West Basin Seawater Barrier Conservation Project
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1 West Basin Seawater Barrier Conservation Project Permitting and Regulating Process SCAP January 22, 2008 Uzi Daniel, M.S. REM West Basin Sr. Environmental Quality Specialist
2 Status of Water Reuse in the U.S. Estimate: 2.6 billion gallons per day recycled nationwide in % Reclaimed Over 1,500 water reuse facilities in U.S. Approximately 8% of municipal wastewater effluent in the U.S. is reclaimed About 32 bgd Municipal Effluent in the U.S. *Source WateReuse
3 West Basin Recycled Water Plant EC Little Water Recycling Plant El Segundo, CA - Completed in 1995 Source: LA City Hyperion Treatment Plant Sold to various customers 5 Qualities of Water Designer Water Plant Capacity of nearly 60 MGD WATER PORTFOLIO APPROACH
4 Barrier Permit Schedule WDR Barrier Permit Issued January 2006 First Quarterly Compliance Sample Feb 2006 UV Ready March 2006 Brine Permit Issued August 2006 Began Consistent 75% Injection November 2006
5 Regulating Authority over California Groundwater Injection Projects California Department of Public Health Regional Water Quality Control Board Air Quality Management District Lead Agency for CEQA Fire Department Local City or County Permits and Utilities
6 California Department of Public Health (DPH) AUTORITY: Title 22, Article 5.1, section of State Code Expert Panel Public Hearing Facts and Findings Letter of Recommendation
7 Regional Water Quality Control Board AUTORITY: Federal Clean Water Act & Porter-Cologne Act Waste Discharge Requirement (WDR) Engineering Report Report of Waste Discharge Requirement (ROWD) Brine Permit Report of Waste Discharge Requirement (ROWD)
8 Others AQMD - AUTORITY: Lewis AUTORITY: Lewis-Presley Air Quality Management Act & Health and Safety Code Lead Agency CEQA - Authority: Public Resources Code & 14 California Code of Regulations Local Municipalities and Utilities - AUTORITY: City or County Codes and Resource Guidelines
9 BARRIER TREATMENT PROCESS To Title 22 Processes Microfiltration (Pressure) Sodium Bisulfite Sulfuric Acid scale inhibitor To Chevron RO Trains Reverse Osmosis Train 3 strainers NaOCl To Washwater Equalization NaOCl MF Clear Well cartridge filters brine Hydrogen Peroxide Ultra-Violet Saturated Lime Soln decarbonators TO WEST COAST BASIN BARRIER PROJECT NaOCl Microfiltration (Submerged) cartridge filters Reverse Osmosis Trains 1, 2, 9 strainers Storage Basin HYPERION PLANT PUMP STATION To Washwater Equalization Sulfuric Acid scale Inhibitor brine TO HYPERION 5-MILE OUTFALL
10 Microfiltration Capacity: 14.7 mgd Fiber Material: Polypropylene Integrity Monitoring: Pressure decay test Turbidity of Effluent: <0.2 Silt Density Index of Effluent: <2
11 Reverse Osmosis Capacity: 12.5 mgd Membrane Type: Polyamide Thin Film Composite Class of Membrane: Low pressure / High rejection Recovery: 85% Integrity Monitoring: Online conductivity Conductivity profiles
12 Advanced Oxidation Process Log virus removal: 12 Log NDMA removal: 1.2 Hydrogen Peroxide Dose: 3 mg/l Integrity Monitoring: Intensity meter Individual lamp status Ballast status
13 Expert Panel Recommendations The panel unanimously supports West Basin MWD proposal to increase the percentage of recycled water delivered to the seawater barrier from 50% to 100% provided: Increase is conducted in a step-wise process Incorporation of additional treatment barriers Continued close communication with CDPH Increase significant water quality monitoring Project evaluation at key decision milestones
14 Permit Conditions OMMP UV Validation Testing Intrinsic Tracer Study Reconvene Expert Panel Source Control Implementation Program
15 Water Quality Analysis Use ELAP Certified In House Lab and 7 additional Outside Labs More than 19,000 Samples Analyzed for Barrier Water Only Cost of over nearly $600, per year on Barrier Analysis Additional R&D On Going
16 CDPH List of Chemicals of Concern Nitrite Asbestos Foaming Agents Radium-226 Radium-228 Gross Alpha Activity Tritium Strontium-90 Gross Beta Activity Uranium Bromate Bromide Monochloroacetic Acid Dichloroacetic Acid Trichloroacetic Acid Monobromoacetic Acid Dibromoacetic Acid 1,1,2-Trichloro Trichloro-1,2,2-Trifluoroethane Bentazon Benzo(a)pyrene Dalapon Di(2-ethylhexyl)adipate Diquat Endothall Ethylene Dibromide Glyphosate Lindane Molinate Oxamyl Picloram Thiobencarb 2,4,5-TP (Silvex( Silvex) Perchlorate
17 NaOCl HYPERION PLANT PUMP STATION Influent Ibuprofen - 80 ppt Gemfibrozil ppt Naproxen - 80 ppt Ketoprofen - 45 ppt Diclofenac - 50 ppt Metoprolol ppt West Basin Water Recycling Plant BARRIER TREATMENT PROCESS TRAIN NO. 3 R&D SAMPLING Results- PhACs (Feb. 2001) MF Effluent Ibuprofen ppt Gemfibrozil ppt Naproxen - 90 ppt Ketoprofen - 40 ppt Diclofenac - 40 ppt Metoprolol ppt Reverse Osmosis RO Effluent Ibuprofen - <10 ppt Gemfibrozil - <10 ppt Naproxen - <10 ppt Ketoprofen - <10 ppt Diclofenac - <10 ppt Metoprolol - <10 ppt MWD Water Ibuprofen - <10 ppt Gemfibrozil - <10 ppt Naproxen - <10 ppt Ketoprofen - <10 ppt Diclofenac - <10 ppt Metoprolol - <10 ppt Disinfection NaOCl strainer NaOCl Micro filtration TO WASHWATER EQUALIZATION Storage Basin H 2 SO 4 scale inhibitor cartridge filter RO Effluent - Post Decarb. Ibuprofen - <10 ppt Gemfibrozil - <10 ppt Naproxen - <10 ppt Ketoprofen - <10 ppt Diclofenac - <10 ppt Metoprolol - <10 ppt UV MWD (Colorado +State Project) TO WEST COAST BASIN BARRIER PROJECT Post UV Ibuprofen - <10 ppt Gemfibrozil - <10 ppt Naproxen - <10 ppt Ketoprofen - <10 ppt Diclofenac - <10 ppt Metoprolol - <10 ppt brine TO HYPERION 5-MILE OUTFALL FeCl 3 - ferric chloride NaOCl - sodium hypochlorite H 2 SO 4 - sulfuric acid CO 2 - carbon dioxide
18 WEST BASIN WATER RECYCLING PLANT Barrier Project Product Water Pharmaceuticals /Endocrine Disrupting Compounds Constituent Analytical Method Reporting MCL or 2007 Method Units Detection Detection Permit Exceedence Limit Limit (MDL) (RDL) Limit MINIMUM MEAN MAXIMUM Acetominopen LC/MS/MS ESI ng/l ND ND ND Amoxicillin * ng/l - NA NA NA Azithromycin ** ng/l - NA NA NA Estriol ** ng/l 10 - ND 1 ND 1 ND 1 17-a Estradiol ** ng/l 10 - ND 1 ND 1 ND 1 17-b Estradiol LC/MS/MS ESI ng/l ND 1 ND 1 ND 1 17-a Ethynylestradiol LC/MS/MS ESI ng/l ND 1 ND 1 ND 1 Epitestosterone ** ng/l 10 - ND 1 ND 1 ND 1 Estrone LC/MS/MS ESI ng/l ND 1 ND 1 ND 1 Ethylamine diamine tetraacetic acid (EDTA) * ng/l - NA NA NA Diethylstilbestrol ** ng/l 10 - ND 1 ND 1 ND 1 Progesterone * ng/l 10 - ND 1 ND 1 ND 1 Trans-testosterone ** ng/l 10 - ND 1 ND 1 ND 1 Bisphenol A GC/MS ng/l ND ND ND Caffeine GC/MS µg/l ND ND ND Carbamazepine ** ng/l 5 - ND ND ND Ciprofloxacin ** ng/l - NA NA NA Gemfibrozil LC/MS/MS ESI ng/l ND ND ND Ibuprofen LC/MSESI ng/l ND ND ND Iodinated contrast media ** ng/l - NA NA NA Lipitor ** ng/l - NA NA NA Methadone ** ng/l - NA NA NA Morphine ** ng/l - NA NA NA Salicylic acid ** ng/l - NA NA NA Triclosan LC/MS/MS ESI ng/l ND ND ND Nonyphenol GC/MS ng/l - NA NA NA Nonyphenol polyethoxylate ** ng/l - NA NA NA Octylphenol GC/MS ng/l - NA NA NA Octylphenol polyethoxylate ** ng/l - NA NA NA PDBE M µg/l ND ND ND PDBE M µg/l ND ND ND PDBE M µg/l ND PDBE M µg/l ND ND ND PDBE M µg/l ND ND ND ND = Analyte not detected at the Method Detection Limt (MDL) Method Development in Progress No Commercial Lab Analyzes "1" = Analyzed in RO Product Water in June and August 2007)
19
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