Vodka intro 2nd most popular spirit worldwide representing 20% of the spirits market, after Soju/Shochu, but ahead of cachaca Smirnoff is the largest brand, selling 24m c/s a year HRS sold unaged, but not a uniform product flavours are delicate (in comparison to other spirits), with impact from different raw materials and production techniques history origins in Poland and Russia, then stretching to Scandinavia to form the Vodka Belt. But nowadays made everywhere eg Vladivar from Varrrington, now made in Scotland; Grey Goose in France historically mainly a flavoured spirit, which suited HRS, as more efficient flavour extraction and few complicating/competing congeners from the base materials; sold unaged by 17C Poles using charcoal filtering, and top Polish and Russian producers distilling 3 or 4 times to give purer spirit 19C continuous distillation introduced, greater control over spirit purity until mid-1940s popular only in Scandinavia and E.Europe 1950s took off in US, functional as a mixer 1980s vodka too off in US with arrival of Absolut - marketing message of modernity, purity, design, and premium values now - lucrative and cluttered marketplace for premium and super-premium brands; plus explosion in flavoured vodkas now - more different raw materials available regulations methanol < 10g/hl of pure spirit (EU); US TTB do not say anything at all about levels of methanol or aka methyl alcohol distillation strength is unspecified EU regs say vodka is a spirit distilled and/or rectified so that the organoleptic characteristics of the raw materials used and by-products formed in fermentation are selectively reduced, though this is achieved at a strength approaching 95.63% abv ie the azeotropic point of ethanol. WSET text states distillation to at least 96% abv - this is neither achievable nor required; it further states that US specifies minimum 95% abv, this is achievable, but not corroborated in government regulations. bottled abv min 37.5% (EU), min 40% (USA) additives in unflavoured vodka in EU product may be given special organoleptic characteristics, but not a predominant flavour, so small amounts of glycerol or sugar may be added for body/mouth-feel in USA, sugar < 2g/l may be added, assumedly for same purpose raw materials - a vodka made from materials other than potatoes or cereals must state that material on the label (EU); eg Ciroc label shows distilled from fine french grapes.
A note on maximum ethanol content achievable when a mixture of water and ethyl alcohol is distilled, ultimately a peak concentration is reached of 95.63% ethanol and 4.37% water - called an azeotrope. Why does it peak below 100%? Since alcohol has a lower boiling point than water it should boil off all the way to 100%, but at the azeotrope, the higher boiling point water, starts to boil off before the lower boiling point alcohol, which limits alcohol purity to 95.63%. producing vodka raw materials any agricultural materials can be used, limited to commercially viable crops barley, wheat, rye, maize potatoes grapes, produced in France, called Ciroc, made by Diageo; this caused a stir in the Vodka Belt who argued grapes were not traditional in vodka production, and should not be labelled as such, peace was brokered with labelling, as above ie Vodka distilled from grapes molasses, labelling as for grapes; eg Downunder Australian vodka made from molasses from their sugar industry raw material processing grains, if > 1, then processed separately milled to a flour or grist water added, heated to make starch solution (hydrolyse the starch) cool, add enzymes to convert starch to sugar, and produce sugar solution malted barley contains suitable enzymes, but expensive so use commercially produced ones potato peeled water added, heated to make starch solution (hydrolyse the starch) cool and add commercially produced enzymes to convert starch to sugar, and produce a sugar solution fermentation add yeast to sugar solution light character of vodka necessitates a yeast which engenders little flavour ie creates as few congeners as possible continuous fermentation large scale vodka production (by continuous distillation) requires huge volumes of alcoholic liquid, of which up to 90% is discarded; to service this requirement use continuous fermentation
Continuous fermentation eg Grey Goose ref http://www.alcademics.com/2012/10/how-grey-goose-ismade.html. uses a continuous fermentation process in a series of six cascading tanks, duration about 30 hours. Wheat-based sugar solution and yeast enters the first tank, which then pours into each successive tank operating at a different phase in the fermentation process. The sixth tank outputs a fully fermented liquid (aka beer) at 10% abv. New sugar solution and yeast are continually added to the first tank, and beer is constantly output from the sixth. distillation large scale production HRS can only be achieved in a column still large scale production processes huge volumes of alcoholic wash, which means continuous distillation is the only option 2-column continuous distillation can be used, but methanol level would not satisfy EU regs of max 10g/hl pure spirit; potato-based HRS shows a high methanol level methanol (and fusel oils) are congeners, so the relatively low EU limit for vodka is related to the production of a spirit with very light or neutral flavour profile; for reference, fruit spirits are limited to methanol 1000g/hl pure spirt, but London gin is even lower than vodka, at methanol 5g/hl pure spirit to satisfy EU limit, demthylising is carried out on almost all vodka produced in EU 5-column continuous distillation - this reduces both methanol (demethyliser) and fusel oils (hydroselector), and suits production of a particularly neutral style. Demethyliser and hydroselector The treatment of undesirable levels of fusel oils and methanol (aka methyl alcohol) in HRS, relies on their volatility with ethanol concentration. Fusel oils: these are handled by a process called hydroselection.. if HRS is reduced to 20% by dilution with water, then fusel oils more volatile. This is achieved in a hydroselector column steam introduced from the column base and hot water sprayed from above, HRS injected at mid-column height, fusel oils become more volatile, rise to top of column where collected. Water diluted spirt collected at bottom of column, redistilled to produce HRS. Methanol is most volatile in an HRS of 96% abv.. if HRS heated gently by an external source (steam or water would dilute), methanol is able to separate out over many plates, collecting at the top of the still, leaving purified HRS at the base. small scale production, 2 options use column still in batch mode
first, this is the start up process for a continuous still in normal mode alcoholic liquid heated, vapours rise through the still, head condenser causes reflux, initiating a downward flow of liquid spirit through the series of rectifier column plates, becoming successively more diluted, and hotter, as it descends through less alcohol rich vapour regions hot vapour rising, bubbles through the downflowed liquid pooling on each plate, heat transfer takes place as the most volatile elements vapourise and rise to the next plate, and the less volatile elements condense as liquid on the current plate. This process progresses sequentially up the column, helping separate the fractions into volatility levels according to plate position in the column, regulated by the temperature gradient in the column, most volatile at the coolest top plate ie methanol, and least volatile at the hottest bottom plate ie fusel oils. The higher the number of plates the more the spirit is stretched, the more rectified it becomes, that is higher in alcohol it becomes off the top of the still, and the more incisively can a desired intermediate distillate(s) be separated and output. it takes several hours of operation for a still to be brought to a balanced state, where it is continuously fed alcoholic liquid, and continuously outputs at various rectifier plate positions, heads, tails and any desired intermediate distillate(s). in batch mode, the only practical difference is that after some time of running the still in its balanced state, the spirit strength starts to drop away, at which time the distiller stops making spirit, and the process is switched to output tails, is subsequently shut down, and a cleaning cycle initiated. use of pot stills when producing vodka, pot stills can only be used to process HRS, which can only be produced by a column still, and which at 96% abv is very low in congeners to process HRS in a pot still, it is first diluted with water cuts are made as distiller chooses the impact on flavour is marginal as HRS is intrinsically low in congeners those using pot stills in this way consider that it smooths out the mouth-feel maturation and finishing ageing 99.9% vodka is unaged, a few aged examples exist eg
Adnams, UK, produce two US and French oak aged bottlings filtration charcoal when used, most effective type is active charcoal (aka activated carbon), used to remove all congeners Absolut (Sweden) and Finlandia (Finland) do not charcoal filter, believing this technology, first introduced in Poland in 17C is obsolete and redundant since modern processes produce a pure spirit. chill vodka is generally served chilled, unexpected haziness/ clouding could be perceived as a fault by the consumer. To eliminate the risk of this, most producers chill filter, in which any compounds causing hazing/clouding are forced to materialise and precipitate, spirit is then filtered/ racked of the residue Voli Vodka (USA) does not chill filter reduction to bottling strength EU min 37.5% abv; USA min 40% abv producers regard water purity as crucial to the style of vodka they produce, all will use high quality and high purity - explicitly, through the use of filtering, so personally I think this is simply marketing hype to add to the story other additions mouth feel/body can be adjusted by addition of small quantities of glycerol or sugar unflavoured vodka styles a distillate of 95.63% abv has congeners at levels undetectable by humans; so to differentiate between unflavoured vodkas, distillers must take different approaches - broadly characterised in neutral and characterful styles neutral a vodka with particularly light, but still discernible flavour(s) achieved by multi-column distillation including hydroselector and demtheyliser columns a style exemplarised by Smirnoff characterful, this retains some degree of contribution by the base material, ie congeners, which can be characterised wheat - slightly rich texture, sweetish mid-palate, dry, some say anise note rye - soft, clean spirit, citrus nose, palate sweet/oily/zesty/ spicy barley - potential to be lightest spirit, owing to low oil content
potato - can be full-bodied and creamy textured corn - soft and delicate, almost ethereal to increase differentiability, a distiller can either adjust the distillation process, or adjust the spirit, post-distillation, eg.. rectify to a lower strength to retain more congeners add lower strength spirit to the final blend, adds congeners add glycerol or sugar for mouthfeel/body age the spirit to add character, by rounding the spirit flavoured vodka styles unflavoured vodka can be flavoured with any number of botanicals, fruits, spices, using maceration, distillation and percolation, also cold compounding of nature identical flavours. traditional flavourings traditionally vodka was flavoured, to mitigate any impurity, palatability was improved using eg cherries, honey, rowan berries and many other fruits/spices; most important is Zubrowka flavoured with bison grass modern flavourings nowadays most brands have flavoured vodkas; anything goes, from lime and raspberry to vanilla and cinnamon, to pepper and chilli akvavit, a predominantly caraway flavoured spirit, is important in Scandinavia many made using nature identical flavourings and cold compounding premium styles more usually use natural flavourings EU regulations predominant flavour is other than that of the raw materials min 37.5% abv can be blended, sweetened, flavoured, coloured or matured if fruit macerated then distilled then the label must show fruit name vodka eg blood orange flavoured vodka regions and brands vodka now made everywhere vodka made with dry ingredients, so can be sourced from anywhere this means country/region of production now conveys little about style or quality what is important now is brand, positioning, packaging, marketing hype - how a vodka is perceived dictates the price it can command from inexpensive - standard - premium - super premium
Last update 19NOV15