Date : December 1, 2016 SAMPLE IDENTIFICATION Internal code : 16K24-TOB4-1-DM Customer identification : Helichrysum Type : Essential oil Source : Helichrysum italicum Customer : Real Oil LLC ANALYSIS Method : PC-PA-001-15E06, "Analysis of the composition of a liquid essential oil by GC-FID" (in French). Analyst : Sylvain Mercier, M. Sc., chimiste Analysis date : 2016-11-30 Checked and approved by : Alexis St-Gelais, M. Sc., chimiste 2013-174 Note: This report is digitally signed, it is only considered valid if the digital signature is intact. Page 1 of 6
IDENTIFIED COMPOUNDS Identification Column: BP5 Column: WAX R.T. R.I. % % R.I. R.T. Molecular Class 2-Methylbutyral 0.57 582 tr tr 763 0.47 Aliphatic aldehyde 2-Methyl-3-pentanone 1.15 730 0.07 0.08 896 0.68 Aliphatic ketone 2,4-Dimethyl-3-pentanone 1.54 784 0.07 Aliphatic ketone 4-Methyl-3-hexanone 2.08 833 0.21 0.22 999 1.08 Aliphatic ketone Tricyclene 3.17 913 0.05 0.05 921 0.76 Monoterpene α-thujene 3.26 919 0.25 0.84 953 0.89 Monoterpene α-pinene 3.43 929 26.87 27.75 951 0.88 Monoterpene α-fenchene 3.63 941 0.40 0.37 980 1.00 Monoterpene Camphene 3.65 942 0.34 0.32 990 1.05 Monoterpene Thuja-2,4(10)-diene 3.74 948 0.02 0.13 1050 1.45* Monoterpene Sabinene 4.08 968 0.13 [0.13] 1050 1.45* Monoterpene β-pinene 4.14 972 0.58 0.55 1034 1.32 Monoterpene Myrcene 4.42 989 0.36 0.38 1109 1.92 Monoterpene trans-dehydroxylinalool 4.47 992 0.01 0.01 1167 2.58 Monoterp. ether oxide 6-Methyl-5-hepten-2-one 4.51 994 0.01 0.02 1290 4.18 Aliphatic ketone Δ3-Carene 4.73* 1007 9.14 9.40 1088 1.75 Monoterpene α-phellandrene 4.73* 1007 [9.14] 0.16 1101 1.86 Monoterpene α-terpinene 4.88 1015 0.17 0.20 1117 2.00 Monoterpene Limonene 5.13* 1029 3.96 3.47 1136 2.23 Monoterpene para-cymene 5.13* 1029 [3.96] 0.37 1199 2.96 Monoterpene β-phellandrene 5.15 1030 0.09 0.44 1139 2.26* Monoterpene 1,8-Cineole 5.17 1031 0.20 [0.44] 1139 2.26* Monoterp. ether cis-β-ocimene 5.29 1038 0.01 0.41 1180 2.74* Monoterpene trans-β-ocimene 5.47 1048 0.05 0.04 1194 2.90 Monoterpene Isobutyl angelate 5.59 1054 0.27 0.39 1230 3.35* Aliphatic ester γ-terpinene 5.65 1058 0.40 [0.41] 1180 2.74* Monoterpene Terpinolene 6.13 1083 0.89 0.89 1218 3.18 Monoterpene para-cymenene 6.34 1095 0.02 0.02 1360 5.18 Monoterpene 2,4-Dimethyl-heptane-3,5- dione 6.49 1101 0.06 0.06 1460 6.80 Aliphatic ketone 2-Methylbutyl 2- methylbutyrate 6.54 1103 0.11 [0.39] 1230 3.35* Aliphatic ester Linalool 6.66 1107 0.58 0.96 1482 7.21 Monoterp. alcohol Nonanal 6.70 1109 0.06 0.07 1332 4.77 Aliphatic aldehyde trans-pinocarveol 7.56 1141 0.04 0.05 1554 8.95 Monoterp. alcohol Camphor 7.66 1145 0.08 0.16 1416 5.98 Monoterp. ketone Isoamyl angelate 7.78 1149 1.03 1.02 1337 4.84 Aliphatic ester Borneol 8.58 1179 0.08 0.09 1605 10.46 Monoterp. alcohol Terpinen-4-ol 8.69 1183 0.17 0.37 1527 8.14* Monoterp. alcohol Page 2 of 6
Dimethyl octanedione 8.77 1186 0.28 [0.37] 1527 8.14* β-diketone isomer 4,6-Dimethyl-3,5-8.83 1188 0.29 0.83 1529 8.18* β-diketone octanedione α-terpineol 9.37 1204 0.26 0.53 1616 10.76* Monoterp. alcohol Unknown (m/z = 81, 168 10.27 1224 0.24 (53), 67 (49), 140 (47), 41 (44)) Nerol 10.56 1231 0.79 1.89 1721 15.23* Monoterp. alcohol Neral 11.18 1244 0.10 1.24 1596 10.16* Monoterp. aldehyde cis-isogeraniol 11.41 1250 0.08 0.08 1733 15.80 Monoterp. alcohol Hexyl angelate 13.05 1286 0.30 0.44 1611 10.60* Aliphatic ester α-ylangene 16.84* 1347 0.27 0.16 1408 5.88 Sesquiterpene α-terpinyl acetate 16.84* 1347 [0.27] [0.44] 1611 10.60* Monoterp. ester 2,6-Dimethyl-1,7- octadiene-3,6-diol 16.95 1348 0.13 0.12 1999 32.33 Monoterp. alcohol Isoitalicene 17.47* 1356 2.22 2.38 1434 6.32 Sesquiterpene α-copaene 17.47* 1356 [2.22] 0.39 1425 6.15 Sesquiterpene Neryl acetate 17.91 1363 7.55 8.04 1657 12.46* Monoterp. ester Geranyl acetate 19.16 1382 0.14 0.11 1704 14.49 Monoterp. ester Italicene 19.45 1387 3.37 3.62 1473 7.06 Sesquiterpene β-caryophyllene 20.41* 1400 3.60 3.12 1523 8.02 Sesquiterpene cis-α-bergamotene 20.41* 1400 [3.60] 0.78 1512 7.77 Sesquiterpene Aromadendrene 21.87 1418 0.66 [0.83] 1529 8.18* Sesquiterpene trans-α-bergamotene 22.25 1422 0.11 0.08 1535 8.34 Sesquiterpene Italidione I 23.04* 1432 1.36 1.73 1800 19.65 β-diketone α-humulene 23.04* 1432 [1.36] 0.33 1586 9.87 Sesquiterpene trans-β-farnesene 23.85 1442 0.36 [0.53] 1616 10.76* Sesquiterpene α-acoradiene 24.21 1446 0.49 0.35 1579 9.68 Sesquiterpene γ-selinene 24.58 1451 0.99 [1.24] 1596 10.16* Sesquiterpene Neryl propionate 24.82 1454 0.89 [1.89] 1721 15.23* Monoterp. ester Germacrene D 25.15 1458 0.18 [0.44] 1611 10.60* Sesquiterpene α-amorphene 25.47 1461 0.26 [1.24] 1596 10.16* Sesquiterpene γ-curcumene 26.10 1469 12.16 10.96 1632 11.36 Sesquiterpene β-selinene 26.19 1470 1.40 2.50 1635 11.45 Sesquiterpene Italidione isomer 26.36 1471 0.76 0.25 1816 20.64 β-diketone α-selinene 26.52 1473 1.84 2.37 1640 11.67 Sesquiterpene ar-curcumene 26.75* 1476 3.23 2.06 1693 14.01* Sesquiterpene Italidione II 26.75* 1476 [3.23] 0.33 1805 19.99 β-diketone α-muurolene 27.35 1483 0.26 0.20 1648 12.04 Sesquiterpene δ-amorphene 27.49 1485 0.19 0.23 1641 11.72 Sesquiterpene γ-cadinene 28.36 1496 0.38 [8.04] 1657 12.46* Sesquiterpene β-curcumene 28.64* 1499 0.90 0.59 1668 12.92 Sesquiterpene Italidione II isomer 28.64* 1499 [0.90] β-diketone Page 3 of 6
δ-cadinene 29.03 1505 0.64 0.59 1673 13.12* Sesquiterpene trans-cadina-1,4-diene 29.38 1510 0.03 0.04 1700 14.32 Sesquiterpene trans-γ-bisabolene 29.87 1516 0.14 [0.59] 1673 13.12* Sesquiterpene β-sesquiphellandrene 30.20 1521 0.17 [2.06] 1693 14.01* Sesquiterpene Italicene ether 31.90 1544 0.12 Sesquiterp. ether Italidione III 33.56 1567 0.26 β-diketone Italidione III isomer 33.90 1571 0.18 β-diketone Italidione III isomer II 33.99 1573 0.17 β-diketone Italidione III isomer III 34.30 1577 0.12 β-diketone Italidione III isomer IV 34.79 1584 0.10 β-diketone Guaiol 35.18 1589 0.13 0.11 2003 32.55 Sesquiterp. alcohol Rosifoliol 35.39 1592 0.03 0.03 1945 29.14 Sesquiterp. alcohol Rosifoliol analog? 35.67 1597 0.29 0.31 2015 33.26 Sesquiterp. alcohol Neryl angelate? 36.81 1624 0.21 Monoterp. ester τ-cadinol 37.35 1637 0.04 0.04 2084 36.36 Sesquiterp. alcohol β-eudesmol 37.72 1646 0.16 0.17 2108 37.16 Sesquiterp. alcohol Selin-11-en-4-α-ol 37.90 1651 0.19 0.16 2129 37.90 Sesquiterp. alcohol Total identified 95.56% 96.45% *: Two or more compounds are coeluting on this column [xx]: Duplicate percentage due to coelutions, not taken account in the identified total Note: no correction factor was applied OTHER DATA Physical aspect : Faintly yellow liquid Refractive index : 1.4750 ± 0.0003 (20 C) CONCLUSION No adulterant, contaminant or diluent were detected using this method. Page 4 of 6
Page 5 of 6
Page 6 of 6