ml) Target Actual Calc Conc(ug/ml) RA2H13C 10209MQ 0.99 50.00 10.00 mg 10.00 mg 50.000 RA2H13D 02024EY 0.90 50.00 11.11 mg 11.10 mg 49.950 VL-001 HY8MZJJ04 0.98 50.00 10.00 mg 10.00 mg 50.000 VL-004 AB236E8U 0.99 50.00 10.00 mg 10.00 mg 50.000 VL-006 AC256A8U 0.99 50.00 10.00 mg 10.00 mg 50.000 VL-013 AA001A00 0.99 50.00 10.00 mg 10.00 mg 50.000 VL-025 8022 0.99 50.00 10.00 mg 10.00 mg 50.000
Certificate of Analysis 110 Benner Circle Bellefonte, PA 16823-8812 Tel: (800)356-1688 Fax: (814)353-1309 FOR LABORATORY USE ONLY-READ MSDS PRIOR TO USE. Catalog No. : 31628 Lot No.: A073321 Description : ASTM D6042 Calibration Mixture Expiration Date : April 2017 Storage: Refrigerate Elution Order CAS # Percent Purity 2 Concentration (weight/volume) 1 2,6-Di-tert-butyl-4-methylphenol (BHT) 128-37-0 99% 2 Erucamide 112-84-5 90% 49.950 ug/ml 3 Irganox 3114 27676-62-6 98% 49.980 ug/ml 4 Irganox 1010 6683-19-8 99% 5 Vitamin E 59-02-9 99% 6 Irganox 1076 2082-79-3 99% 7 Irgafos 168 31570-04-4 99% 3 % Uncertainty (95% C.L.; K=2) 4 Solvent: Isopropanol 67-63-0 99% Column: 150 mm x 4.6 mm Ultra C8 (cat.# 9103565) Flow Rate: 1.5 ml/min. Mobile Phase A: H2O Mobile Phase B: Acetonitrile Mobile Phase Comp 0 min.-75%b; 5 min.-100%b; 25 min.-100%b Det. Type: Wavelength: 200 nm Date Passed: 08-Mar-2010 Balance: 1128342313 1 Expiration date of the unopened ampule stored at recommended temperature. 2A Purity was determined by one or more of the following techniques: GC/FID, HPLC, GC/ECD, GC/MS. Value rounded to the nearest whole number. In addition to detectors listed above, chemical identity and purity are confirmed using one or more of the following: MS, DSC, solid probe MS, GC/FPD, GC/NPD, GC/TC, FTIR, melting point, refractive index, and Karl Fisher. See data pack or contact Restek for further details. 2B s with a listed purity of less than 99% have been weight corrected to compensate for impurities. 2C s with a listed purity of less than 99% may be salts, derivatives, or hydrates. The listed purity is actually a correction factor that was used to calculate the amount of compound necessary to achieve the desired concentration of the parent compound. 2D Purity of isomeric compounds is reported as the sum of the isomers. Value is rounded to the nearest whole number after summation. 3 Based upon gravimetric preparation with balance calibration verified using NIST traceable weights (seven mass levels) and/or class A glassware used for dilutions. 4 Uncertainties determined using repeatability and reproducibility data for balances and glassware from measurement systems analysis methodology, balance and glassware tolerances, raw material purity, and, where applicable, eccentricity and linearity values from an accredited calibration laboratory. Manufactured under Restek's ISO 9001:2008 Registered Quality System Certificate #FM 80397
Catalog #: 31628 Target: 50 ug/ml Description: ASTM D6042 Calibration Mixture Solvent: Isopropanol Solvent Lot: 48319 Chemical Standard Batch Sheet Lot #:A073321 Final Volume: 200 ml Made by: Matt Hepfer Date: 3/3/2010 6:28:08PM Tested by: Sara Eyster Pass Date: 3/4/2010 1:46:07PM By: Diane Shaffer Date: 3/8/2010 4:18:34PM Packaged by: Jessie Emel / cozzoli Date: 3/4/2010 11:05:16AM No. Units: 139 Pkg Size: 1 ml Balance Used: ARMBALPC1 XP205 Serial #: 1128342313 CAS Vitamin E 59-02-9 Erucamide 112-84-5 Irganox 3114 27676-62-6 Irganox 1010 6683-19-8 Irganox 1076 2082-79-3 Irgafos 168 31570-04-4 2,6-Di-tert-butyl-4-methylphenol (BHT) 128-37-0 Storage Target Location Lot # Purity Conc(ug/ml) Target Actual Calc Conc(ug/ml) R1102 10209MQ 0.99 50.00 10.00 mg 10.00 mg 50.000 R1103 02024EY 0.90 50.00 11.11 mg 11.10 mg 49.950 VL-001 HY8MZJJ04 0.98 50.00 10.20 mg 10.20 mg 49.980 VL-004 AB236E8U 0.99 50.00 10.00 mg 10.00 mg 50.000 VL-006 AC256A8U 0.99 50.00 10.00 mg 10.00 mg 50.000 VL-013 AA001A00 0.99 50.00 10.00 mg 10.00 mg 50.000 VL-025 8022 0.99 50.00 10.00 mg 10.00 mg 50.000
QA Report: ASTM D6042 Calibration Mixture (Cat.#31628) Runs of Lot # A073321 Runs of Lot # A066644 COMPONENT Run #1 Run #2 Run #3 AVG STD DEV % RSD Run #1 Run #2 Run #3 AVG STD DEV % RSD %D ME... P/F 2,6-Di-tert-butyl-4-methylphenol 1929089 1926738 1878805 191154 28377 1.48 1807202 1772904 1795634 179191 17449 0.97 6.26 PASS Erucamide 1777921 1768863 1752886 176655 12676 0.72 1630441 1638621 1642286 163711 6064 0.37 7.33 PASS Irganox 3114 147144 145577 143812 145511 1667 1.15 133112 125697 138428 132412 6394 4.83 9.00 PASS Irganox 1010 1440160 1433205 1419221 143086 10664 0.75 1337901 1342969 1346210 134236 4188 0.31 6.19 PASS Vitamin E 854751 845284 834662 844899 10050 1.19 770435 771508 772739 771561 1153 0.15 8.68 PASS Irganox 1076 875139 859389 851987 862172 11824 1.37 824626 832905 833292 830274 4895 0.59 3.70 PASS Irgafos 168 1745517 1586671 1643039 165840 80531 4.86 1560865 1569980 1535870 155557 17660 1.14 6.20 PASS 3/8/2010 4:15:28 PM 1/1-1