DragoColor colorants. Issue 01/05

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FOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODS FOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFO ODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOOD SFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODS FOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFO DragoColor colorants ODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOOD SFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODS FOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFOODSFO DRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGS DRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRU GSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGS DRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRU GSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGS DRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRU GSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGS DRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRUGSDRU COSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSM ETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOS METICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSC OSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSM ETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOS METICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSC OSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSME TICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOSMETICSCOS Issue 01/05 www.symrise.com

CONTENTCONTENTCONTENTCONTENTCONTENT 1. DragoColor colorants for foods, drugs and cosmetics..........................................6 SO RED TASTES BETTER. SO YELLOW FEELS BETTER. SO BLUE LASTS LONGER. 2. DragoColor dye, lake and pigment compounds...............................................10 3. DragoColor colorants for instant products...................................................14 More colors, more quality, more options: DragoColor by Symrise is the ideal solution for every product and every taste. 3.1 General processing information.......................................................14-15 The DragoColor product range offers a wide selection of water- and oil soluble colorants, color lakes and pigments to suit your individual preferences in coloring foods, drugs and cosmetics. From sweets, ice cream, dessert products and soft drinks, instant beverages, soups and sauces all the way to snack foods DragoColor gives your foods that certain something. At the same time, it is equally suited for liquid medicines, pills, coated tablets and bath articles, toothpastes and gels, mouth washes, oral care products and many other cosmetics 1 DragoColor will bring the right nuance to everything you make. With the DragoColor range, Symrise brings more color into your life and into your business. 2 1 See also the DragoColor colorants for cosmetics brochure. It will provide you with more information about other Symrise products which are not suitable for use in food. 3

SAFETY AND DRAGOCOLOR : QUALITY YOU CAN COUNT ON. SYMRISE SERVICE: WHAT WE CAN DO FOR YOU. Analyzed, tested, approved: DragoColor food dyes fulfill the legal guidelines of the member states of the European Union for coloring foods 2 Everything at a glance: The overview below will provide you with everything you need to know about the product descriptions, application and drugs. DragoColor products also fulfill guidelines in many other countries as well. All food dyes are suitable and have been approved for instructions and recommended doses. If you have further questions about legal guidelines and using DragoColor colorants for international use as colorants in cosmetic products. export, we would be more than happy to assist you. Please contact: Bernd Schröder Symrise GmbH & Co. KG Color Dept. 37601 Holzminden/Germany Phone: + 49/0 55 31/90-32 48 Fax: + 49/0 55 31/90-38 20 E-Mail: bernd.schroeder@symrise.com Our complete Dictionary of Colors can be found online at www.symrise.com. 2 The maximum quantities of food dyes stated in the EU directive 94/36/EWG are to be observed. 4 5

1. DragoColor colorants for foods, drugs and cosmetics Listed by E-Number E-Number Color Index Product Number Name Color, Delivery form, Solubility Examples of application 3 Number E 101 (i) 115418 Riboflavin pur (Lactoflavin) yellow, powder, water soluble sweets, desserts E 102 19140 100296 Tartrazine 85% yellow, powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing E 102 19140 656802 FD&C Yellow No. 5 85% yellow, powder, water soluble for the export in the USA: beverages, sweets, desserts, bubble bath, dishwashing E 102 19140 106654 FD&C Yellow No. 5 lake 24 28% yellow, powder, lake for the export in the USA: dragees, fatty filling compounds E 102 19140:1 656828 Tartrazine lake 17% yellow, powder, lake dragees, fatty filling compounds E 104 47005 100290 Quinoline Yellow 70% yellow, powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing E 104 47005 645296 Quinoline Yellow granular 70% yellow, granular, water soluble beverages, sweets, desserts, bubble bath, dishwashing E 104 47005:1 656829 Quinoline lake 11% yellow, powder, lake dragees, decorative cosmetics, fatty filling compounds E 110 15985 100291 Orange Yellow 85% orange, powder, water soluble sweets, beverages, desserts, bubble bath, dishwashing E 110 15985 645571 Orange Yellow granular 85% orange, granular, water soluble beverages, sweets, desserts, bubble bath, dishwashing E 110 15985 656685 Golden Orange Yellow 30% orange, powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing E 110 15985 656803 FD&C Yellow 4 No. 6 85% orange, powder, water soluble for the export in the USA: beverages, sweets, desserts, bubble bath, dishwashing E 110 15985:1 186691 FD&C Yellow No. 6 lake orange, powder, lake for the export in the USA: dragees, decorative cosmetics, fatty filling compounds E 110 15985:1 656831 Orange Yellow lake 11% orange, powder, lake dragees, decorative cosmetics, fatty filling compounds E 120 75470 656825 Carmine 43% red, powder, water soluble sweets, beverages E 120 75470 656461 Carmine 4.1 4.5% red, powder, water soluble sweets, beverages E 122 14720 100293 Azorubine 85% red, powder, water soluble beverages, sweets, desserts, bubble bath E 122 14720 656445 Azorubine 35% red, powder, water soluble beverages, sweets, desserts, bubble bath E 122 14720 656832 Azorubine lake 11-13% red, powder, lake dragees, decorative cosmetics, fatty filling compounds E 123 16185 100292 Amaranth 85% red, powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing E 123 16185 656448 Amaranth 32% red, powder, water soluble beverages, sweets, desserts, bubble bath E 124 16255 100300 Ponceau 4R 70% (Cochineal Red A) red, powder, water soluble beverages, sweets, desserts, bubble bath E 124 16255 656813 Ponceau 4R 80% red, powder, water soluble beverages, sweets, desserts, bubble bath E 124 16255 656447 Ponceau 4R 28% red, powder, water soluble beverages, sweets, desserts, bubble bath 3 4 The American designation yellow is misleading, since the aqueous solution of the dye is orange. 6 7

E-Number Color Index Product Number Name Color, Delivery Form, Solubility Examples of application 3 Number E 127 45430 656808 Erythrosine 85% red, powder, water soluble cherries/tinned food E 128 18050 656809 Red 2G red, powder, water soluble meat products, bubble bath; in the EU not allowed for coloring drugs E 129 16035 100304 Allura Red 85% red, powder, water soluble beverages, sweets, desserts, bubble bath, mouth wash; in the EU not allowed for coloring drugs E 129 16035 100295 FD&C Red No. 40 85% red, powder, water soluble for the export in the USA: beverages, sweets, desserts, bubble bath, mouth wash E 129 16035 186693 FD&C Red No. 40 lake 35-41% red, powder, lake for the export in the USA: dragees, decorative cosmetics, fatty filling compounds E 131 42051 100294 Patent Blue V 80% blue, powder, water soluble beverages, sweets, desserts, bubble bath, mouth wash, gel toothpaste E 131 42051 645295 Patent Blue granular 85% blue, granular, water soluble beverages, sweets, desserts, mouth wash, gel toothpaste E 131 42051 656597 Brilliant Blue 7.5% blue, powder, water soluble beverages, sweets, desserts, bubble bath, mouth wash, gel toothpaste E 131 42051 656598 Patent Blue 50% blue, powder, water soluble beverages, sweets, desserts, bubble bath, mouth wash, gel toothpaste E 132 73015 100298 Indigotine 85% blue, powder, water soluble sweets E 132 73015 656827 Indigotine lake 7.5% blue, powder, lake dragees, decorative cosmetics, fatty filling compounds E 132 73015 656602 Indigotine 16% blue, powder, water soluble sweets E 133 42090 656601 Brilliant Blue FCF 85% blue, powder, water soluble beverages, sweets, desserts, bubble bath, mouth wash, gel toothpaste; in the EU not allowed for coloring drugs E 133 42090 645367 Brilliant Blue FCF granular 85% blue, granular, water soluble beverages, sweets, desserts, bubble bath, mouth wash, gel toothpaste; in the EU not allowed for coloring drugs E 133 42090 100301 FD&C Blue No. 1 85% blue, powder, water soluble for the export in the USA: beverages, sweets, desserts, bubble bath, mouth wash, gel toothpaste E 133 42090:2 186692 FD&C Blue No. 1 lake 10 13% blue, powder, lake for the export in the USA: dragees, decorative cosmetics, fatty filling compounds E 141 75810 656678 Copper chlorophyll complex green, paste, oil soluble oils and fats, creams, soap E 141 75810 656821 Copper chlorophyll complex 10% green, paste, oil soluble oils and fats, creams, soap E 141(ii) 75815 656683 Sodium copper chlorophyllin 9% green, powder, water soluble beverages (not in sour range), sweets E 141 75815 5 100308 Sodium copper chlorophyllin 95-100% green, powder, water soluble beverages (not in sour range), sweets E 142 44090 656805 Brilliant Acid Green 78% green, powder, water soluble sweets E 150 c --- 656815 Caramel brown, powder, water soluble soups, sauces, sweets E 150 d --- 103603 Couleur brown, liquid, water soluble acid-stable caramel, particularly suitable for softdrinks E 151 28440 100303 Brilliant Black BN 80% black, powder, water soluble beverages, sweets, bubble bath E 155 20285 656798 Brown HT 85% brown, powder, water soluble sweets; in the EU not allowed for coloring drugs and cosmetics E 160 a 40800 656818 ß-Carotine approx. 0.3% yellow-orange, liquid, oil soluble margarine, oils, mayonnaise, fats, soft cheese, creams, cosmetic products E 160 a 40800 656819 ß-Carotine approx. 10% yellow-orange, powder, water dispersible beverages, sweets, desserts E 160 b 75120 656816 Annatto approx. 0.5% orange, liquid, oil soluble margarine, oils, mayonnaise, soft cheese E 163 --- 656824 Enocyanine red, powder, water soluble sweets, beverages E 171 77891 656838 Titanium dioxide white, powder, pigment dragees, sweets, decorativ cosmetics, soap, toothpaste E 172 77492 656835 Iron oxide Yellow yellow, powder, pigment dragees, sweets, decorativ cosmetics, soap E 172 77491 656836 Iron oxide Red red, powder, pigment dragees, sweets, decorativ cosmetics, soap E 172 77499 656837 Iron oxide Black black, powder, pigment dragees, sweets, decorativ cosmetics, soap 3 5 The number C.I. 75810 as indicated in numerous publications and articles of legislature is incorrect. 8 9

2. DragoColor dye, lake and pigment compounds Color Product Number Name E- and Color Index Number Delivery Form, Solubility Examples of application 6 red 607527 Red E 124, 110, 132, C.I. 16255, 15985, 73015 powder, water soluble beverages, sweets, desserts red 656440 Scarlet Red E 124, 110, C.I. 16255, 15985 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing brown 656605 Cognac Brown E 102, 122, 151, C.I. 19140, 14720, 28440 powder, water soluble sweets, desserts brown 656606 Gold Brown E 102, 110, 151, C.I. 19140, 15985, 28440 powder, water soluble sweets, desserts brown 656607 Light Brown E 110, 102, 151, C.I. 15985, 19140, 28440 powder, water soluble sweets, desserts brown 656613 Chocolate Brown E 110, 151, 122, 102, C.I. 15985, 28440, 14720, 19140 powder, water soluble sweets, desserts brown 100306 Chocolate Brown E 102, 124, 151, C.I. 19140, 16255, 28440 powder, water soluble sweets, desserts brown 656614 Coffee Brown extra E 102, 110, 124, 151, C.I. 19140, 15985, 16255, 28440 powder, water soluble sweets, desserts brown 656615 Chocolate Brown E 110, 151, C.I. 15985, 28440 powder, water soluble sweets, desserts brown 656616 Coffee Brown E 110, 122, 132, 104, C.I. 15985, 14720, 73015, 47005 powder, water soluble sweets, desserts brown 656617 Natural E 171, 172, C.I. 77491, 77492, 77499, 77891 powder, pigment dragees, decorative cosmetics brown 656621 Pigment Brown E 171, 172, C.I. 77491, 77492, 77499, 77891 powder, pigment dragees, decorative cosmetics brown 656622 Chocolate Brown E 171, 172, C.I. 77491, 77492, 77499, 77891 powder, pigment dragees, decorative cosmetics brown 656623 Brown 1478/14 E 171, 172, C.I. 77491, 77492, 77499, 77891 powder, pigment dragees, decorative cosmetics brown 656624 Brown CT E 171, 172, C.I. 77491, 77492, 77499, 77891 powder, pigment dragees, decorative cosmetics brown 656625 Brown E 172, C.I. 77491, 77499 powder, pigment dragees, decorative cosmetics brown 656626 Red Brown E 172, C.I. 77491, 77492, 77499, 77891 powder, pigment dragees, decorative cosmetics brown 656627 Brown 1642/10 E 171, 172, C.I. 77491, 77492, 77499, 77891 powder, pigment dragees, decorative cosmetics brown 656628 Brown 1464 E 171, 172, C.I. 77491, 77492, 77499, 77891 powder, pigment dragees, decorative cosmetics brown 656629 Brown 1060/82 E 172, 171, C.I. 77491, 77492, 77499, 77891 powder, pigment dragees, decorative cosmetics brown 656630 Brown 1060/81 E 171, 172, C.I. 77491, 77492, 77499, 77891 powder, pigment dragees, decorative cosmetics yellow 614574 Yellow E 160a, 101, C.I. 40800 powder, water dispersible sweets, desserts yellow 656304 Vanilla Yellow E 104, 110, 124, C.I. 47005, 15985, 16255 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing yellow 656635 Light Yellow E 104, C.I. 47005, 30% powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing yellow 656639 Egg Yellow E 102, 110, 124, C.I. 19140, 15985, 16255 powder, water soluble beverages, sweets, desserts, bubble bath yellow 656641 Banana Yellow E 102, 110, C.I. 19140, 15985 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing yellow 656642 Yellow E 104, 110, C.I. 47005, 15985 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing 6 10 11

Color Product Number Name E- and Color Index Number Delivery Form, Solubility Examples of application 6 yellow 656644 Yellow E 102, 110, C.I. 19140, 15985 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing yellow 656645 Egg Yellow E 102, 110, 124, C.I. 19140, 15985, 16255 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing yellow 656648 Egg Yellow E 102, 110, C.I. 19140, 15985 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing yellow 656649 Egg Yellow E 102, 110, C.I. 19140, 15985 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing yellow 656650 Yellow E 102, 124, C.I. 19140, 16255 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing yellow 656651 Gold Yellow E 102, 110, C.I. 19140, 15985 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing yellow 656654 Riboflavine E 101 powder, water soluble sweets, desserts yellow 656656 Carotine E 160a, C.I. 40800 powder, water dispersible beverages, sweets, desserts, creams yellow 100305 Lemon Yellow E 102, C.I. 19140, 32% powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing green 656302 Green E 102, 131, 132 powder, water soluble beverages, sweets, desserts green 656449 Grass Green E 104, 132, C.I. 47005, 73015 powder, water soluble beverages, sweets, desserts green 656661 Peppermint Green E 102, 132, C.I. 19140, 73015 powder, water soluble beverages, sweets, desserts green 656662 Brilliant Green E 102, 131, C.I. 19140, 42051 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing green 656663 Brilliant Green extra E 102, 131, C.I. 19140, 42051 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing green 656664 Ocean Green E 104, 131, C.I. 47005, 42051 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing green 656665 Brilliant Green extra E 104, 132, C.I. 47005, 73015 powder, water soluble beverages, sweets, desserts green 656668 Green BT E 104, 110, 131, C.I. 47005, 15985, 42051 powder, water soluble beverages, sweets, desserts, bubble bath, mouth wash, dishwashing green 656670 Brilliant Green E 104, 131, C.I. 47005, 42051 powder, water soluble beverages, sweets, desserts, bubble bath, mouth wash, dishwashing green 656671 Green E 104, 110, 131, 124, C.I. 47005, 15985, 42051, 16255 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing green 656672 Herbs Green E 102, 131, 124, C.I. 19140, 42051, 16255 powder, water soluble beverages, liqueur, sweets, desserts, bubble bath, dishwashing green 656673 Leaves Green E 104, 110, 131, C.I. 47005, 15985, 42051 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing green 656674 Green 114 E 102, 133, C.I. 19140, 42090 powder, water soluble beverages, sweets, desserts, bubble bath, mouth wash, dishwashing green 656675 Woodruff Green E 102, 131, C.I. 19140, 42051 powder, water soluble beverages, sweets, desserts, dishwashing green 656676 Peppermint Green E 102, 132, C.I. 19140, 73015 powder, water soluble beverages, sweets, desserts, dishwashing green 656830 Greenlake E 104, 132, C.I. 47005, 73015 powder, lake dragees, fatty filling compounds green 656681 Yellow Green lake E 104, 132, C.I. 47005, 73015 powder, lake dragees, fatty filling compounds green 646076 Green E 102, 133, C.I. 19140, 42090 in Propandiol 1.2 a. Water liquid, oil and water soluble fatty filling compounds orange 656687 Orange E 102, 124, C.I. 19140, 16255 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing orange 656688 Red Orange E 110, 124, C.I. 15985, 16255 powder, water soluble beverages, sweets, desserts, bubble bath, dishwashing black 656464 Black E 123, 102, 142, C.I. 16185, 19140, 44090 powder, water soluble sweets, desserts black 656466 Black E 151, 110, 104, C.I. 28440, 15985, 47005 powder, water soluble sweets, desserts black 656463 Dark Black E 151, 110, 102, C.I. 28440, 15985, 19140 powder, water soluble sweets, desserts 6 12 13

3. DragoColor colorants for instant products 7 Color Product Number Name E- and Color Index Number Delivery Form, Solubility Examples of application 6 brown 656467 Caramel Brown E 104, 110, 122, 132, C.I. 47005, 15985, 14720, 73015 powder, water soluble desserts, beverage powders brown 842716 Caramel Brown E 102, 110, 151 powder, water soluble desserts, beverages yellow 656646 Light Yellow E 104, C.I. 47005 powder, water soluble beverage powders, sweets, desserts yellow 656647 Yellow Instant E 102, 110, 124, C.I. 19140, 15985, 16255 powder, water soluble desserts, beverages yellow 656468 Lemon Yellow E 102, C.I. 19140 powder, water soluble desserts, beverage powders yellow 842150 Gold Yellow Instant E 110, 102, C.I. 15985, 19140 powder, water soluble desserts, beverages green 656469 Brilliant Green TF E 104, 110, 131, C.I. 47005, 15985, 42051 powder, water soluble desserts, beverage powders orange 656436 Gold Orange E 110, C.I. 15985 powder, water soluble desserts, beverages orange 656470 Gold Orange E 110, C.I. 15985 powder, water soluble desserts, beverage powders 3.1 General processing information Soluble dyes Color lakes and pigments Usually 30 to 50 g of dye are dissolved in one liter of hot water to process water soluble dyes. It must be noted that the appearance (i.e. aspect) of a dye powder, whether in individual dyes or mixtures of dyes, is normally not identical to the color of the solution and can Pigments and lakes are insoluble dyes which achieve their colorant effect by being evenly distributed throughout the final product. Optimal processing of the dye and the desired color saturation can be ensured by means of appropriate technical equipment. vary from batch to batch. A comparison with the color standard must thus be performed by comparing the dye solutions (concentration of 1 g/l, for example). Oil soluble dyes are dissolved in the oil that is used in the formulation of the cosmetic product being manufactured. The dose of the dye in the finished product usually ranges between 50 to 500 g/ton and can be varied as desired. Care must always be taken that the dye used is completely dissolved before being added to the product being developed. If necessary, this can be monitored by filtering the stock solution. 6 7 Particle size < 0.6 mm 100%, < 0.4 mm 93%. 14 15