Current practice and future trends of quality and safety of Chinese alcohlic beverages

Transcription

1 6 7 Vol. 6 No Journal of Food Safety and Quality Jul., 2015 范文来, 徐 * 岩 (,, ) 摘要 : 10,,,,,,,,,,,, 关键词 : ; ; ; Current practice and future trends of quality and safety of Chinese alcohlic beverages FAN Wen-Lai, XU Yan * (Key Laboratory of Industrial Biotechnology, Ministry of Education, Laboratory of Brewing Microbiology and Applied Enzymology, School of Biotechnology, Jiangnan University, Wuxi , China) ABSTRACT: The production status of alcoholic beverages in China was systematically reviewed in nearly 10 years. The production increased significantly, quality improved constantly, and increasingly attention to product quality was paid by nation, industry and enterprise. At the same time, the quality accidents were frequently reported by media with the overall cognitive ability improvement of the consumers. The quality safety problems become the new hotspot for consumers, industries and enterprises. In recent years, the research intensity of the quality and safety gradually has increased. Compared with foreign research, the gap was huge, and the research focus was not balanced in China, especially in the production process control, reduction of toxic and hazardous compounds. This was not conducive to quality safety improvements of alcoholic beverages. We suggested that the researches of these aspects would be strengthened. We expected the quality and safety of alcoholic beverages would reach the international advanced level in the near future. KEY WORDS: alcoholic beverage; quality; quality safety; review and prospect 1 引言 10,, , % , ; 4922, , 基金项目 : (863 )(2013AA102108) Fund: Supported by the National High-tech Research and Development Projects (863) (2013AA102108) * 通讯作者 :,,, yxu@jiangnan.edu.cn *Corresponding author: XU Yan, Doctor, Professor, Key Laboratory of Industrial Biotechnology, Ministry of Education, Laboratory of Brewing Microbiology and Applied Enzymology, School of Biotechnology, Jiangnan University, Wuxi , China. yxu@jiangnan.edu.cn

2 7, : %, 10, 13, / 46%vol, 3.66 kg /, 8.2 / (1980 ), 17.1 / (1979 ), 10.5 [1], / 4.18 /, 318%; 0.21 / 0.38 /, 80.95%, , 2014, 91, 2.68, ~ , ( ),, , 2014, 47, 产品质量是行业与企业永恒的主题, ; ; ( ) 16SrDNA, ( ), [2-5] [6-21],, , ( ) 169, ,, 20,, , 169,,, [22],,,,,,,,, +,,,,,,,,,,,,, ( ) ( ) ( ) ( ) ( ) ( ) ( ) ( ), 3 品质安全问题是行业与企业面临的新课题,, 1988 [23,24], (EC), [25-39],

3 [40], 2010, EC [31,41-44],,, 863 [31,42,43,45-50], ( ),,,, , 1142, 387, 454, 146,, EC 170, 256, 243, 147, 91, 1004 ( ), EC,, , 250, 208, 167, 108,, ISI SciFinder wine safety ( ) , wine safety China wine safety Chinese ISI 20 23, 43, 7.73%; SciFinder 10 80, 90, 12.47%, EC,, 1991 EC 70 μg/l; EC 1200 μg/l 5 μg/l; 300 μg/l 55 μg/l; 130 μg/l 10~40 μg/l [51], 2000, 10, EC 53 μg/l 30 μg/l [51] EC, (WHO) (International Agency for Research on Cancer, IARC) , EC 2B 2A [52,53] 1985, EC, EC µg/l [54], EC [51, 54-59],, 8 8, 2, 6 2 6, 2, 1, 1 / - ; 1 ; 1 ; 1 ; 1,,,,,,,,, 参考文献 [1] World Health Organization, Department of Mental Health and Substance Abuse. WHO Global status report on alcohol 2004 [Z]. [2],. [Z] Jiangnan University, Beijing niulanshan. Identification material of " flavor characteristics of niulanshan liquor and the effects of two production technology on base liquor quality " [Z] [3],,. [Z] Jiangnan University, Yibin wu liang ye, Sichuan jian nan chun. Identification material of " flavor olfactory threshold measurement system of Chinese liquor "[Z] [4],. [Z] Jiangnan University, Shanxi xing hua cun. Identification material of " analysis technology system of flavors and key flavor of light aroma type fenjjiu liquor"[z] [5], ( ). [Z]

4 7, : 2623 Jiangnan University, Hengshui lao bai gan. Identification material of " analysis technology of flavors and key flavor microorganism of laobaigan type liquor"[z] [6] Fan H, Fan W, Xu Y. Characterization of key odorants in Chinese chixiang aroma-type liquor by gas chromatography olfactometry, quantitative measurements, aroma recombination, and omission studies [J]. J Agric Food Chem, 2015, 63 (14): [7] Chen S, Wang D, Xu Y. Characterization of odor-active compounds in sweet-type Chinese rice wine by aroma extract dilution analysis with special emphasis on sotolon [J]. J Agric Food Chem, 2013, 61: [8] Chen S, Xu Y, Qian MC. Aroma characterization of Chinese rice wine by gas chromatography olfactometry, chemical quantitative analysis, and aroma reconstitution [J]. J Agric Food Chem, 2013, 61: [9] Cheng P, Fan W, Xu Y. Quality grade discrimination of Chinese strong aroma type liquors using mass spectrometry and multivariate analysis [J]. Food Res Int, 2013, 54: [10] Du H, Fan W, Xu Y. Characterization of geosmin as source of earthy odor in different aroma type Chinese liquors [J]. J Agric Food Chem, 2011, 59: [11] Du H, Xu Y. Determination of the microbial origin of geosmin in Chinese liquor [J]. J Agric Food Chem, 2012, 60: [12] Fan W, Shen H, Xu Y. Quantification of volatile compounds in Chinese soy sauce aroma type liquor by stir bar sorptive extraction (SBSE) and gas chromatography mass spectrometry (GC MS) [J]. J Sci Food Agric, 2011, 91: [13] Fan W, Xu Y, Jiang W, et al. Identification and quantification of impact aroma compounds in 4 nonfloral Vitis vinifera varieties grapes [J]. J Food Sci, 2010, 75: S81 S88. [14] Gao W, Fan W, Xu Y. Characterization of the key odorants in light aroma type Chinese liquor by gas chromatography olfactometry, quantitative measurements, aroma recombination, and omission studies [J]. J Agric Food Chem, 2014, 62: [15] Xu Y, Fan W, Qian MC. Characterization of aroma compounds in apple cider using solvent-assisted flavor evaporation and headspace solid-phase microextraction [J]. J Agric Food Chem, 2007, 55: [16] Xu Y, Wang D, Fan W, et al. Traditional Chinese Biotechnology [C]. In Biotechnology in China II: Chemicals, Energy and Enviromen, 2010, 122: [17] Zhu B, Xu Y. A feeding strategy for tetramethylpyrazine production by Bacillus subtilis based on the stimulating effect of ammonium phosphate [J]. Bioproc Biosyst Eng, 2010, 33: [18] Zhang WX, Qiao ZW, Tang YQ, et al. Analysis of the fungal community in Zaopei during the production of Chinese Luzhou-flavour liquor [J]. J Inst Brew, 2007, 113: [19] Zhang WX, Wu ZY, Zhang QS, et al. Combination of newly developed high quality Fuqu with traditional Daqu for Luzhou-flavor liquor brewing [J]. World J Microbiol Biotechnol, 2009, 25: [20],,,. [C]., 2011, pp Xu Y, Fan WL, Wang HY, et al. Research advance in flavor-oriented analytic technology for liquor-making [C]. key technology research progress of Chinese liquor-the first academic conference on Chinese liquor, 2011, pp [21],,,. [J]., 2012, 211: Xu Y, Fan WL, Wu Q, et al. Research Advance in Flavor-oriented Analytic Technology for Liquor-making[J]. Liquor Making Sci Technol, 2012, 211: [22]. 169 [J]., 2013, 2: Qian GJ. Speech at the acceptance meeting of "169 Project of Chinese Liquor"[J]. Liquor Making Sci Technol, 2013, 2: [23],. [J]., 1988, 5: Zhao GA, Liu JQ. Research of ethyl carbamate in wines[j]. Food Ferment Ind, 1988, 5: [24] [Z]. :, Simple quick detection of ethyl carbamate in alcoholic beverages by gas chromatography [Z]. Results report OF Jia South Medicine Science Project: Taiwan, [25],,,. [J]., 1991, 10: Yuan SS, Liu YM, Wang LX, et al. Determination methods of ethyl carbamate in alcoholic beverages [J]. J Food Sci Biotechnol, 1991, 10: [26],,. [J]., 1996, 15: Ma yp, Sun SC, Deng FQ. Quantitative determination of ethyl carbamate in chinese liquor by two-dimensional chromatography[j]. J Instrum Anal, 1996, 15: [27],. GC/MS [J], 2004, 33(5): Wu PG, Chen ZD. Determination of ethyl carbamate in wines by solid phase extraction combined with GC/MS[J]. J Hyg Res, 2004, 33(5): [28],,,. - [J]., 2007, 19: Zhou PP, Zhao YF, Zhang G, et al. Determination of ethyl carbamate in wine by stable isotope dilution gas chromatography mass spectrometry [J]. Chin J Food Hyg, 2007, 19: [29]. [D]. :, Liang XH. Study on ethyl carbamate levels in chinese table wine[d]. Baoji: North West Agricultural and Forestry University, [30],,, [J]., 2011, 45: Wu PG, Yang DJ, Shen XH, et al. In 2010, investigation and analysis of ethyl carbamate in fermented foods in hangzhou 2010[J]. Chin J Prevent Med, 2011, 45: [31]. [D]. :, Shi BB. Studies on ethyl carbamate of chinese liquor[d]. Wuxi: Jiangnan University, 2012.

5 [32] Zhang Y, Zhang J. Optimization of headspace solid-phase microextraction for analysis of ethyl carbamate in alcoholic beverages using a face-centered cube central composite design [J]. Anal Chim Acta, 2008, 627: [33] Centre for Food Safety, Food and Enviromental Hygiene Department. Guidelines to the trade on reducing the level of ethyl carbamate (EC) in alcoholic beverages during storage and transport [Z], [34] Centre for Food Safety (CFS), Food and Enviromental Hygiene Department. CFS risk assessment studies report No. 39. ethyl carbamate in local fermented foods [Z], [35] Wu P, Pan X, Wang L, et al. A survey of ethyl carbamate in fermented foods and beverages from Zhejiang, China [J]. Food Control, 2012, 23: [36] Fu ML, Liu J, Chen QH, et al. Determination of ethyl carbamate in Chinese yellow rice wine using high-performance liquid chromatoraphy with fluorescence detection [J]. Int J Food Sci Technol, 2010, 45: [37] Liu J, Xu Y, Zhao GA. Rapid determination of ethyl carbamate in Chinese rice wine using headspace solid-phase microextraction and gas chromatography mass spectrometry [J]. J Inst Brew, 2012, 118: [38] Wang R, Wu H, Zhou X, et al. Simultaneous detection of ethyl carbamate and urea in Chinese yellow rice wine by HPLC-FLD [J]. J Liquid Chromatogr Relate Technol, 2014, 37: 39. [39] Wang SHW, Sheu FC, Gow CY. Determination of ethyl carbamate in alcoholic beverages retailed in Taiwan [J]. J Chin Agric Chem Soc, 1997, 35: [40] SN [S]. SN Determination Method of Ethyl Carbamate Residues in exported liquor [S]. [41],,,. [J]., 2011, 38: Wu JM, Hong RZ, Ma LH, et al. Determination and control of ethyl carbamate in the production of rice wine [J]. Niangjiu, 2011, 38: [42],,. [J]., 2012, 33: Fan WL, Xu Y, Shi BB. Evolvement of ethyl carbamate and urea from fermented grains in the fermentation process of Chinese liquor [J]. Sci Technol Food Ind. 2012, 33: [43]. [D]. :, Zhang ZY. Research of ethyl carbamate during the distillation and storage of Chinese liquors. [D]. Wuxi: Jiangnan University, [44],. [J]., 2012, 213: Fan WL, Xu Y. Review of functional factors and quality safety factors of Baijiu (Chinese liquor) [J]. Liquor Making Sci Technol, 2012, 213: [45] Xu X, Gao Y, Cao X, et al. Derivatization followed by gas chromatography-mass spectrometry for quantification of ethyl carbamate in alcoholic beverages [J]. J Sep Sci, 2012, 35: [46],,,. 5 HPLC [J]., 2013, 34: Wen YZ, Fan WL, Xu Y, et al. Quantification for 5 selected biogenic amines in fermentation and distillation of Chinese liquor by HPLC [J]. Sci technol of food Ind. 2013, 34: [47],,,. [C]. 2014, 2014, pp Wu CC, Fan WL, Xu Y, et al. Research of heavy metal ion manganese, cadmium, chromium, lead in Chinese liquor [C]. Health and safety and ecology brewing technology research of Chinese liquor--the 2nd Chinese Liquor Technology Symposium, 2014, pp [48],. [C]. 2014, 2014, pp Fan WL, Xu Y. Current practice and future trends of exogenous hazardous compounds in international and domestic liquors [C]. Health and safety and ecology brewing technology research of Chinese liquor-the 2nd Chinese Liquor Technology Symposium, 2014, pp [49],. [C]. 2014, 2014, pp Fan WL, Xu Y. Current practice and future trends of endogenous hazardous compounds in international and domestic liquors. Health and safety and ecology brewing technology research of Chinese liquor-the 2nd Chinese Liquor Technology Symposium, 2014, pp [50],., 5 [J]., 2015, 36: Fan WL, Xu Y, Wen YZ. Quantification for 5 selected biogenic amines in fermentation and distillation of Chinese liquor by HPLC [J]. Sci technol of food Ind. 2015, 36: [51] Weber JV, Sharypov VI. Ethyl carbamate in foods and beverages: A review [J]. Environ Chem Lett, 2009, 7: [52] Baan R, Straif K, Grosse Y, et al. Carcinogenicity of alcoholic beverages [J]. Lancet Oncol, 2007, 8: [53] De Stefani E, Boffetta P, Deneo-Pellegrini H, et al. The effect of smoking and drinking in oral and pharyngeal cancers: a case-control study in Uruguay [J]. Cancer Letters, 2007, 246: [54] EFSA. Ethyl carbamate and hydrocyanic acid in food and beverages Scientific opinion of the panel on contaminants [J]. EFSA J, 2007, 551: [55] Zealand FSAN. Ethyl carbamate in Australian foods [S]. [56] Lachenmeier DW, Lima MC, Nóbrega IC, et al. Cancer risk assessment of ethyl carbamate in alcoholic beverages from Brazil with special consideration to the spirits cachaça and tiquira [J]. BMC Cancer, 2010, 10: 266. [57] Weber JV, Sharypov VI. Ethyl carbamate in foods and beverages a review [M]. Climate change, intercropping, pest control and beneficial microorganisms. Springer Netherlands, 2009: [58] Lachenmeier DW, Kanteres F, Kuballa T, et al. Ethyl carbamate in alcoholic beverages from Mexico (tequila, mezcal, bacanora, sotol) and Guatemala (cuxa): Market survey and risk assessment [J]. Inter J Environ Res Public Health, 2009, 6: [59] EFSA. Ethyl carbamate and hydrocyanic acid in food and beverages Scientific opinion of the panel on contaminants [J]. EFSA J, 2007, 551: ( 责任编辑 : 杨翠娜 )

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