FOD060A March Shalini Shahani Dewan Project Analyst ISBN:

Transcription

1 GLOBAL MARKETS FOR CONTROLLED INTELLIGENT PACKAGING, PRESERVATION AND SHELF-LIFE EXTENSION FOR FOOD AND BEVERAGES -- FOCUS ON ENCAPSULATION, IRRADIATION AND OTHER APPLICATIONS FOD060A March 2013 Shalini Shahani Dewan Project Analyst ISBN: BCC Research 49 Walnut Park, Building 2 Wellesley, MA , Custom Reports: carol.laverty@bccresearch.com

2 TABLE OF CONTENTS CHAPTER 1 INTRODUCTION 2 STUDY OBJECTIVES 2 REASONS FOR DOING THIS STUDY 2 CONTRIBUTIONS OF THE STUDY AND FOR WHOM 3 SCOPE OF THE STUDY 3 METHODOLOGY 3 INFORMATION SOURCES 3 ABOUT THE AUTHOR 3 RELATED BCC RESEARCH REPORTS 4 CUSTOM ANALYSES 4 BCC ON-LINE SERVICES 4 DISCLAIMER 5 CHAPTER 2 EXECUTIVE SUMMARY 7 SUMMARY TABLE GLOBAL REVENUE OF PRESERVATION, PACKAGING AND SHELF LIFE EXTENDERS, THROUGH 2017 ($ SUMMARY FIGURE GLOBAL REVENUE OF PRESERVATION, PACKAGING AND SHELF LIFE EXTENDERS, ($ 8 8 CHAPTER 3 OVERVIEW 10 IMPORTANCE OF THE PRESERVATION AND PACKAGING INDUSTRY 10 FOOD PRESERVATION HISTORY 11 TABLE 1 HIGHLIGHTS IN FOOD PRESERVATION HISTORY 13 FOOD PRESERVATION AND SHELF LIFE EXTENDERS 14 TYPES OF PRESERVATIVES AND SHELF-LIFE EXTENDERS 15 TABLE 2 KEY PRESERVATIVES AND SHELF-LIFE EXTENDERS 15 CHEMICAL AND NATURAL PRESERVATIVES 15 ANTIOXIDANTS 15 TABLE 3 SELECTED ANTIOXIDANTS 16 Selected Antioxidants 16 Tertiary-butylhydroquinone (TBHQ) 17 Propyl Gallate 17 Trihydroxybutyrophenone (THBP) 18 Tocopherols 18 Flavonoids and Phenolics 18 TABLE 4 ADVANTAGES OF SELECTED ANTIOXIDANTS 19 ANTIMICROBIALS 19 TABLE 5 SELECTED ANTIMICROBIALS 20 Selected Antimicrobials 20 Acetic Acid 20 Benzoic Acid 21 Lysozyme 21 Natamycin 21 Nisin (Bacteriocins) 22 Phosphoric and Citric Acids 22 Propionic Acid, Sodium and Calcium Propionates 22

3 Parabens 23 Sorbates (Sorbic Acid, Potassium Sorbate) 23 Sulfites 24 Nitrates and Nitrites 24 Glutaraldehyde 24 TABLE 6 ADVANTAGES OF SELECTED ANTIMICROBIALS 25 SYNERGISMS AND CHEMICAL COMPOUNDS 26 PACKAGING 27 TABLE 7 CHARACTERISTICS OF PACKAGING BY TYPE AND FUNCTION 27 PLASTICS/ POLYMERS 28 Plastics and Films 28 Additional Plastic/Polymer Technologies for Use in Food Preservation 29 Ethylene Vinyl Alcohol Copolymer (EVOH) 29 High-Density Polyethylene (HDPE) 29 Polyethylene Terephthalate (PET) 29 Polypropylene (PP) 30 CANNING AND BOTTLING (METAL AND GLASS) 30 FOIL 31 FLEXIBLE PACKAGING (WOOD, PAPER AND CARDBOARD) 32 HIGH-PRESSURE PACKAGING (HPP) 33 SMART PACKAGING 33 Active Packaging 33 Controlled Packaging 34 Modified Atmosphere Packaging (MAP) 34 Controlled Atmosphere Packaging (CAP) 35 Intelligent Packaging 36 TABLE 8 FUNCTIONS OF PACKAGING BY TYPE 36 ENCAPSULATION 37 TABLE 9 TYPES AND CATEGORIES OF ENCAPSULATION AND THEIR FUNCTIONS 38 SPRAY DRYING 38 SPRAY CONGEALING OR COOLING 39 DRUM DRYING 40 FLUIDIZED BED 40 EXTRUSION 40 ROTATING DISK 41 VIBRATION NOZZLE 41 COACERVATION 41 RENNET-GELLED PROTEIN ENCAPSULATION 42 ADVANTAGES OF ENCAPSULATION 42 DISADVANTAGES OF ENCAPSULATION 42 CHILLING AND HEATING 43 TABLE 10 TYPES AND CATEGORIES OF CHILLING AND HEATING AND THEIR FUNCTIONS CHILLING 44 Refrigeration and Freezing 44 Blast Chilling 44 Blast Freezing/Flash Freezing 45 Freeze Drying or Lyophilization 45 43

4 Convenience Fresh Foods 46 Versatile Freezing Equipment (VFE) 46 Advantages of Refrigeration and Freezing 47 HEATING 47 Sterilization 47 Retorting 48 Pasteurization 48 Ohmic Heating 49 Induction/Inductive Heating 49 Microwave Heating 50 Radio-Frequency Heating 50 Thermization 51 ADVANTAGES OF HEATING AND OTHER THERMAL PROCESSES 51 IRRADIATION 51 BIOTECHNOLOGY 52 ADVANTAGES OF IRRADIATION 53 CONCERNS REGARDING IRRADIATION 53 ADDITIONAL METHODS 54 SALTING AND SPICING 54 PICKLING 55 FERMENTATION 55 DEHYDRATION AND SMOKING 55 SUGARING AND SYRUPING 56 CHAPTER 4 REGULATORY ASPECTS 58 LABELING OF FOODS 59 REGULATIONS FOR FOOD AND BEVERAGES PRESERVATIVES 59 BUTYLATED HYDROXYANISOLE (BHA) 59 TABLE 11 LIMITS OF BHA AND BHT IN TYPES OF FOOD 60 BUTYLATED HYDROXYTOLUENE (BHT) 60 TABLE 12 LIMITS OF BHT AND BHA IN TYPES OF FOOD 61 TERTIARY BUTYL HYDROQUINONE (TBHQ) 61 PROPYL GALLATE 61 TRIHYDROXYBUTYROPHENONE (THBP) 62 TOCOPHEROLS 62 BENZOIC ACID 62 Sodium Benzoate 62 PHOSPHORIC ACID 62 CITRIC ACID 63 PROPIONIC ACID 63 SORBIC ACID 63 SULFITES IN STANDARDIZED FOOD 63 NITRITES AND/OR NITRATES IN CURING PREMIXES 63 Potassium Nitrate 64 Sodium Nitrate 64 Sodium Nitrite 64 TABLE 13 PRESERVATIVE AND STANDARD APPROXIMATE LIMITS 66

5 REGULATIONS FOR FOOD AND BEVERAGES PACKAGING 66 REGULATIONS FOR CHILLING AND THERMAL PROCESSING OF FOOD AND BEVERAGES REGULATIONS FOR FOOD ENCAPSULATION 69 MICROCAPSULES FOR FLAVORING SUBSTANCES 69 REGULATION OF IRRADIATED FOODS AND BEVERAGES 70 TABLE 14 STATUS OF FOOD IRRADIATION REGULATIONS IN THE U.S., 1985 TO 2000 TABLE 15 RECALLS OF FOOD AND BEVERAGE PRODUCTS REGULATORY DEVELOPMENTS OF PRESERVATIVES, PACKAGING AND SHELF LIFE EXTENDERS CHAPTER 5 NEW DEVELOPMENTS 76 TABLE 16 NEW DEVELOPMENTS IN 2012 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF-LIFE EXTENDERS TABLE 17 ACQUISITIONS, MERGERS AND AWARDS IN 2012 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF LIFE EXTENDERS TABLE 18 NEW DEVELOPMENTS IN 2011 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF-LIFE EXTENDERS TABLE 19 ACQUISITIONS, MERGERS AND AWARDS IN 2011 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF LIFE EXTENDERS TABLE 20 NEW DEVELOPMENTS IN 2010 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF LIFE EXTENDERS TABLE 21 ACQUISITIONS, MERGERS AND AWARDS IN 2010 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF-LIFE EXTENDERS TABLE 22 NEW DEVELOPMENTS IN 2009 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF-LIFE EXTENDERS TABLE 23 ACQUISITIONS, MERGERS AND AWARDS IN 2009 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF LIFE EXTENDERS CHAPTER 6 GLOBAL MARKETS - PACKAGING AND PRESERVATIVES 95 MARKET BY TYPE 96 MARKET OVERVIEW 98 MARKET REVENUE 101 TABLE 24 GLOBAL SALES FOR PACKAGING AND PRESERVATIVES OF FOOD PRODUCTS BY TYPE, THROUGH 2017 ($ FIGURE 1 GLOBAL SALES FOR PACKAGING AND PRESERVATIVES OF FOOD PRODUCTS BY TYPE, ($ MARKET SHARE 102 TABLE 25 MARKET SHARE OF GLOBAL SALES FOR PACKAGING AND PRESERVATIVES OF FOOD PRODUCTS BY TYPE, 2011 (%) FIGURE 2 MARKET SHARE OF GLOBAL SALES FOR PACKAGING AND PRESERVATIVES OF FOOD PRODUCTS BY TYPE, 2011 (%) MARKET BY REGION 103 MARKET OVERVIEW 104 MARKET REVENUE 106 TABLE 26 MARKET FOR PRESERVATIVES AND PACKAGING USED IN FOOD PRESERVATION BY REGION, THROUGH 2017 ($ FIGURE 3 MARKET FOR PRESERVATIVES AND PACKAGING USED IN FOOD PRESERVATION BY REGION, ($ MARKET SHARE

6 TABLE 27 MARKET SHARE OF PRESERVATIVES AND PACKAGING USED IN FOOD PRESERVATION BY REGION, 2011 (%) FIGURE 4 MARKET SHARE OF PRESERVATIVES AND PACKAGING USED IN FOOD PRESERVATION BY REGION, 2011 (%) PRESERVATIVES BY REGION 107 TABLE 28 REGIONAL BREAKDOWN FOR SALES OF PRESERVATIVES USED IN FOOD, THROUGH 2017 ($ FIGURE 5 REGIONAL BREAKDOWN FOR SALES OF PRESERVATIVES USED IN FOOD, ($ MARKET SHARE 109 TABLE 29 MARKET SHARE FOR SALES OF PRESERVATIVES USED IN FOOD BY REGION, 2011 (%) FIGURE 6 MARKET SHARE FOR SALES OF PRESERVATIVES USED IN FOOD BY REGION, 2011 (%) PACKAGING BY REGION 110 TABLE 30 REGIONAL BREAKDOWN FOR SALES OF PACKAGING, THROUGH 2017 ($ FIGURE 7 REGIONAL BREAKDOWN FOR SALES OF PACKAGING, ($ MARKET SHARE 111 TABLE 31 MARKET SHARE REGIONAL BREAKDOWN FOR SALES OF PACKAGING, 2011 (%) FIGURE 8 MARKET SHARE REGIONAL BREAKDOWN FOR SALES OF PACKAGING, 2011 (%) THERMAL AND FREEZING PROCESS BY REGION 112 TABLE 32 REGIONAL BREAKDOWN FOR SALES OF THERMAL AND FREEZING PROCESSES USED IN FOOD, THROUGH 2017 ($ FIGURE 9 REGIONAL BREAKDOWN FOR SALES OF THERMAL AND FREEZING PROCESSES USED IN FOOD, ($ MARKET SHARE 113 TABLE 33 MARKET SHARE OF REGIONAL BREAKDOWN FOR SALES OF THERMAL AND FREEZING PROCESS USED IN FOOD, 2011 (%) FIGURE 10 MARKET SHARE OF REGIONAL BREAKDOWN FOR SALES OF THERMAL AND FREEZING PROCESS USED IN FOOD, 2011 (%) ENCAPSULATION, IRRADIATION AND ADDITIONAL FOOD PRESERVATION PROCESSES BY REGION TABLE 34 REGIONAL BREAKDOWN FOR SALES OF ENCAPSULATION, IRRADIATION AND ADDITIONAL FOOD PRESERVATION PROCESSES USED IN FOOD, THROUGH 2017 ($ FIGURE 11 BREAKDOWN FOR SALES OF ENCAPSULATION, IRRADIATION AND ADDITIONAL FOOD PRESERVATION PROCESSES USED IN FOOD, ($ MARKET SHARE 116 TABLE 35 MARKET SHARE OF REGIONAL BREAKDOWN FOR SALES OF ENCAPSULATION, IRRADIATION AND ADDITIONAL FOOD PRESERVATION PROCESSES, 2011 (%) FIGURE 12 MARKET SHARE OF REGIONAL BREAKDOWN FOR SALES OF ENCAPSULATION, IRRADIATION AND ADDITIONAL FOOD PRESERVATION PROCESSES, 2011 (%) MARKET BY APPLICATION 117 MARKET OVERVIEW 117 MARKET REVENUE

7 TABLE 36 MARKET FOR PACKAGING AND PRESERVATION USED IN FOOD, BEVERAGE AND OTHER BY APPLICATIONS, THROUGH 2017 ($ FIGURE 13 MARKET FOR PACKAGING AND PRESERVATION USED IN FOOD, BEVERAGE AND OTHER BY APPLICATIONS, ($ MARKET SHARE 121 TABLE 37 MARKET SHARE FOR PACKAGING AND PRESERVATION USED IN FOOD, BEVERAGE AND OTHER BY APPLICATIONS, 2011 (%) FIGURE 14 MARKET SHARE FOR PACKAGING AND PRESERVATION USED IN FOOD, BEVERAGE AND OTHER BY APPLICATIONS, 2011 (%) CHAPTER 7 MARKET FOR ENCAPSULATION, IRRADIATION AND OTHER APPLICATIONS 124 MARKET BY TYPE 125 ENCAPSULATION 125 Spray Drying 125 Spray Cooling or Spray Chilling 125 Extrusion 126 Fluidized-Bed Coating 126 Coacervation 126 TABLE 38 FOOD INGREDIENTS AND CORRESPONDING ENCAPSULATION METHODS 127 Drum Dryers 127 IRRADIATION 127 OTHERS 128 Salting and Spicing 129 Pickling 129 Fermentation 130 Dehydration and Smoking 130 Sugaring and Syruping 131 MARKET OVERVIEW 131 MARKET REVENUE 132 TABLE 39 MARKET FOR PRODUCTS THROUGH ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION METHODS BY TYPE, THROUGH 2017 ($ FIGURE 15 MARKET FOR PRODUCTS THROUGH ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION METHODS BY TYPE, ($ MARKET SHARE 134 TABLE 40 MARKET SHARE OF ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION METHODS BY TYPE, 2011 (%) FIGURE 16 MARKET SHARE OF ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION METHODS BY TYPE, 2011 (%) MARKET BY REGION 134 TABLE 41 MARKET FOR ENCAPSULATION, IRRADIATION AND OTHER METHODS USED IN FOOD PRESERVATION BY REGION, THROUGH 2017 ($ FIGURE 17 MARKET FOR ENCAPSULATION, IRRADIATION AND OTHER METHODS USED IN FOOD PRESERVATION BY REGION, ($ MARKET OVERVIEW 136 MARKET REVENUE 137 Encapsulation 137 TABLE 42 MARKET FOR ENCAPSULATION METHOD USED IN FOOD PRESERVATION BY REGION, THROUGH 2017 ($ FIGURE 18 MARKET FOR ENCAPSULATION METHOD USED IN FOOD PRESERVATION BY REGION, ($

8 Irradiation 138 TABLE 43 MARKET FOR IRRADIATION METHOD USED IN FOOD PRESERVATION BY REGION, THROUGH 2017 ($ FIGURE 19 MARKET FOR IRRADIATION METHOD USED IN FOOD PRESERVATION BY REGION, ($ Additional Food Preservative Methods 139 TABLE 44 MARKET FOR ADDITIONAL FOOD PRESERVATION METHODS BY REGION, THROUGH 2017 ($ FIGURE 20 MARKET FOR ADDITIONAL FOOD PRESERVATION METHODS BY REGION, ($ MARKET SHARES 140 Encapsulation 140 TABLE 45 MARKET SHARE OF FOOD-ENCAPSULATION TECHNIQUE BY REGION, 2011 (%) FIGURE 21 MARKET SHARE OF FOOD-ENCAPSULATION TECHNIQUE BY REGION, 2011 (%) Irradiation 141 TABLE 46 MARKET SHARE OF FOOD-IRRADIATION TECHNIQUE BY REGION, 2011 (%) 141 FIGURE 22 MARKET SHARE OF FOOD IRRADIATION TECHNIQUE BY REGION, 2011 (%) Additional Food Preservative Methods 142 TABLE 47 MARKET SHARE OF ADDITIONAL FOOD PRESERVATION TECHNIQUE BY REGION, 2011 (%) FIGURE 23 MARKET SHARE OF ADDITIONAL FOOD PRESERVATION TECHNIQUE BY REGION, 2011 (%) MARKET BY APPLICATION 143 ENCAPSULATION 143 Baked Goods 143 Confectioneries 144 Dairy Products 144 Others 145 IRRADIATION 145 Food 145 Beverages 146 Other 146 ADDITIONAL METHODS 146 Food 146 Beverages 147 MARKET OVERVIEW 147 MARKET REVENUE 148 Encapsulation 148 TABLE 48 MARKET FOR FOOD ENCAPSULATION BY APPLICATION, THROUGH 2017 ($ FIGURE 24 MARKET FOR FOOD ENCAPSULATION BY APPLICATION, ($ Irradiation 149 TABLE 49 MARKET FOR FOOD IRRADIATION BY APPLICATION, THROUGH 2017 ($ FIGURE 25 MARKET FOR FOOD IRRADIATION BY APPLICATION, ($

9 Other Preservative Techniques 150 TABLE 50 MARKET FOR OTHER PRESERVATION TECHNIQUES BY APPLICATION, THROUGH 2017 ($ FIGURE 26 MARKET FOR OTHER PRESERVATION TECHNIQUES BY APPLICATION, ($ MARKET SHARE 151 TABLE 51 MARKET SHARE OF ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION TECHNIQUES BY APPLICATION, 2011 (%) FIGURE 27 MARKET SHARE OF ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION TECHNIQUES BY APPLICATION, 2011 (%) INDUSTRY STRUCTURE 152 ENCAPSULATION 152 Market Leaders 153 TABLE 52 LEADING MANUFACTURERS/ SUPPLIERS OF PRODUCTS FOR FOOD ENCAPSULATION, 2011 Market Shares 154 TABLE 53 MARKET SHARES OF MANUFACTURERS/PROCESSORS FOR FOOD ENCAPSULATION, 2011 (%) FIGURE 28 MARKET SHARES OF MANUFACTURERS/PROCESSORS FOR FOOD ENCAPSULATION, 2011 (%) IRRADIATION 156 Market Leaders 156 TABLE 54 LEADING MANUFACTURERS/ SUPPLIERS OF PRODUCTS FOR FOOD IRRADIATION, 2011 Market Shares 156 TABLE 55 MARKET SHARES OF MANUFACTURERS/ PROCESSORS FOR FOOD IRRADIATION, 2011 (%) FIGURE 29 MARKET SHARES OF MANUFACTURERS/ PROCESSORS FOR FOOD IRRADIATION, 2011 (%) ADDITIONAL FOOD PRESERVATION TECHNIQUES 157 Market Leaders 158 TABLE 56 LEADING MANUFACTURERS/ SUPPLIERS OF PRODUCTS FOR ADDITIONAL FOOD PRESERVATION TECHNIQUES, 2011 Market Shares 158 TABLE 57 MARKET SHARES OF MANUFACTURERS/PROCESSORS FOR ADDITIONAL PRESERVATION TECHNIQUES, 2011 (%) FIGURE 30 MARKET SHARES OF MANUFACTURERS/PROCESSORS FOR ADDITIONAL PRESERVATION TECHNIQUES, 2011 (%) CHAPTER 8 PATENT ANALYSIS 161 PATENTS BY YEAR 162 TABLE 58 TOTAL NUMBER OF PATENTS EACH YEAR 2009 TO 162 FIGURE 31 TOTAL NUMBER OF PATENTS EACH YEAR, 2009 TO 162 PATENTS BY PRESERVATION AND PACKAGING CATEGORY 162 TABLE 59 NUMBER OF PATENTS BY PRESERVATION AND PACKAGING CATEGORY, 2009 TO FIGURE 32 NUMBER OF PATENTS BY PRESERVATION AND PACKAGING CATEGORY, 2009 TO PATENTS BY PRESERVATION AND PACKAGING TYPE 163 PATENTS BY PRESERVATION

10 TABLE 60 PATENTS BY TYPES OF PRESERVATIVES TYPE, 2009 TO 164 FIGURE 33 PATENTS BY TYPE OF PRESERVATIVES, 2010 TO 164 PATENTS BY PACKAGING 164 TABLE 61 PATENTS BY TYPE OF PACKAGING, 2009 TO 165 FIGURE 34 PATENTS BY TYPE OF PACKAGING, 2009 TO 165 PATENTS BY CHILLING AND THERMAL PROCESSING 165 TABLE 62 PATENTS BY TYPE OF CHILLING AND THERMAL PROCESSING, 2009 T0 FIGURE 35 PATENTS BY TYPE OF CHILLING AND THERMAL PROCESSING, 2009 TO PATENTS BY ENCAPSULATION, IRRADIATION AND OTHER METHODS 166 TABLE 63 PATENTS BY ENCAPSULATION, IRRADIATION AND OTHER METHODS, 2009 TO FIGURE 36 PATENTS BY ENCAPSULATION, IRRADIATION AND OTHER METHODS, 2009 TO PATENTS BY COUNTRY 167 FOOD PRESERVATIVES 167 TABLE 64 NUMBER OF U.S. PATENTS BY COUNTRY FOR PRESERVATIVES, 2009 TO FIGURE 37 NUMBER OF U.S. PATENTS BY COUNTRY FOR PRESERVATIVES, 2009 TO TABLE 65 PATENT SHARES BY COUNTRY FOR PRESERVATIVES, 2009 TO OCTOBER 2012 (%) FIGURE 38 PATENT SHARES BY COUNTRY FOR PRESERVATIVES 2009 TO OCTOBER 2012 (%) FOOD PACKAGING 169 TABLE 66 NUMBER OF U.S. PATENTS BY COUNTRY FOR PACKAGING, 2009 TO FIGURE 39 NUMBER OF U.S. PATENTS BY COUNTRY FOR PACKAGING, 2009 TO TABLE 67 SHARE OF PATENTS BY COUNTRY FOR PACKAGING 2009 TO OCTOBER 2012 (%) FIGURE 40 SHARE OF PATENTS BY COUNTRY FOR PACKAGING, 2009 TO OCTOBER 2012 (%) THERMAL PROCESSING AND CHILLING 172 TABLE 68 NUMBER OF U.S. PATENTS BY COUNTRY FOR CHILLING AND THERMAL PROCESSING, 2009 TO FIGURE 41 NUMBER OF U.S. PATENTS BY COUNTRY FOR CHILLING AND THERMAL PROCESSING, 2009 TO TABLE 69 SHARE OF PATENTS BY COUNTRY FOR CHILLING AND THERMAL PROCESSING, 2009 TO (%) FIGURE 42 SHARE OF PATENTS BY COUNTRY FOR CHILLING AND THERMAL PROCESSING, 2009 TO (%) ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION TECHNIQUES TABLE 70 NUMBER OF U.S. PATENTS BY COUNTRY FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO FIGURE 43 NUMBER OF U.S. PATENTS BY COUNTRY FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO TABLE 71 PATENT SHARES BY COUNTRY FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO (%)

11 FIGURE 44 SHARE OF PATENTS BY COUNTRY FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO (%) PATENTS BY COMPANY 178 FOOD PRESERVATIVES 178 TABLE 72 NUMBER OF U.S. PATENTS BY COMPANY* FOR FOOD PRESERVATIVES, 2009 TO FOOD PACKAGING 180 TABLE 73 NUMBER OF U.S. PATENTS BY COMPANY* FOR FOOD PACKAGING 2009 TO CHILLING AND THERMAL PROCESSING 185 TABLE 74 NUMBER OF U.S. PATENTS BY COMPANY* FOR CHILLING AND THERMAL PROCESSING, 2009 TO ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION TECHNIQUES TABLE 75 NUMBER OF U.S. PATENTS BY COMPANY FOR ENCAPSULATION IRRADIATION AND OTHER TECHNIQUES, 2009 TO PATENTS BY ASSIGNEE 192 FOOD PRESERVATIVES 192 TABLE 76 PATENTS BY ASSIGNEE FOR FOOD PRESERVATIVES, 2009 TO OCTOBER 2012 FIGURE 45 PATENTS BY ASSGINEE FOR FOOD PRESERVATIVES 2009 TO OCTOBER 2012 FOOD PACKAGING 193 TABLE 77 PATENTS BY ASSIGNEE FOR FOOD PACKAGING, 2009 TO 193 FIGURE 46 PATENTS BY ASSIGNEE FOR FOOD PACKAGING, 2009 TO OCTOBER 2012 CHILLING AND THERMAL PROCESSING 194 TABLE 78 PATENTS BY ASSIGNEE FOR CHILLING AND THERMAL PROCESSING, 2009 TO FIGURE 47 PATENTS BY ASSIGNEE FOR CHILLING AND THERMAL PROCESSING, 2009 TO ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION TECHNIQUES TABLE 79 PATENTS BY ASSIGNEE FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO FIGURE 48 PATENTS BY ASSGINEE FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO CHAPTER 9 CURRENT SITUATION 198 MARKET TRENDS 198 PRESERVATIVES 198 Market Drivers 199 FOOD PACKAGING 200 Market Drivers 201 CHILLING AND THERMAL PROCESSING 202 Market Drivers 203 ENCAPSULATION, IRRADIATION AND OTHER PRESERVATION METHODS 203 Encapsulation 203 Irradiation 204 Additional Preservation Techniques 205

12 Market Drivers 205 FACTORS GOVERNING THE MARKET 206 COLLABORATIONS-MERGERS AND ACQUISITIONS 206 CHAPTER 10 COMPANY PROFILES 210 ALCOA INC. 210 AMCOR LIMITED 210 ARCHER DANIELS MIDLAND COMPANY 212 AVURE TECHNOLOGIES, LLC 213 BALCHEM CORPORATION 213 BALL CORPORATION 214 BASF SE 215 BEMIS COMPANY, INC. 216 BIOPROGRESS TECHNOLOGY INTERNATIONAL, INC. 217 CAMPDEN BRI 218 CARGILL INCORPORATED 219 CONWED PLASTICS LLC 220 CPM WOLVERINE PROCTOR, LLC 221 CSP TECHNOLOGIES, INC. 222 DAI NIPPON PRINTING CO., LTD. 222 DANISCO A/S 223 DIXIE CANNER 224 E. I. DU PONT DE NEMOURS AND COMPANY 225 EASTMAN CHEMICAL COMPANY 226 ECOLAB INC. 227 EL CLARIN SPICES S.L. 228 ENWAVE CORPORATION 228 FIRMENICH INTERNATIONAL 229 FMC BIOPOLYMER 230 FOOD TECHNOLOGY SERVICES INC. 231 FUCHS NORTH AMERICA 232 GEA REFRIGERATION TECHNOLOGIES 232 GRAY STAR, INC. 233 HAWKINS WATTS AUSTRALIA PTY. LTD. 234 HEAT AND CONTROL INC., AUSTRALIA 234 HONEYWELL INTERNATIONAL INC. 235 ICL PERFORMANCE PRODUCTS 236 INGREDION INC. 237 INTERNATIONAL DAIRY QUEEN 238 INTERNATIONAL FLAVOR AND FRAGRANCES, INC. 238 INTERNATIONAL PAPER CO. 239 IOTRON INDUSTRIES CANADA INC. 240 KEMIN INDUSTRIES, INC. 241 KIRIN HOLDINGS 242 KRAFT FOODS INC. 242 LALLEMAND INC. 243 MANITOWOC FOODSERVICE 244

13 MECHANICAL REFRIGERATION, INC. 245 MITSUI CHEMICALS, INC. 245 NESTLE S.A. 246 NORDION INC. 247 PACTIV LLC 248 PALSGAARD A/S 249 PEAKFRESH USA 250 PHENOFARM S.R.L. 251 PLACON 251 QUALITY INGREDIENTS CORPORATION 252 RAZTEK CORP. 253 RIO TINTO ALCAN INC. 253 ROBERT BOSCH, GMBH 254 ROQUETTE FRERES 255 SEALED AIR CORP. 256 SENSIENT TECHNOLOGIES CORPORATION 257 SHREE ADDITIVES 258 SIGMA-ALDRICH CORP. 258 SOLVAY 258 STERIS ISOMEDIX SERVICES 259 STERITECH PTY. LTD. 260 STOCK AMERICA INC. 261 TASTETECH LIMITED 262 TETRA PAK INTERNATIONAL 263 THE WRIGHT GROUP 265 TYSON FOODS INC. 265 UNILEVER N.V. 266 WACKER BIOCHEM CORP. 267 WATLOW ELECTRIC MANUFACTURING COMPANY 268 WEYERHAEUSER COMPANY 268 WILD FLAVORS, INC. 269 WINPAK LTD. 270 CHAPTER 11 APPENDIX ABBREVIATIONS 272

14 LIST OF TABLES TABLE HEADING SUMMARY TABLE GLOBAL REVENUE OF PRESERVATION, PACKAGING AND SHELF LIFE EXTENDERS, THROUGH 2017 ($ TABLE 1 HIGHLIGHTS IN FOOD PRESERVATION HISTORY 13 TABLE 2 KEY PRESERVATIVES AND SHELF-LIFE EXTENDERS 15 TABLE 3 SELECTED ANTIOXIDANTS 16 TABLE 4 ADVANTAGES OF SELECTED ANTIOXIDANTS 19 TABLE 5 SELECTED ANTIMICROBIALS 20 TABLE 6 ADVANTAGES OF SELECTED ANTIMICROBIALS 25 TABLE 7 CHARACTERISTICS OF PACKAGING BY TYPE AND FUNCTION 27 TABLE 8 FUNCTIONS OF PACKAGING BY TYPE 36 TABLE 9 TYPES AND CATEGORIES OF ENCAPSULATION AND THEIR FUNCTIONS 38 TABLE 10 TYPES AND CATEGORIES OF CHILLING AND HEATING AND THEIR FUNCTIONS TABLE 11 LIMITS OF BHA AND BHT IN TYPES OF FOOD 60 TABLE 12 LIMITS OF BHT AND BHA IN TYPES OF FOOD 61 TABLE 13 PRESERVATIVE AND STANDARD APPROXIMATE LIMITS 66 TABLE 14 STATUS OF FOOD IRRADIATION REGULATIONS IN THE U.S., 1985 TO TABLE 15 RECALLS OF FOOD AND BEVERAGE PRODUCTS TABLE 16 NEW DEVELOPMENTS IN 2012 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF-LIFE EXTENDERS TABLE 17 ACQUISITIONS, MERGERS AND AWARDS IN 2012 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF LIFE EXTENDERS TABLE 18 NEW DEVELOPMENTS IN 2011 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF-LIFE EXTENDERS TABLE 19 ACQUISITIONS, MERGERS AND AWARDS IN 2011 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF LIFE EXTENDERS TABLE 20 NEW DEVELOPMENTS IN 2010 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF LIFE EXTENDERS TABLE 21 ACQUISITIONS, MERGERS AND AWARDS IN 2010 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF-LIFE EXTENDERS TABLE 22 NEW DEVELOPMENTS IN 2009 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF-LIFE EXTENDERS TABLE 23 ACQUISITIONS, MERGERS AND AWARDS IN 2009 FOR CONTROLLED PACKAGING, PRESERVATIVES AND SHELF LIFE EXTENDERS TABLE 24 GLOBAL SALES FOR PACKAGING AND PRESERVATIVES OF FOOD PRODUCTS BY TYPE, THROUGH 2017 ($ TABLE 25 MARKET SHARE OF GLOBAL SALES FOR PACKAGING AND PRESERVATIVES OF FOOD PRODUCTS BY TYPE, 2011 (%) TABLE 26 MARKET FOR PRESERVATIVES AND PACKAGING USED IN FOOD PRESERVATION BY REGION, THROUGH 2017 ($ TABLE 27 MARKET SHARE OF PRESERVATIVES AND PACKAGING USED IN FOOD PRESERVATION BY REGION, 2011 (%) TABLE 28 REGIONAL BREAKDOWN FOR SALES OF PRESERVATIVES USED IN FOOD, THROUGH 2017 ($ TABLE 29 MARKET SHARE FOR SALES OF PRESERVATIVES USED IN FOOD BY REGION, 2011 (%) TABLE 30 REGIONAL BREAKDOWN FOR SALES OF PACKAGING, THROUGH 2017 ($ TABLE 31 MARKET SHARE REGIONAL BREAKDOWN FOR SALES OF PACKAGING, 2011 (%)

15 TABLE HEADING TABLE 32 REGIONAL BREAKDOWN FOR SALES OF THERMAL AND FREEZING PROCESSES USED IN FOOD, THROUGH 2017 ($ TABLE 33 MARKET SHARE OF REGIONAL BREAKDOWN FOR SALES OF THERMAL AND FREEZING PROCESS USED IN FOOD, 2011 (%) TABLE 34 REGIONAL BREAKDOWN FOR SALES OF ENCAPSULATION, IRRADIATION AND ADDITIONAL FOOD PRESERVATION PROCESSES USED IN FOOD, THROUGH 2017 ($ TABLE 35 MARKET SHARE OF REGIONAL BREAKDOWN FOR SALES OF ENCAPSULATION, IRRADIATION AND ADDITIONAL FOOD PRESERVATION PROCESSES, 2011 (%) TABLE 36 MARKET FOR PACKAGING AND PRESERVATION USED IN FOOD, BEVERAGE AND OTHER BY APPLICATIONS, THROUGH 2017 ($ TABLE 37 MARKET SHARE FOR PACKAGING AND PRESERVATION USED IN FOOD, BEVERAGE AND OTHER BY APPLICATIONS, 2011 (%) TABLE 38 FOOD INGREDIENTS AND CORRESPONDING ENCAPSULATION METHODS 127 TABLE 39 MARKET FOR PRODUCTS THROUGH ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION METHODS BY TYPE, THROUGH 2017 ($ TABLE 40 MARKET SHARE OF ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION METHODS BY TYPE, 2011 (%) TABLE 41 MARKET FOR ENCAPSULATION, IRRADIATION AND OTHER METHODS USED IN FOOD PRESERVATION BY REGION, THROUGH 2017 ($ TABLE 42 MARKET FOR ENCAPSULATION METHOD USED IN FOOD PRESERVATION BY REGION, THROUGH 2017 ($ TABLE 43 MARKET FOR IRRADIATION METHOD USED IN FOOD PRESERVATION BY REGION, THROUGH 2017 ($ TABLE 44 MARKET FOR ADDITIONAL FOOD PRESERVATION METHODS BY REGION, THROUGH 2017 ($ TABLE 45 MARKET SHARE OF FOOD-ENCAPSULATION TECHNIQUE BY REGION, 2011 (%) TABLE 46 MARKET SHARE OF FOOD-IRRADIATION TECHNIQUE BY REGION, 2011 (%) 141 TABLE 47 MARKET SHARE OF ADDITIONAL FOOD PRESERVATION TECHNIQUE BY REGION, 2011 (%) TABLE 48 MARKET FOR FOOD ENCAPSULATION BY APPLICATION, THROUGH 2017 ($ TABLE 49 MARKET FOR FOOD IRRADIATION BY APPLICATION, THROUGH 2017 ($ TABLE 50 MARKET FOR OTHER PRESERVATION TECHNIQUES BY APPLICATION, THROUGH 2017 ($ TABLE 51 MARKET SHARE OF ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION TECHNIQUES BY APPLICATION, 2011 (%) TABLE 52 LEADING MANUFACTURERS/ SUPPLIERS OF PRODUCTS FOR FOOD ENCAPSULATION, 2011 TABLE 53 MARKET SHARES OF MANUFACTURERS/PROCESSORS FOR FOOD ENCAPSULATION, 2011 (%) TABLE 54 LEADING MANUFACTURERS/ SUPPLIERS OF PRODUCTS FOR FOOD IRRADIATION, 2011 TABLE 55 MARKET SHARES OF MANUFACTURERS/ PROCESSORS FOR FOOD IRRADIATION, 2011 (%) TABLE 56 LEADING MANUFACTURERS/ SUPPLIERS OF PRODUCTS FOR ADDITIONAL FOOD PRESERVATION TECHNIQUES, 2011 TABLE 57 MARKET SHARES OF MANUFACTURERS/PROCESSORS FOR ADDITIONAL PRESERVATION TECHNIQUES, 2011 (%)

16 TABLE HEADING TABLE 58 TOTAL NUMBER OF PATENTS EACH YEAR 2009 TO 162 TABLE 59 NUMBER OF PATENTS BY PRESERVATION AND PACKAGING CATEGORY, 2009 TO TABLE 60 PATENTS BY TYPES OF PRESERVATIVES TYPE, 2009 TO 164 TABLE 61 PATENTS BY TYPE OF PACKAGING, 2009 TO 165 TABLE 62 PATENTS BY TYPE OF CHILLING AND THERMAL PROCESSING, 2009 T0 TABLE 63 PATENTS BY ENCAPSULATION, IRRADIATION AND OTHER METHODS, 2009 TO TABLE 64 NUMBER OF U.S. PATENTS BY COUNTRY FOR PRESERVATIVES, 2009 TO TABLE 65 PATENT SHARES BY COUNTRY FOR PRESERVATIVES, 2009 TO OCTOBER 2012 (%) TABLE 66 NUMBER OF U.S. PATENTS BY COUNTRY FOR PACKAGING, 2009 TO TABLE 67 SHARE OF PATENTS BY COUNTRY FOR PACKAGING 2009 TO OCTOBER 2012 (%) TABLE 68 NUMBER OF U.S. PATENTS BY COUNTRY FOR CHILLING AND THERMAL PROCESSING, 2009 TO TABLE 69 SHARE OF PATENTS BY COUNTRY FOR CHILLING AND THERMAL PROCESSING, 2009 TO (%) TABLE 70 NUMBER OF U.S. PATENTS BY COUNTRY FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO TABLE 71 PATENT SHARES BY COUNTRY FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO (%) TABLE 72 NUMBER OF U.S. PATENTS BY COMPANY* FOR FOOD PRESERVATIVES, 2009 TO TABLE 73 NUMBER OF U.S. PATENTS BY COMPANY* FOR FOOD PACKAGING 2009 TO TABLE 74 NUMBER OF U.S. PATENTS BY COMPANY* FOR CHILLING AND THERMAL PROCESSING, 2009 TO TABLE 75 NUMBER OF U.S. PATENTS BY COMPANY FOR ENCAPSULATION IRRADIATION AND OTHER TECHNIQUES, 2009 TO TABLE 76 PATENTS BY ASSIGNEE FOR FOOD PRESERVATIVES, 2009 TO OCTOBER 2012 TABLE 77 PATENTS BY ASSIGNEE FOR FOOD PACKAGING, 2009 TO 193 TABLE 78 PATENTS BY ASSIGNEE FOR CHILLING AND THERMAL PROCESSING, 2009 TO TABLE 79 PATENTS BY ASSIGNEE FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO

17 LIST OF FIGURES FIGURE TITLE SUMMARY FIGURE GLOBAL REVENUE OF PRESERVATION, PACKAGING AND SHELF LIFE EXTENDERS, ($ FIGURE 1 GLOBAL SALES FOR PACKAGING AND PRESERVATIVES OF FOOD PRODUCTS BY TYPE, ($ FIGURE 2 MARKET SHARE OF GLOBAL SALES FOR PACKAGING AND PRESERVATIVES OF FOOD PRODUCTS BY TYPE, 2011 (%) FIGURE 3 MARKET FOR PRESERVATIVES AND PACKAGING USED IN FOOD PRESERVATION BY REGION, ($ FIGURE 4 MARKET SHARE OF PRESERVATIVES AND PACKAGING USED IN FOOD PRESERVATION BY REGION, 2011 (%) FIGURE 5 REGIONAL BREAKDOWN FOR SALES OF PRESERVATIVES USED IN FOOD, ($ FIGURE 6 MARKET SHARE FOR SALES OF PRESERVATIVES USED IN FOOD BY REGION, 2011 (%) FIGURE 7 REGIONAL BREAKDOWN FOR SALES OF PACKAGING, ($ FIGURE 8 MARKET SHARE REGIONAL BREAKDOWN FOR SALES OF PACKAGING, 2011 (%) FIGURE 9 REGIONAL BREAKDOWN FOR SALES OF THERMAL AND FREEZING PROCESSES USED IN FOOD, ($ FIGURE 10 MARKET SHARE OF REGIONAL BREAKDOWN FOR SALES OF THERMAL AND FREEZING PROCESS USED IN FOOD, 2011 (%) FIGURE 11 BREAKDOWN FOR SALES OF ENCAPSULATION, IRRADIATION AND ADDITIONAL FOOD PRESERVATION PROCESSES USED IN FOOD, ($ FIGURE 12 MARKET SHARE OF REGIONAL BREAKDOWN FOR SALES OF ENCAPSULATION, IRRADIATION AND ADDITIONAL FOOD PRESERVATION PROCESSES, 2011 (%) FIGURE 13 MARKET FOR PACKAGING AND PRESERVATION USED IN FOOD, BEVERAGE AND OTHER BY APPLICATIONS, ($ FIGURE 14 MARKET SHARE FOR PACKAGING AND PRESERVATION USED IN FOOD, BEVERAGE AND OTHER BY APPLICATIONS, 2011 (%) FIGURE 15 MARKET FOR PRODUCTS THROUGH ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION METHODS BY TYPE, ($ FIGURE 16 MARKET SHARE OF ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION METHODS BY TYPE, 2011 (%) FIGURE 17 MARKET FOR ENCAPSULATION, IRRADIATION AND OTHER METHODS USED IN FOOD PRESERVATION BY REGION, ($ FIGURE 18 MARKET FOR ENCAPSULATION METHOD USED IN FOOD PRESERVATION BY REGION, ($ FIGURE 19 MARKET FOR IRRADIATION METHOD USED IN FOOD PRESERVATION BY REGION, ($ FIGURE 20 MARKET FOR ADDITIONAL FOOD PRESERVATION METHODS BY REGION, ($ FIGURE 21 MARKET SHARE OF FOOD-ENCAPSULATION TECHNIQUE BY REGION, 2011 (%) FIGURE 22 MARKET SHARE OF FOOD IRRADIATION TECHNIQUE BY REGION, 2011 (%) 142 FIGURE 23 MARKET SHARE OF ADDITIONAL FOOD PRESERVATION TECHNIQUE BY REGION, 2011 (%) FIGURE 24 MARKET FOR FOOD ENCAPSULATION BY APPLICATION, ($

18 FIGURE TITLE FIGURE 25 MARKET FOR FOOD IRRADIATION BY APPLICATION, ($ FIGURE 26 MARKET FOR OTHER PRESERVATION TECHNIQUES BY APPLICATION, ($ FIGURE 27 MARKET SHARE OF ENCAPSULATION, IRRADIATION AND OTHER FOOD PRESERVATION TECHNIQUES BY APPLICATION, 2011 (%) FIGURE 28 MARKET SHARES OF MANUFACTURERS/PROCESSORS FOR FOOD ENCAPSULATION, 2011 (%) FIGURE 29 MARKET SHARES OF MANUFACTURERS/ PROCESSORS FOR FOOD IRRADIATION, 2011 (%) FIGURE 30 MARKET SHARES OF MANUFACTURERS/PROCESSORS FOR ADDITIONAL PRESERVATION TECHNIQUES, 2011 (%) FIGURE 31 TOTAL NUMBER OF PATENTS EACH YEAR, 2009 TO 162 FIGURE 32 NUMBER OF PATENTS BY PRESERVATION AND PACKAGING CATEGORY, 2009 TO FIGURE 33 PATENTS BY TYPE OF PRESERVATIVES, 2010 TO 164 FIGURE 34 PATENTS BY TYPE OF PACKAGING, 2009 TO 165 FIGURE 35 PATENTS BY TYPE OF CHILLING AND THERMAL PROCESSING, 2009 TO FIGURE 36 PATENTS BY ENCAPSULATION, IRRADIATION AND OTHER METHODS, 2009 TO FIGURE 37 NUMBER OF U.S. PATENTS BY COUNTRY FOR PRESERVATIVES, 2009 TO FIGURE 38 PATENT SHARES BY COUNTRY FOR PRESERVATIVES 2009 TO OCTOBER 2012 (%) FIGURE 39 NUMBER OF U.S. PATENTS BY COUNTRY FOR PACKAGING, 2009 TO FIGURE 40 SHARE OF PATENTS BY COUNTRY FOR PACKAGING, 2009 TO OCTOBER 2012 (%) FIGURE 41 NUMBER OF U.S. PATENTS BY COUNTRY FOR CHILLING AND THERMAL PROCESSING, 2009 TO FIGURE 42 SHARE OF PATENTS BY COUNTRY FOR CHILLING AND THERMAL PROCESSING, 2009 TO (%) FIGURE 43 NUMBER OF U.S. PATENTS BY COUNTRY FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO FIGURE 44 SHARE OF PATENTS BY COUNTRY FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO (%) FIGURE 45 PATENTS BY ASSGINEE FOR FOOD PRESERVATIVES 2009 TO OCTOBER 2012 FIGURE 46 PATENTS BY ASSIGNEE FOR FOOD PACKAGING, 2009 TO 193 FIGURE 47 PATENTS BY ASSIGNEE FOR CHILLING AND THERMAL PROCESSING, 2009 TO FIGURE 48 PATENTS BY ASSGINEE FOR ENCAPSULATION, IRRADIATION AND OTHER TECHNIQUES, 2009 TO