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ACS Webinars We will start momentarily at 2pm ET Download slides: http://acswebinars.org/bamforth Contact ACS Webinars at acswebinars@acs.org Upcoming ACS Webinars www.acswebinars.org/events Thursday, September 2, 2010, 2-3 p.m. EDT Programs and Funding Opportunities for Manufacturers and Small Chemical Businesses Doug Devereaux, Senior Industrial Specialist, National Institute of Standards and Technology. Thursday, September 9, 2010, 2-3 p.m. EDT How Scientific Skills Are Used in Advising the Movie Industry Facts and Fiction Dr. Barry Byrne, Associate Chair and Professor, University of Florida. 1

Have Questions? Please use the Question Panel to ask the speaker Or tweet us using #acswebinars Download slides: http://acswebinars.org/bamforth ACS WEBINARS August 26, 2010 Tapping into the Chemistry of Beer and Brewing Speaker: Charles Bamforth, Ph.D., D.Sc. University of California, Davis Moderator: Steven Carlo, Ph.D. Chemist, Home Brewer Please submit your questions for the speaker via the Questions Panel in GoToWebinar Slides download at: http://acswebinars.org/bamforth Contact ACS Webinars at acswebinars@acs.org 2

Tapping into the Chemistry of Beer and Brewing Charlie Bamforth ACS Webinar August 26 2010 5 6 3

Barley Malt Wort Green Beer Malting mashing fermentation stabilization Beer filtration 7 Light Caramel malt Munich malt Dark Caramel malt Pale malt Specially Processed malt (kilned and roasted) Wheat malt Chocolate malt Roast barley 8 4

Resins Oils 9 Saccharomyces cerevisiae Saccharomyces pastorianus 10 5

11 12 6

hoppiness Lagers Pilsner Marzen Bock Doppelbock American lager American light Helles Dunkel subtler, refreshing heavier, fuller, maltier 13 hoppiness Ales American pale ale India pale ale Imperial stout Barley wine English pale ale Porter Scottish ale Stout Hefeweissen English mild/brown Weisse Sweet stout subtler, refreshing heavier, fuller, maltier 14 7

Hefeweissen 15 Enterobacteria Kloeckera apiculata Saccharomyces cerevisiae S. pastorianus S. bayanus S. globosus S. dairensis Pedicococcus damnosus P. cerevisiae Lactobacillus Brettanomyces lambicus B. bruxellensis. Candida Hansenula Pichia Lambic 16 8

17 Brettanomyces.if used properly with care, it can add rich aromas and flavors of earthiness, leather, smoke, barnyard, & our favorite descriptor - wet dog in a phone booth. 18 9

19 rho tetra hexa 20 10

Flavor compounds produced by yeast -Esters - Alcohols -Acids - Vicinal diketones - Sulfur compounds - Acetaldehyde - Short-chain fatty acids 21 Carbonyls e.g. E-2-nonenal 22 11

Carbon Dioxide - 1-3 volumes - Sparkle - Volatile delivery - Tingle - Foam 23 Nitrogen - Foam (10-50 mg. L -1 ) - Suppression of hoppy character 24 12

Oxygen - Staling -Haze 25 Ethanol - 3-6% ABV mostly - Direct effect on flavor - Indirect effect on flavor - Foaming - surface tension, inhibition - Effect on health 26 13

27 But beer can make a significant contribution to dietary intake Parameter Daily adult (age 25-50) requirement Range in beer (per litre) Male Female Energy (Kcal) 2550 1940 150-1100 Protein (g) 63 50 3-5 Carbohydrate (g) a a 0-61 Fat (g) a a Neg. Vitamin A (μg) 1000 800 Neg. Vitamin D (μg) 5 5 Neg. Vitamin E (mg) 10 8 Neg. Vitamin K (μg) 80 65 Neg. Vitamin C (mg) 60 60 Up to 30 Thiamine (mg) 1.5 1.1 0.003-0.08 Riboflavin (mg) 1.7 1.3 0.02-0.8 Niacin (mg) 19 15 3-8 Vitamin B 6 (mg) 2.0 1.6 0.07-1.7 Folate (μg) 200 180 40-600 Vitamin B 12 (μg) 2 2 3-30 Biotin (μg) 30-100 20-100 2-15 Calcium (mg) 800 800 40-140 Phosphorus (mg) 800 800 90-400 Magnesium (mg) 350 280 60-200 Potassium (mg) 330-1100 Sodium (mg) 40-230 Iron (mg) 10 15 0.1-0.5 Zinc (mg) 15 12 0.01-1.48 Selenium (μg) 70 55 <0.4-7.2 ] The importance of beer as part of a wellbalanced diet Silicon 28 14

Proteins Amphipathic polypeptides - foam Lipids Foam inhibitory Staling 29 cwbamforth@ucdavis.edu 30 15

Q&A SESSION Tapping into the Chemistry of Beer and Brewing Speaker: Charles Bamforth, Ph.D., D.Sc. University of California, Davis Moderator: Steven Carlo, Ph.D. Chemist, Home Brewer Please submit your questions for the speaker via the Questions Panel in GoToWebinar Slides download at: http://acswebinars.org/bamforth Contact ACS Webinars at acswebinars@acs.org More Questions? ACS Webinars Post-Event Discussion Board https://communities.acs.org/groups/acswebinars 16

Upcoming ACS Webinars www.acswebinars.org/events Thursday, September 2, 2010, 2-3 p.m. EDT Programs and Funding Opportunities for Manufacturers and Small Chemical Businesses Doug Devereaux, Senior Industrial Specialist, National Institute of Standards and Technology. Thursday, September 9, 2010, 2-3 p.m. EDT How Scientific Skills Are Used in Advising the Movie Industry Facts and Fiction Dr. Barry Byrne, Associate Chair and Professor, University of Florida. ACS Webinars does not endorse any products or services. The views expressed in this presentation are those of the presenter and do not necessarily reflect the views or policies of the American Chemical Society. 17