SECTION 1: PRODUCT IDENTIFICATION SECTION 2: HAZARDS IDENTIFICATION
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1 SECTION 1: PRODUCT IDENTIFICATION PRODUCT NAME PRODUCT CODE SUPPLIER EMERGENCY PHONE USES FLEXIBLE COLLODION, USP 0625 MEDISCA Inc. Tel.: Fax.: Route 3, Unit C, Plattsburgh, NY, W. Mesa Vista Ave., Unit A-10, Las Vegas, NV, N. Belt Line Road, Suite 130, Irving, TX, MEDISCA Pharmaceutique Inc. Tel.: Fax.: Rue Dobrin, St. Laurent, QC, H4R 2L Gordon Way, Unit 153/158, Richmond, BC V6W 1M2 MEDISCA Australia PTY LTD Tel.: Fax.: Unit 7, Heritage Business Park 5-9 Ricketty Street, Mascot, NSW 2020 CHEMTREC Day or Night Within USA and Canada: NSW Poisons Information Centre: Dermatological Substance SECTION 2: HAZARDS IDENTIFICATION GHS CLASSIFICATION PICTOGRAM Flammable Liquid (Category 2) Eye Irritation (Category 2A) Specific Target Organ Toxicity - Single Exposure (Category 3) - narcotic effects Specific Target Organ Toxicity - Repeated Exposure (Category 2) - blood, kidneys and nervous system Acute Toxicity - Oral (Category 4) SIGNAL WORD HAZARD STATEMENT(S) AUSTRALIA-ONLY HAZARDS Danger Highly flammable liquid and vapor. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure: vapors and prolonged absorption through skin could cause damage to blood, kidneys and nervous system. Harmful if swallowed. Repeated exposure may cause skin dryness or cracking. FLEXIBLE COLLODION, USP Page 1 of 9
2 PRECAUTIONARY STATEMENT(S) Prevention Response Storage Disposal Keep away from heat, sparks, open flames and hot surfaces. No smoking. Keep container tightly closed. Ground container and receiving equipment. Use explosion-proof equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing, eye protection, face protection. Wash thoroughly after handling. Do not breathe dust/fume/gas/mist/ vapors/spray. Use only outdoors or in a well-ventilated area. Do not eat, drink or smoke when using this product. IN CASE OF FIRE: Use dry chemical, CO2, alcohol resistant foam. IF ON SKIN OR HAIR: Take off immediately all contaminated clothing. Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF EYE IRRITATION PERSISTS: Get medical advice/attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel unwell. IF SWALLOWED: Call a poison center or doctor if you feel unwell. Rinse mouth. IF EXPOSED OR CONCERNED: Get medical advice/attention. Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Dispose of contents and container in accordance with local regulations. HMIS CLASSIFICATION Health Hazard 2 Flammability 4 Reactivity 0 Personal Protection G SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL NAME BOTANICAL NAME SYNONYM CHEMICAL FORMULA CAS NUMBER ALTERNATE CAS NUMBER MOLECULAR WEIGHT COMPOSITION CHEMICAL NAME CAS NUMBER % BY WEIGHT ETHER ~ 65 ETHANOL ~ 25 CAMPHOR ~ 2 CASTOR OIL ~ 3 PYROXYLIN ~ 5 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as health hazards and hence require reporting in this section. FLEXIBLE COLLODION, USP Page 2 of 9
3 SECTION 4: FIRST-AID MEASURES IN CASE OF EYE CONTACT IN CASE OF SKIN CONTACT IF SWALLOWED IF INHALED SYMPTOMS AND EFFECTS Irrigate immediately. Flush with copious amounts of water for 15 minutes, separating eyelids with fingers. If irritation persists seek medical aid. Remove contaminated clothes. Wash promptly with soap & water for 15 minutes. If irritation persists seek medical aid. Medical attention immediately. Wash out mouth with water. Do not induce vomiting without medical advice. Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Refer for medical attention. Not expected to present a significant hazard under anticipated conditions of normal use. SECTION 5: FIREFIGHTING MEASURES SPECIFIC HAZARDS ARISING FROM THE CHEMICAL FLAMMABLE PROPERTIES HAZARDOUS COMBUSTION PRODUCTS EXTINGUISHING MEDIA PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. Highly flammable: will be easily ignited by heat, sparks or flames. Under fire conditions, hazardous fumes will be present. Small fire: dry chemical, CO₂. Large fire: dry chemical, CO₂, alcohol resistant foam. Do not get water inside containers. Do not use water jet or water-based fire extinguishers. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. SECTION 6: ACCIDENTAL EASE MEASURES PERSONAL PRECAUTIONS METHODS & MATERIAL FOR CONTAINMENT CLEANUP PROCEDURE Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. On land, sweep or shovel into suitable containers. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Wear respirator, chemical safety goggles, rubber boots and heavy rubber gloves. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Shut off all sources of ignition. Evacuate the area. If necessary, employ water fog to disperse the vapors. Absorb the matter with compatible vermiculite or other absorbing material. Place in a suitable container and retain for disposal. Ventilate and clean the affected area. Do not flush into sewerage system or to drains. SECTION 7: HANDLING AND STORAGE PRECAUTIONS FOR SAFE HANDLING Do not inhale. Avoid contact with eyes, skin and clothing. Avoid prolonged or repeated exposure. Wash thoroughly after handling. FLEXIBLE COLLODION, USP Page 3 of 9
4 STORAGE CONDITIONS Store in original container, tightly sealed container, protected from direct sunlight, in a dry, cool and well-ventilated area, away from incompatible materials. Store in accordance with local regulations. Eliminate all ignition sources. Separate from oxidizing materials. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. Preserve in tight containers, at a temperature not exceeding 30 C, remote from fire. SECTION 8: EXPOSURE CONTROLS/ PERSONAL PROTECTION Chemical Name: CAMPHOR CAS #: OSHA PEL 2 mg/m³ N/L ACGIH TLV 2 ppm N/L 3 ppm NIOSH 2 mg/m³ N/L N/L N/L 200 mg/m³ - Safe Work Australia HSIS 2ppm N/L 3ppm HSE N/L N/L N/L Chemical Name: CASTOR OIL CAS #: OSHA PEL N/L N/L ACGIH TLV N/L N/L N/L NIOSH N/L N/L N/L N/L N/L - Safe Work Australia HSIS N/L N/L N/L HSE N/L N/L N/L Chemical Name: ETHANOL CAS #: OSHA PEL 1000 ppm (1900 mg/m³) N/L ACGIH TLV N/L N/L N/L NIOSH 1000 ppm (1900 mg/m³) N/L N/L 1000 ppm (1900 mg/m³) 3300 ppm 10%LEL (See:64175) Safe Work Australia HSIS HSE 1000 ppm (1880 mg/m³) 1000 ppm (1920 mg/m³) N/L N/L N/L N/L FLEXIBLE COLLODION, USP Page 4 of 9
5 Chemical Name: ETHER CAS #: OSHA PEL 400 mg/m³; 1200 mg/m³ N/L ACGIH TLV 400 ppm N/L 500 ppm NIOSH 400 mg/m³; 1200 mg/m³ N/L N/L N/L 1900 ppm 10% LEL (See:60297) Safe Work Australia HSIS 400 mg/m³; 1200 mg/m³ HSE 100 ppm; 310 mg/m³ Chemical Name: PYROXYLIN CAS #: N/L 500 ppm; 1520 mg/m³ N/L 200 ppm; 620 mg/m³ OSHA PEL N/L N/L ACGIH TLV N/L N/L N/L NIOSH N/L N/L N/L N/L N/L - Safe Work Australia HSIS N/L N/L N/L HSE N/L N/L N/L N/L = Not Listed EXPOSURE GUIDELINES PERSONAL PROTECTIVE EQUIPMENT SPECIFIC ENGINEERING CONTROLS Consult local authorities for provincial or state exposure limits.particulates not otherwise regulated, respirable fraction: 5 mg/m³ Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by WHMIS or OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: Follow WHMIS or OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Adequate mechanical ventilation. Fumehood, eye wash station, and safety shower. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE DESCRIPTION SOLUBILITY ODOR FLAMMABILITY Liquid Clear, or slightly opalescent, viscous liquid. Is colorless or slightly yellow, and has the odor of ether. The strong odor of camphor becomes noticeable as the ether evaporates Slightly soluble in water. Odor of ether/alcohol Highly flammable ODOR THRESHOLD ph MELTING POINT BOILING POINT C, 97 F FREEZING POINT FLASH POINT -45 C, -49 F (closed cup) FLEXIBLE COLLODION, USP Page 5 of 9
6 SPECIFIC GRAVITY EVAPORATION RATE < 1 EXPLOSIVE LIMIT UPPER FLAMMABLE/ EXPLOSIVE LIMIT(S) 36 % LOWER FLAMMABLE/ 0.6 % VAPOR PRESSURE EXPLOSIVE LIMIT(S) VAPOR DENSITY (AIR = 1) >1 ATIVE DENSITY log P (WATER = 1) (OCTANOL-WATER) AUTO-IGNITION TEMPERATURE DECOMPOSITION TEMPERATURE VISCOSITY SECTION 10: STABILITY AND REACTIVITY REACTIVITY STABILITY MATERIALS TO AVOID HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION POSSIBLITY OF HAZARDOUS REACTION CONDITIONS TO AVOID Not established Stable under recommended storage conditions Strong oxidants, acids, bases, amines, halogens, interhalogens, sulfur and sulfur compounds. Contains 65% ether that can form explosive peroxides under the influence of light and air. Reacts violently with halogens, interhalogens, sulfur compounds and oxidants. This generates fire and explosion hazard. Attacks plastics and rubber. Toxic fumes of carbon monoxide, carbon dioxide, nitrogen oxides and other gases may occur Will not occur Not established Heat, sparks, flames and other sources of ignition. Avoid allowing unmodified resin to become dry. SECTION 11: TOXICOLOGICAL INFORMATION ACUTE TOXICITY SKIN CORROSION/IRRITATION SERIOUS EYE DAMAGE/EYE IRRITATION RESPIRATORY OR SKIN SENSITIZATION GERM CELL MUTAGENICITY CARCINOGENICITY ATE of mixture (calculated): Oral: Rat: LD50: (mg/kg): 1711 Dermal: Rabbit LD50: (mg/kg): 2136 Inhalation: Rat: LD50: (ppm/4hr): Contains camphor, collodion, ethanol and ether; all very irritating compounds. ETHER: Narcosis (HE8) Irritation-Eye, Nose, Throat, Skin ---Mild (HE16) Contains camphor, collodion, ethanol and ether; all very irritating compounds. ETHER: Narcosis (HE8) Irritation-Eye, Nose, Throat, Skin ---Mild (HE16) Due to lack of data the classification is not possible. OSHA NTP IARC California Proposition 65 No component of this product, present at 0.1%, is listed. No component of this product, present at 0.1%, is listed. No component of this product, present at 0.1% has been evaluated. No component of this product, present at 0.1% is known to the State of California to cause cancer, birth defects, or any other reproductive harm. FLEXIBLE COLLODION, USP Page 6 of 9
7 ADDITIONAL CARCINOGENICITY INFORMATION REPRODUCTIVE TOXICITY SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE ASPIRATION HAZARDS SIGNS AND SYMPTOMS OF EXPOSURE Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. Prolonged exposure to vapors in concentrations in excess of TLV can cause damage to kidneys, blood and nervous system. Health Hazards (acute and chronic): Vapors irritating to eyes, nose and throat. Liquid irritating to eyes and skin. Prolonged and repeated exposure to vapor concentrations in excess of TLV or through prolonged absorption through skin may cause. Main side effect of collodion is the ethyl ether fumes. Once the collodion has cured, there are no other vapors. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. POTENTIAL HEALTH EFFECTS Inhalation Ingestion Skin Eyes May be harmful if inhaled. May cause respiratory tract irritation. Harmful if swallowed. Ingestion health risks and sympoms of exposure: Headache, lethargy, drowsiness, weakness, difficulty walking, personality change, poor appetite, nausea and weight loss. May be harmful if absorbed through skin. May cause skin irritation. No known significant effects or critical hazards. Causes serious eye irritation. SECTION 12: ECOLOGICAL INFORMATION TOXICITY PERSISTENCE AND DEGRADABILITY BIOACCUMULATIVE POTENTIAL MOBILITY IN SOIL OTHER ADVERSE EFFECTS EC50: 48 Hr: Crustacea: (mg/l): LC50: 96 Hr: Fish: (mg/l): IC50: 72 Hr: Algae: (mg/l): Slightly soluble in water. This product is not intended to be released into the environment SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL Dispose of in accordance with federal / local laws and regulations. Avoid release into the environment. SECTION 14: TRANSPORT INFORMATION UNITED STATES & CANADA UN PROPER SHIPPING NAME UN NUMBER CLASS NITROCELLULOSE SOLUTION, FLAMMABLE FLEXIBLE COLLODION, USP Page 7 of 9
8 PACKING GROUP II AUSTRALIA UN PROPER SHIPPING NAME UN NUMBER CLASS PACKING GROUP HAZCHEM NITROCELLULOSE SOLUTION, FLAMMABLE II 2Y, 2YE ENVIRONMENTAL HAZARDS SPECIAL SHIPPING INFORMATION SECTION 15: REGULATORY INFORMATION Chemical Name & CAS ETHER, ETHANOL, PYROXYLIN, CAMPHOR, CASTOR OIL, N/L = Not Listed; X = Listed CERCLA 40 CFR Part SARA (Title III) 40 CFR Part EPA 40 CFR Part 355 Appendix A Appendix B Pennsylvania Right-to-know New Jersey Massachusetts California Prop 65 X N/L N/L N/L X X X N/L N/L N/L N/L N/L X X X N/L N/L N/L N/L N/L X X X N/L N/L N/L N/L N/L X X X N/L N/L N/L N/L N/L N/L N/L N/L N/L AUSTRALIAN REGULATIONS Chemical Name & CAS Poisons and Therapeutic Goods Regulation Therapeutic Goods Act Code of Practices - Illicit Drug Precursors ETHER, N/L Listed as Schedule 2 Listed as Category III ETHANOL, N/L N/L Listed as Category III PYROXYLIN, N/L N/L N/L CAMPHOR, N/L Listed as Schedule 6 N/L CASTOR OIL, N/L Listed as Schedule 6 N/L SECTION 16: OTHER INFORMATION REFERENCES Available upon request FLEXIBLE COLLODION, USP Page 8 of 9
9 ABBREVIATIONS AND ACRONYMS CAS Chemical Abstract Service; GHS Global Harmonized System; OSHA PEL Occupational Safety & Health Administration Permissible Exposure Limits; Time Weighted Average; HSIS Hazardous Substances Information System; Short Term Exposure Limit; AIHA WEEL American Industrial Hygiene Association Workplace Environment Exposure Levels; LD50 Lethal Dose, 50%; IARC International Agency for Research on Cancer; NTP National Toxicology Program; WHMIS Workplace Hazardous Materials Information System; SARA Superfund Amendments and Reauthorization Act; EPA Environmental Protection Agency; CERCLA Comprehensive Environmental Response, Compensation, and Liability Act; HMIS Hazardous Materials Information System; NIOSH National Institute for Occupational Safety and Health; MSHA - Mine Safety and Health Administration; ACGIH - American Conference of Governmental Industrial Hygienists; IDHL - Immediately Dangerous to Health or Life; TLV Threshold Limit Value; HSE Health and Safety Executive; - Recommended Exposure Limit LAST REVISION SUPERSEDES 09/ /2015 DISCLAIMER This document was created in accordance with OSHA, Safe Work Australia and WHMIS regulations. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. MEDISCA shall not be held liable for any damage resulting from handling or from contact with the above product. Recipients of the product must take responsibility for observing existing laws and regulations. FLEXIBLE COLLODION, USP Page 9 of 9
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