Gluten Replacement Save cost & maintain quality by using more soft wheat & improvers in baking and pasta applications

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Gluten Replacement Save cost & maintain quality by using more soft wheat & improvers in baking and pasta applications Dr. Lutz Popper Mühlenchemie GmbH & Co KG, Germany

Contents Gluten Enhancer Water Absorption New Bromate Replacer Pasta and Noodles

Gluten Enhancer

LP02092011 4 Gluten Enhancement The Solution Your challenge Wheat with sufficient protein and good baking performance is expensive Vital wheat gluten is expensive The solution EMCEgluten Plus improves the baking performance of low protein flour EMCEgluten Plus allows for reduction or omission of added vital wheat gluten EMCEgluten Plus reduces the costs

LP31012006 5 Effect of Protein Content and Enzyme Treatment on Volume Yield German A-wheat, breakfast rolls, 40 ppm ascorbic acid, Alphamalt A 6003 Enzymes have always been able to compensate for the lack of protein content in baking! Most enzymes have a pronounced effect on dough rheology.

LP02112008 Gluten Enhancer US Sandwich Basic treatment BX 350 ppm SSL 4,000 ppm Null A B Sample No. Null A B C EMCEvit C (%) - 3 1.5 - EMCEgluten Plus (%) - - 0.08 0.10 Vol. yield (ml 100 g flour) 840 910 920 910 Costs (USD t flour) 83.2 47.9 10.9 Null C

TKP/LP03052011 Baking Trials with Gluten Enhancer: White Bread Recipe Component % Weight (g) Flour 100 1000 Water 62 620 Sugar 4 40 Salt 1.5 15 Instant dried yeast 1 10 Shortening 4 40

TKP/LP03052011 White Bread Baking Trials with Gluten Enhancer EMCEgluten Plus Improver Function Unit Trial 1 Trial 2 Elco P100 K Ascorbic aicd ppm 100 100 Alphamalt VC 5000 SN α-amylase ppm 100 100 Alphamalt HCC Hemicellulase ppm 100 100 Vital wheat gluten % 2.15 EMCEgluten Plus Gluten enhancer % 0.215

TKP/LP03052011 Gluten Enhancer (GE) vs. Vital Wheat Gluten (VWG) in Sandwich Bread 2.15% VWG 0.215% GE 2.15% VWG 0.215% GE

TKP/LP03052011 Baking Trials with Gluten Enhancer: Whole Meal Bread Recipe Component % Weight (g) Flour 86 860 Bran 14 140 Water 62 620 Sugar 8 80 Salt 1.5 15 Instant Dry Yeast 1 10 Shortening 8 80

TKP/LP03052011 Whole Meal Bread Baking Trials with Gluten Enhancer EMCEgluten Plus Improver Function Unit Trial 1 Trial 2 Elco P100 K Ascorbic acid ppm 100 100 Alphamalt VC 5000 SN α-amylase ppm 100 100 Vital wheat gluten % 5 2 EMCEgluten Plus Gluten enhancer % 0.3

TKP/LP03052011 Gluten Enhancer (GE) vs. Vital Wheat Gluten (VWG) in Whole Meal Sandwich Bread 5% VWG 2% VWG + 0.3% GE 5% VWG 2% VWG + 0.3% GE

Rheology Test Results - General Whole Meal Bread White Bread Sample 86% flour + 14% bran 86% flour + 14% bran + 5% gluten 86% flour + 14% bran + 2% gluten + 0.3% enhancer Flour only 2.15% gluten 0.215% enhancer Moisture % 14.63 14.26 14.41 14.76 14.53 14.63 Wet gluten % 34.60 43.50 36.75 34.15 38.35 33.90 Dry gluten % 11.15 14.35 12.00 11.44 12.90 11.50 Gluten Index % 82 77 84 86 81 84 Protein (m.b.) % 12.05 15.12 13.24 11.92 13.19 11.89 Ash (m.b.) % 0.79 0.87 0.80 0.56 0.59 0.56 Falling Number s 418 425 461 397 408 423 Gluten enhancer replacer 10-fold quantity of vital wheat gluten Falling Number higher than with or without vital wheat gluten

TKP/LP03052011 Rheology Test Results - Farinograph Whole Meal Bread White Bread Sample Water Absorption (500 FU) 86% flour + 14% bran 86% flour + 14% bran + 5% gluten 86% flour + 14% bran + 2% gluten + 0.3% enhcr. Flour only 2.15% gluten 0.215% enhancer % 68.40 70.00 70.50 64.50 65.10 65.50 Development Time Min 7.8 9.4 8.0 10.7 10.8 9.3 Stability Min 8.1 10.8 9.2 15.1 16.5 15.5 Degree of Softening (ICC) Farinograph Quality Number BU 82.0 73.0 89.0 63 57.0 60.0 120 141 116 171 181 169 Increase of water absorption with gluten enhancer better than with gluten Stability better than for untreated flour, but Softening higher

TKP/LP03052011 Rheology Test Results - Extensograph Whole Meal Bread White Bread Sample Water Absorp. (500 FU) 86% flour + 14% bran 86% flour + 14% bran + 5% gluten 86% flour + 14% bran + 2% gluten + 0.3% enhcr. Flour only 2.15% gluten 0.215% enhancer % 64.0 65.3 66.1 62.1 62.4 62.8 Energy cm 2 92 113 100 162 168 171 121 148 118 128 140 132 155 163 149 135 141 111 Resistance BU 362 512 512 603 748 805 468 623 589 396 575 692 494 780 782 460 720 726 Extensibility mm 145 136 125 149 139 136 148 146 129 161 141 131 156 129 129 153 128 115 Maximum BU 454 624 624 808 963 1030 609 789 737 618 769 840 789 1029 953 686 916 778 Ratio 2.5 3.8 4.1 4.0 5.4 6.3 3.2 4.3 4.6 2.5 4.1 5.3 3.2 6.1 6.0 3.0 5.6 6.3 Ratio (Max) 3.1 4.6 5.0 5.4 6.9 7.6 4.1 5.4 5.7 3.8 5.5 6.4 5.1 8.0 7.4 4.5 7.2 6.8 Water absorption with gluten enhancer better than with gluten Effect of gluten enhancer on dough rheology weaker than that of gluten

TKP/LP03052011 Rheology Test Results - Amylograph Whole Meal Bread White Bread Sample Gelatinization onset Gelatinization temperature Gelatinization Maximum 86% flour + 14% bran 86% flour + 14% bran + 5% gluten 86% flour + 14% bran + 2% gluten + 0.3% enhcr. Flour only 2.15% gluten 0.215% enhancer o C 59.80 59.90 57.40 60 60.30 58.80 o C 88.30 88.60 87.00 87.4 88.10 88.90 AU 1042 1025 1253 738 763 957 Although the gelatinization starts earlier, the maximum viscosity is higher

LP03052011 Gluten Enhancer Benefits Dosage only 400 3,000 ppm Can replace 50% and more of added gluten Upgrades low protein flour Boosts vital wheat gluten function Does not interfere with standard flour treatment or bread improvers Improves rheological and baking properties Lable-friendly Safes up to 50% of the gluten costs

Powerzym S A New Bromate Replacing Compound

LP02092011 19 Optimizing Dough Stability The Solution Your challenge Wheat with weak properties occurring more often More stability required for weak flour Replacement of potassium bromate Cost control The solution Powerzym S has beneficial effects particularly on dough from weak flours Powerzym S creates a balance between stability and elasticity improves the machinability Powerzym S simplifies the flour improvement and it Achieves high volume yields

LP21092011 20 Powerzym S and its Competition in East Africa back: BX Local improver front: Powerzym S Local improver BX Powerzym S Wheat from Pakistan, FN 250 s, protein 11.5 %, wet gluten 26 %

SMA22042011 21 Powerzym S Simplified Treatment of Flour for Baguette Rolls Customer treatment 50 ppm ascorbic acid 30 ppm Oxem 23 30 ppm Gloxy 5080 100 ppm VC 5000 80 ppm H 19450 Customer treatment 300 ppm Powerzym S Powerzym S simplifies the treatment and improves the baking results

EMCEbest WA Plus - Increasing the Water Absorption

LP02092011 23 Water Absorption The Solution Your challenge More WA needed to meet the specifications of the customers to improve the shelf life Vital wheat gluten is expensive Guar gum impairs the baking performance and the taste The solution EMCEbest WA Plus increases the WA while maintaining the baking performance

Water absorption (%) LP02092011 Farinograph Water Absorption of EMCEbest WA Plus Comparison and Vital Wheat Gluten 70 Vienna Vienna 68 66 Bun T 1050 EMCEbest WA Plus Bun T 1050 64 62 EMCEvit C 60 58 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Dosage (%) Dosage: 0.1 1 % Effect: up to 6 % more water absorption

Resistance (BU) AWO03022010 EMCEbest WA Plus Farinograph Evaluation 600 500 400 300 200 100 0 Untreated EMCEbest WA Plus 0.5 % EMCEbest WA Plus 1 % EMCEvit C 3 % 0 5 10 15 20 25 30 Mixing time (min)

Recent Developments to Improve the Quality of Pasta and Noodles

Improving Pasta & Noodle Flour The Solution LP02092011 27 Your challenge Improvement of the noodle quality Replacing durum by hard wheat or hard by soft wheat The solution because of limited availabilty of durum wheat to reduce the costs while maintaining the noodle quality Pastazym improves the cooking & eating quality of noodles & pasta made from soft and hard wheat

KRU22042011 28 The Pastazym Family Has Grown Product name Principle Dosage* (ppm) Pastazym Enzymes 100-300 Pastazym Plus Enzymes 200-250 Pastazym BCT Enzymes, ß-carotene, tartrazine 200-400 Pastazym BCN Enzymes, natural beta carotene 200-300 Pastazym CUR Enzymes, natural curcumin 400-600 * Dosage depends on processing conditions and the quality of the flour Remarks: The use of colourants in pasta is not permitted in Europe. The food legislation needs to be checked for each country.

LP02092011 29 Properties of the Pastazym Family Property Pastazym Pastazym Plus Pastazym BCT Pastazym BCN Pastazym CUR Colour - + +++ ++ ++ Firmness ++ ++ ++ ++ ++ Stickiness ++ +++ ++ ++ ++ Cost reduction ++ +++ ++ ++ +

KRU22042011 30 Durum Colour for Soft Wheat Pasta Pastazym BCN Untreated soft wheat flour Pastazym CUR Pastazym BCT

Firmness (g) LP23092011 31 Firmness of Spaghetti from Durum or Soft Wheat Flour - Effect of Pastazym on Firmness 300 250 200 150 100 50 0 Durum Untreated +Pastazym, Soft +Pastazym 200 ppm Plus, +Pastazym 200 ppmcur, 500 ppm German Soft wheat; Texture Analyser XT2

USD / t LP/EMW23092011 32 Cost Reduction Potential of a Durum/Soft Wheat Mix with Pastazym 450 400 200 ppm Pastazym 350 300 250 200 0 20 40 60 80 100 Hard Wheat (%) Calculation based on Figures from July 2011 USD/bu USD/t /t Spring Wheat 7 257 184 Hard Red Winter 8 294 210 Durum 11 404 289

Source: Peter Cate, AGES Vienna From Grains Canada Courtesy of R. Kuhn (2010) 33 Further Challenges Addressed by MC www.uvm.edu/~entlab/sunnpest

Thank You for Your Attention! Mühlenchemie GmbH & Co. KG - a member of the Stern-Wywiol Group - Kurt-Fischer-Str. 55 22926 Ahrensburg, Germany +49 4102 202 001 www.muehlenchemie.de www.stern-wywiol-gruppe.de