VAPOR-LIQUID EQUILIBRIUM DATA COLLECTION

Transcription

1 J. Gmehling U. Onken VAPORLIQUID EQUILIBRIUM DATA COLLECTION Esters Supplement 2 Chemistry Data Series Vol. I, Part 5b Published by DECHEMA Gesellschaft fur Chemische Technik und Biotechnologie e. V. Executive Editor: Gerhard Kreysa

2 Bibliographic information published by Die Deutsche Bibliothek Die Deutsche Bibliothek lists this publication in the Deutsche Nationalbibliographie; detailed bibliographic data is available on the Internet at ISBN: DECH EMA Gesellschaft for Chemische Technik und Biotechnologie e. V. Postfach , D661 Frankfurt am Main, Germany, 22 Dieses Werk ist urheberrechtlich geschutzt. Alle Rechte, auch die der Obersetzung, des Nachdrucks und der Vervielfi:Htigung des Buches oder Teilen daraus sind vorbehalten. Kein Teil des Werkes darf ohne schriftliche Genehmigung der DECHEMA in irgendeiner Form (Fotokopie, Mikrofilm oder einem anderen Verfahren), auch nicht for Zwecke der Unterrichtsgestaltung, reproduziert oder unter Verwendung elektronischer Systeme verarbeitet, vervielfaltigt oder verbreitet werden. Die Herausgeber Obernehmen for die Richtigkeit und Vollstandigkeit der publizierten Daten keinerlei Gewahrleistung. This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, including those of translation, reprinting, reproduction by photocopying machine or similar means. No part of this work may be reproduced, processed or distributed in any form, not even for teaching purposes by photocopying, microfilm or other processes, or implemented in electronic information storage and retrieval systems without the written permission of the publishers. The publishers accept no liability for the accuracy and completeness of the published dat This volume of the Chemistry Data Series was printed using acidfree paper. Technical Production: Mitterweger & Partner, Plankstadt

3 VaporLiquid Equilibrium Data Collection 5b Esters Supplement 2 Tables and diagrams of data for binary and multicomponent mixtures up to moderate pressures. Constants of correlation equations for computer use. J. Gmehling, U. Onken Technische Chemie Universiti:it Oldenburg

4 5b Esters Systems with: Allyl Acetate Benzyl Acetate Butanoic Acid1,2,Propanetriyl Ester Butyl Acetate tertbutyl Acetate Butyl Formate Butyl Methacrylate NButyl Octadecanoate Butyl Propionate secbutylacrylate GammaButyrolactone Epsilon Caprolactane Dibutyl Phthalate Diethyl carbonate Diethyl Oxalate Dimethyl Carbonate Dimethyl Glutarate Dinonyl Phthalate 1,Dioxolan2ne <Ethylene Carbonate> Ethan Acetate Ethyl Acetate Ethyl Butyrate Ethyl Formate Ethyl Propinate Ethyl Stearate Ethyl Trichloroacetate Hexyl Acetate lsobronyl Formate Isobutyl Acetate Isobutyl Formate Isobutyl lsobutyrate lsopentyl Acetate Isopropyl Acetate Methyl Acetate Methyl Acrylate Methyl Butyrate Methyl Formate Methyl Methacrylate Methyl Palmitate Methyl Perfluorobutyrate Methyl Propionate Methyl Stearate Monomethyl Adipate Pentyl Acetate Propyl Acetate Propyl Butyrate Propyl Formate Propyl Propionate 1,2Propyleneglycol Diacetate Tributyl Phosphate Vinyl Acetate Vinyl Propionate

5 vi SUBJECTS OF VOLUME I The subjects of Volume I in the Chemistry Data Series (S) are: Subtitle Vol. I, Part Aqueous Systems 1 1a 1b Organic Hydroxy Compounds Alcohols Alcohols and Phenols 2a 2b 2c 2d 2e 2f Aldehydes, Ketones, Ethers /4 Aldehydes Ketones Et hers a b 4a 4b Carboxylic Acids, Anhydrides, 5 Esters Carboxylic Acids, Anhydrides Esters Aliphatic Hydrocarbons C4C6 Aliphatic Hydrocarbons C7C18 Aliphatic Hydrocarbons C4C 5a 5b 6a 6b 6c 6d/e Aromatic Hydrocarbons 7 7a 7/b Halogen, Nitrogen, Sulfur and other compounds 8 8a A substance index to Volume I on ROM is available from the DECHEMA e. V. and its agents.

6 vii AUTHORS' PREFACE With this volume we have pleasure in publishing a new supplement of the Vapor Liquid Equilibrium Data Collection for esters as DECHEMA Chemistry Data Series Volume I Part 5b. The data in this book are taken from the Dortmund Data Bank and are available in electronic form. The Dortmund Data Bank covers a wide range of properties in addition to the VLE, h E, yoo, for example: data bases of the vaporliquid equilibria of low boiling substances (HPV), azeotropic data (AZD), gas solubilities (GLE), solidliquid equilibria (SLE) and a pure component property data base(pcp). Data in electronic form can be obtained from DDBST GmbH, Oldenburg, Germany or DECHEMA e. V., Frankfurt am Main. Data collections for inhouse use are available from DDBST GmbH; DECHEMA e.v.; FIZ Chemie GmbH, Berlin, Germany and Aspen Technology, Inc., Cambridge, Massachusetts, USA. DDBST GmbH can also supply a large program system well suited to handling the data in the data banks. Online versions of the database are hosted by ST N International (Columbus, Ohio, USA; Karlsruhe, Germany and Tokyo, Japan) and DECHEMA e. V. (via the Internet). We would like to thank J. Krafczyk and J. Menke for computer programming assistance in order to allow publication of data determined under nonisotherm and nonisobaric conditions. In addition we would like to sincerely thank all those colleagues who have both supported and continue to support the endeavours of the thermodynamic group at the University of Oldenburg by delivering VLE data from their research. At this juncture we would like to request other colleagues in this field to send us unpublished data and reprints of their publications on thermophysical properties. Oldenburg, November 22 J. Gmehling U. Onken

7 viii EXECUTIVE EDITOR'S PREFACE The aim of DECHEMA e.v., The Society for Chemical Technology and Biotechnology when it was founded in 1926 was to improve cooperation between chemist and engineer. As the importance of mathematical modelling, computer simulation and optimisation became apparent in the midnineteenseventies, this ideal resulted in the production and publication of collections of basic thermophysical data in both electronic and book form. This is not data that could have easily found a publisher outside the engineering societies, because of its sheer volume and limited circle of interest. By its sponsoring and publication of the DECHEMA Chemistry Data Series DECHEMA e. V. has been associated with these endevours for over a quarter of a century. Much of the original work to determine the values obtained was financed by the German Ministry of Research. lt is to be hoped that publication of this data collection by DECHEMA e. V. in the DECHEMA Chemistry Data Series will inspire other authors to consider publishing their collections of thermophysical dat DECHEMA e.v. is always pleased to assist colleagues from the thermophysical data community in preparing their results, their studies, their collections and their assessments for publication. DECHEMA e.v. is always prepared to enlarge the scope of the DECHEMA Chemistry Data Series and is thus pleased to hear from readers, designers, scientists and engineers of areas where thermophysical data is not available or scarce. We hope that the end user finds the data of utility and of interest. Frankfurt am Main, November 22 Gerhard Kreysa

8 ix CONTENTS Vol. I, Part 5b Subjects of Volume I VI Authors' Preface VII Executive Editor's Preface VIII Contents Volume I, Part 5b... IX Guide to Tables XI List of Symbols XXI References... XXIII Data Tables Esters Methyl Formate... 1,Dioxolan2ne <ethylene Carbonate>... 4 Ethyl Formate... 7 Methyl Acetate Dimethyl Carbonate Ethyl Trichloroacetate GammaButyrolactone Methyl Acrylate Vinyl Acetate Ethyl Acetate Methyl Propionate Propyl Formate Methyl Perfluorobutyrate Allyl Acetate Methyl Methacrylate Vinyl Propionate Butyl Formate Isobutyl Formate Butyl Formate Ethyl Propionate Isobutyl Formate Isopropyl Acetate Methyl Butyrate Propyl Acetate Diethyl Carbonate

9 X Epsilon Caprolactane Diethyl Oxalate Butyl Acetate tertbutyl Acetate Ethyl Butyrate Isobutyl Acetate Propyl Propionate secbutylacrylate Dimethyl Glutarate Dimethyl Adipate ,2Propyleneglycol Diacetate Butyl Prc :>ionate lsopentl Acetate P,mtyl Acetate Propyl Butyrate Butyl Methacrylate Hexyl Acetate Isobutyl lsobutyrate Benzyl Acetate Isobornyl Formate Tributyl Phosphate Benzyl Benzoate Butanoic Acid1,2,Propanetriyl Ester Dibutyl Phthalate Methyl Palmitate Methyl Stearate Ethyl Stearate NButyl Octadecanoate Dinonyl Phthalate Ternary Systems Appendix A: Pure Component Parameters Appendix B: Dimerization Constants of Carboxlic Acids Formula Index of Binary Systems Formula Index of Ternary Systems Alphabetical Index of Binary Systems Alphabetical Index of Ternary Systems

10 ... CI4Sn Tin Tetrachloride C4H5CI2 Ethyl Trichloroacetate C Hs2 Ethyl Acetate 2(}22, 21 CsH1o2 Butyl Formate Ethyl Propinate 192 Ethyl Propionate 2122 C6H,22 Butyl Acetate 8891 C1H,.2 Butyl Propionate lsopentyl Acetate CC I. Tetrachloromethane CHs2 Ethyl Formate 7 CHs Dimethyl Carbonate 81 C4Hs2 Ethyl Acetate 226 C8H,62 Hexyl Acetate 469 "T1 C,2H214P Tributyl Phosphate """' CH Br Tribromomethane (R2b) Methyl Acetate 2728 c CHCb Chloroform Methyl Acetate 294R C,2H214P Tributyl Phosphate :::1 CH2CI2 Dichloromethane CHs2 Methyl Acetate 56 Q. Ethyl Acetate 2728 >< CH1 Methyl Iodide CHs2 CHs2 C.H82 CHs2 CHs2 C Hs2 Methyl Acetate 78R CHN2 Nitromethane Methyl Acetate Ethyl Acetate :::1 CsH1o2 Methyl Propionate 272 """' Ethyl Propionate 18 en Isopropyl Acetate C/) Propyl Acetate 42 C2CIF 1,1,2Trichloro1,2,2 CHs2 Methyl Acetate 4 '1 Trifluoroethane (R1 1) a> C/) < 9

11 ... C2HBrCIF C2HCis C2H2CI2 C2H2C14 Pentachloroethane Trans1,2Dichloroethylene 1,1,2,2Tetrachloro Ethane CHs2 CHs2 C4H82 1Bromo1 Chloro2,2,2 Trifluoroethane CHa2 CHa2 C Ha2 CsH1o2 CaH1 22 Methyl Acetate 41 "'T1 '1...j Methyl Acetate 42 c Ethyl Acetate 214 Sll Methyl Acetate 4 ::J Ethyl Formate 8 Ethyl Acetate >< Propyl Formate Ethyl Propinate 224 ro Propyl Acetate 444 ::J Sll Ethyl Butyrate 4294 Propyl Propionate 4445 (J) 1,1,2,2Tetrachloroethane C7H,.2 Propyl Butyrate 46146R (JJ.+ C2HCI 1,1, 1Trichloroethane (R14a) CHa Dimethyl Carbonate 8285R C2HN Acetinitrile Ethyl Acetate 217 Acetonitrile C Ha2 CHa2 Ethyl Formate 9 Methyl Acetate 44 (JJ C Ha2 Ethyl Acetate R CsHa2 Methyl Methacrylate 294 Acetonitrille C.H62 Vinyl Acetate 179 C2H.CI2 1,2Dichloroethane CHa Dimethyl Carbonate 8689R CaH1 22 Butyl Acetate 92 C2H 2 Methyl Formate CHa2 Methyl Acetate C Ha2 Propyl Formate 2 CsH1o2 Propyl Acetate C2HsN2 Nitroethane CHs2 Methyl Acetate 45

12 C.Hs2 Ethyl Acetate 22 Methyl Propionate 27 CsH1o2 Ethyl Propinate 25 Isopropyl Acetate 1 Propyl Acetate 45 C2H68 Dimethyl Sulfoxide C Hs2 Ethyl Acetate 221 CHN Acrylonitrile C Hs2 Vinyl Acetate 18 CsHs2 Methyl Methacrylate 295 CH4 1,Dioxolan2ne CsHs Benzene 4 <ethylene Carbonate> C1Hs To luene 5 C8H, pxylene 6 CHsCI Chloro1 Propene C Hs2 Ethyl Acetate 222 CH6CI2 1,2Dichloropropane C1H,2 1,2Propyleneglycol Diacetate CHs2 Ethyl Formate CCI4 Tetrachloromethane 7 c C2H2CI4 1,1,2,2Tetrachloro Ethane 8 Ol C2HN Acetonitrile 9 :::J CH1Br Propyl Bromide 1 C Hs2 Ethyl Acetate 11 X CsH1 Diethyl Carbonate CsHsCI Chlorobenzene 15 OJ :::J CsHs Benzene Ol CsH, Diethyl Oxalate 222 CsH12 Cyclohexane 2 (/'J C1Hs To luene 2426 CIJ r+ Methyl Acetate CHBr Tribromomethane (R2b) 2728 '1 CHCI Chloroform 294R...1 CIJ "T1..

13 CJl Dichloromethane 56 "'T1 "' 1\) """'' CH1 Methyl Iodide 78R CH2CI2 CHN2 Nitromethane 9 C2CIF 1,1,2Trichloro1,2,2Trifluoroethane (R1 1) C2H BrCIF 1Bromo 1 Chloro2,2,2Trifluoroethane 41 :::J C2HCI5 Pentachloroethane 42 C2H2CI2 Trans1,2Dichloroethylene 4 X C2HN Acetonitrile 44 C2H42 Methyl Formate 1 :::J C2HsN2 Nitroethane Ol CH1Br Propyl Bromide 46 C4Hs2 Ethyl Acetate 5155R CJ) Methyl Acrylate 47 (/) Vinyl Acetate 485 C4Hs2 Propyl Formate 56 (/) 4 45 c: Ol CsHs2 Methyl Methacrylate 57 CsH1o 1Pentene 5859 CsH1o2 Propyl Acetate 6 C5H11CI 1Chloropentane 61 CsH12 Pentane 6264 C6H7N Aniline 65 CsH,o4 Acetaldehyde Diacetate 66 CsH1 2 1Hexene 67 CsH,22 Butyl Acetate 68 C6H1 CI 1Chlorohexane 69 CsH,4 Hexane 7G74

14 C1Ha To luene 75 C1H1s Heptane 76 CaH,o Ethyl benzene 77 axylene 78 C8H,N N,NDimethylaniline 79 c,2h2s Dodecane 8 CHa Dimethyl Carbonate CCI4 Tetrachloromethane 81 C2HCI 1,1,1Trichloroethane (R1 4a) 82SSR C2H.CI2 1,2Dichloroethane 8689R C4H6 Propylene Carbonate 9 C HaO Dimethyl Oxalate 91 CsH,o Diethyl Carbonate 9298R., C6H5CI Chlorobenzene , Benzene R c CaHa CsH,o 1Hexyne Sl) CH7Br Propyl Bromide 2Hexyne :::J Hexyne CO CaH12 Cyclohexane X 1Hexene C6H,4 Hexane OJ C1H,42 lsopentyl Acetate 147 :::J Sl) C1H1s Heptane , CaH,a Octane (/) c.h,2 Isopropyl benzene C,oH22 Decane 16 CO 1 Ethyl Formate 1.,1 (J.) CHs2 C/J r+ C/J

15 Methyl Acetate 46., '1...!.!::> ""'I Vinyl Acetate 181 CsHa2 Methyl Methacrylate 296 c C Hs2 CsH1o2 Ethyl Propinate 2628 tu Methyl Butyrate 41 :::J Propyl Acetate 4649R <D CH7NO N,NDimethylformamide (DMF) C4H82 Ethyl Acetate X CsH,22 Butyl Acetate 995R C,sH224 Dibutyl Phthalate 5 OJ :::J CH9N Trimethylamine c.h.o2 Ethyl Acetate 226 tu C.HsCis2 Ethyl Trichloroacetate CI4Sn Tin Tetrachloride < c.h. 1,Butadiene c.h.o2 Ethyl Acetate 227 en C.Hs2 Ethyl Acetate CsHs2 Methyl Acetate 5155R en GammaButyrolactone Benzene <D CsHs c, sh1 2 Diphenylmethane 17Q1 72 en Methyl Acrylate CHs2 Methyl Acetate 47 CsH1 2 Pentane 17 CsHs Benzene 174 C6H,. Hexane 175 C7H1 s Heptane 176 CaH,s Octane 177 C,oH22 Decane 178 Vinyl Acetate C2HN Acetonitrille 179 CsHN Acrylonitrile 18 CsHs2 Methyl Acetate 485 CH7Br Propyl Bromide 181

16 ... C Ha2 Ethyl Acetate 182 CsH1o2 Ethyl Propionate 18 Isopropyl Acetate 184 Propyl Acetate 185 CsHs Benzene 186 CsH,o4 Acetaldehyde Diacetate CsH1 22 Butyl Acetate 189 Isobutyl Acetate 19 CsH,. Hexane R C1Ha To luene 196 C1H,.2 Pentyl Acetate 197 CsH2o Nonane 198, Decane ,. C.Hs Propylene Carbonate CHs Dimethyl Carbonate 9 c:: C, oh22 c.hso. Dimethyl Oxalate CHs Dimethyl Carbonate 91 Dl C4Ha2 Ethyl Acetate CI4Sn Tin Tetrachloride 222, 21 :::J CCI4 Tetrachloromethane 226 Q. Dichloromethane 2728 >< CH2CI2 CHN2 Nitromethane C2HCis...,. Pentachloroethane 214 IJJ C2H2CI4 1,1,2,2Tetrachloro Ethane :::J Dl C2HN Acetinitrile 217 Acetonitrile R (J) C2H5N2 Nitroethane 22 C2H6S Dimethyl Sulfoxide CH5CI Chloro1 Propene 222.j 1 rj).. rj)

17 Ethyl Formate 11 "'T1 (11 "" ) ""' CH1NO N,NDimethylformamide (DMF) CH9N Trimethylamine 226 c CHs2 C4Hs 1,Butadiene 227 Q) C4Hs2 :::1... Vinyl Acetate 182 C4H9CI Butyl Chloride 2282 C4H11N Diethylamine 2122 >< CsHsN Pyridine 226 :::1 C5H11CI 1Chloropentane 27 OJ C6H5CI Chlorobenzene 28 Q) CsHs Benzene R < CsH7N Aniline (J) 2Methylpyridine 245 (J).. CsH1 2 Cyclohexane 24625R CsH122 Butyl Acetate 251 en CsH1CI 1Chlorohexane 252 CsH,4 Hexane 25 C1H14 Methylcyclohexane R C1H,42 lsopentyl Acetate 257 Pentyl Acetate 258 C1H1s Heptane R CaH1 oxylene 265 CaH,a Octane C9H2o Nonane 269 C,oH1 2 1,2,,4Tetrahydronaphthalene 27 c,2h2s Dodecane 271

18 ..., Methyl Propionate CHN2 Nitromethane 272 C2H5N2 Nitroethane 27 C1H,.2 Butyl Propionate Propyl Formate C2H2CI4 1,1,2,2Tetrachloro Ethane C2H42 Methyl Formate 2 CHs2 Methyl Acetate 56 CsH1o2 Propyl Acetate 278 CaHs Benzene C1H1 s Heptane 285 c.h,. Octane 286 C9H2o C.Ha2 Nonane 287 C.HgCI Butyl Chloride Ethyl Acetate 2282., c.hgno N, NDimethylacetamide CsH,22 Butyl Acetate 96 2Methylpropane CsH1 22 tertbutyl Acetate 428 c C4H1 C.H,N Diethylamine C Ha2 Ethyl Acetate 2122 CsHF12 C5H5N Methyl Perfluorobutyrate Pyridine Benzene ::::J C1F,. Perfluoromethylcyclohexane 29292R ('[) Ethyl Acetate 226 X CsHs C.H82 C5H1o2 Propyl Acetate 5 CsH,22 Butyl Acetate 97 OJ ::::J CsHa2 Allyl Acetate c.h,2o. Diethyl Maleate 29 Methyl Methacrylate C2HN Acetonitrile 294 < CHN Acrylonitrile 295 en CHs2 Methyl Acetate 57 CH1Br Propyl Bromide 296 ('[) CsH,o Cyclopentane J...J en r+ en

19 C5H,o Benzene 298., (11 "'J CO """' CsH,z Cyclohexane 299R c.h,. Hexane 45 c CsHs C1Hs To luene 6 C1H1s Heptane 7 :::J CsH,z Vinyloxyethyl Methacrylate 8 Cl> CaH,s Octane 9 X CsHzo Nonane 1 Vinyl Propionate CsH,oOz Vinyl Butyrate 1 1 ClJ :::J Cyclopentane Methyl Methacrylate 297 CsH,oOz Isopropyl Acetate 2 C5Hsz 1Pentene Methyl Acetate 5859 en C5H,oz Butyl Formate CI4Sn Tin Tetrachloride 1214 (JJ.+ CsH,oOz Isobutyl Formate 1516 Cl> CHsz C1Hs To luene 1 7 (JJ Ethyl Propinate CI4Sn Tin Tetrachloride 192 CzHzC14 1,1,2,2Tetrachloro Ethane 224 CzHsNOz Nitroethane 25 CH1Br Propyl Bromide 2628 Ethyl Propionate CI4Sn Tin Tetrachloride 2122 CHN2 Nitromethane 1 8 C HsOz Vinyl Acetate 18 Isobutyl Formate CsH,oOz Butyl Formate C1Hs To luene 29 Isopropyl Acetate CHNz Nitromethane CzHsNOz Nitroethane 1

20 ... :::l C4Hs2 Vinyl Acetate 184 CsH1o Cyclopentane 2 CsH1 2 Cyclohexane 4 CaH,4 Hexane 57 CaH1o mxylene 8 CaH1 a Octane 94 Methyl Butyrate CH1Br Propyl Bromide 41 Propyl Acetate CHN2 Nitromethane 42 C2H2CI4 1,1,2,2Tetrachloro Ethane 444 C5H1o Diethyl Carbonate C2H42 Methyl Formate C2HsN2 Nitroethane 45 CHs2 C4Hs2 Methyl Acetate 6 '"T1 """'' CH1Br Propyl Bromide 4649R Vinyl Acetate 185 c C4Ha2 Propyl Formate 278 DJ C5H5N :::l Pyridine 5 Benzene 5154 Cyclohexane 55, 57R >< CaHs CsH1 2 C1H1 4 C1H1 s CsH1 Methylcyclohexane 586R Heptane 61 IJJ mxylene 62 CaH1 24 Diethyl Maleate 6 C9H1 2 C9H2o CHs2 DJ """'' Isopropyl benzene 6467 (/) Nonane 68 Ethyl Formate ()1 CHs Dimethyl Carbonate 9298R.1 CO CJ).+ CJ)

21 ()) CsHs Benzene 69 "'T1 1 CsH,oO Diethyloxalate 7G72 CsH1 2 Cyclohexane 774 c C6H1 4 Hexane 7576 C1H1 s Heptane 77 ::J c.. C5H11CI 1Chloropentane CsHs2 Methyl Acetate 61 >< Ethyl Acetate 27 CaH,a Octane 7879 C Hs2 C5H12 Pentane CsHs2 Methyl Acetate 6264 lll Methyl Acrylate 17 C2sH 2o. Dinonyl Phthalate 57 < C4Hs2 C5H122 Propyl Acetate CsH1 2 Cyclohexane 56 (/) CsH5CI Chlorobenzene CsHs2 Ethyl Formate 15 en.+ CsHsOs Dimethyl Carbonate 991 C Hs2 Ethyl Acetate 28 en '""'' ::J CsHs Benzene CsH Os 1,Dioxolan2ne <ethylene Carbonate> 4 CsHs2 Ethyl Formate CsHsOs Dimethyl Carbonate 11114R C Hs2 GammaButyrolactone Methyl Acrylate 174 Vinyl Acetate 186 C Ha2 Ethyl Acetate R Propyl Formate C5HF12 Methyl Perfluorobutyrate C5Ha2 Methyl Methacrylate 298 C5H,2 Propyl Acetate 5154

22 .. CsH,o Diethyl Carbonate 69 C6H,oz Epsilon Caprolactane 8 Epsilon Caprolactane 8182 CsH,zOz Butyl Acetate 98 C,zHz74P Tributyl Phosphate CzsH424 Dinonyl Phthalate 58 C6H7N Aniline CHsz Methyl Acetate 65 C4Haz Ethyl Acetate Methylpyridine C4Haz Ethyl Acetate 245 CsH1o 1Hexyne CHs Dimethyl Carbonate Hexyne CHs Dimethyl Carbonate CsH12 CsH,o4 CsH12 Hexyne CHs Dimethyl Carbonate "Tl Epsilon Caprolactane Benzene 8 """'' Epsilon Caprolactane Benzene 8182 c:: CsHs CsHs Vinyl Butyrate CsHaOz Vinyl Propionate 11 DJ Acetaldehyde Diacetate Diethyl Oxalate CHsz C4Hsz CHsz Methyl Acetate 66 :::J Vinyl Acetate Ethyl Formate 222 X CaHa Methyl Salicylate 887 Diethyloxalate CsH1 Diethyl Carbonate 772 aj :::J Cyclohexane Ethyl Formate 2 DJ CHs Dimethyl Carbonate < CHsz C4Haz C5Haz Ethyl Acetate 24625R (/) Methyl Methacrylate 299R CsH1o2 Isopropyl Acetate 4 1 Propyl Acetate 55, 57R (X).. en.+ en

23 CsH1 s Diethyl Carbonate 774 'T1 '1 (X) CsH1 22 CsH1 22 Propyl Acetate 56 Butyl Acetate 994 c C2sH 24 Dinonyl Phthalate 59 Cl 1Hexene CsHs2 Methyl Acetate 67 ::J CsHsOs Dimethyl Carbonate c. CsH,22 Butyl Acetate CI4Sn Tin Tetrachloride 8891 >< C2H4CI2 1,2Dichloroethane 92 _., CsHs2 Methyl Acetate 68 CO CH7NO ::J N,NDimethylformamide (DMF) 995R Cl C Hs2 Vinyl Acetate 189 < C Hs2 Ethyl Acetate 251 CJ) c.hgno N, NDimethylacetamide 96 (/J... C5H5N Pyridine 97 CsHs Benzene 98 (/J 1\) """'' CsH1 2 Cyclohexane 994 CsH,. Hexane 41 C7H8 To luene 424R C7H,. Methylcyclohexane 4446R CsH, Ethylbenzene 4749 oxylene c.h,. 1ctyne ctyne C8H1 6 1ctene 4242 C9HsN22 2,4To luene Diisocyanate 424 CgH,o AlphaMethyl Styrene

24 tertbutyl Acetate C H1o 2Methylpropane 428 Ethyl Butyrate C2H2C14 1,1,2,2Tetrachloro Ethane 4294 Isobutyl Acetate c.hs2 Vinyl Acetate 19 C7Ha To luene 41 C7H1 s Heptane 42 CaH1 s 1ctene 4 Propyl Propionate C2H2CI4 1,1,2,2Tetrachloro Ethane 4445 C7H1 s Heptane 4647 CsH2o Nonane 4849 C6H1CI 1Chlorohexane CHs2 Methyl Acetate 69 C Ha2 Ethyl Acetate 252 CsH1 Hexane CHs2 CHs C Hs2 Methyl Acetate 774, Dimethyl Carbonate "'"" Methyl Acrylate 175 c Vinyl Acetate R!l) C.Ha2 Ethyl Acetate 25 :::J C5Ha2 Methyl Methacrylate 45 C5H1o2 Isopropyl Acetate 57 X C5H1 Diethyl Carbonate 7576 CsH1 22 Butyl Acetate 41 (JJ C22H442 NButyl Octadecanoate 5556 :::J!l) C7F14 Perfluoromethylcyclohexane C5HF72 Methyl Perfluorobutyrate 29292R < C7Ha To luene CH4 1,Dioxolan2ne <ethylene Carbonate> 5 (/) CHs2 Ethyl Formate 2426 C Hs2 h C/) Methyl Acetate 75 '1 Vinyl Acetate 196 (X) C/) w

25 C7H,22 CsHa2 Methyl Methacrylate 6 "T1 1 ()) Isobutyl Formate 29 c:: CsH1 2 Butyl Formate 17 CsH122 Butyl Acetate 424R Dl Isobutyl Acetate 41 ::::J CaH1 s2 Isobutyl lsobutyrate 47 >< C9H,o2 Benzyl Acetate 471 c,.h,2o2 Benzyl Benzoate 497 secbutylacrylate CaH,s 1ctene 44 (lj ::::J C1H,2 Dimethyl Glutarate CaH,.4 Dimethyl Adipate 441 Dl Monomethyl Adipate CaH,.4 Dimethyl Adipate 442 < 1,2Propyleneglycol Diacetate CsHsCI2 1,2Dichloropropane (/') C1H,. Methylcyclohexane Ethyl Acetate R fj) CsH1o2 Propyl Acetate 586R C Ha2 CsH122 Butyl Acetate 4446R fj) C1H,.o2 Butyl Propionate CI4Sn Tin Tetrachloride j:>., C Ha2 Methyl Propionate lsopentyl Acetate CI4Sn Tin Tetrachloride CsHsOs Dimethyl Carbonate 147 C Ha2 Ethyl Acetate 257 Pentyl Acetate c.h62 Vinyl Acetate 197 C Ha2 Ethyl Acetate 258 CaH1o oxylene CsH2o Nonane Propyl Butyrate C2H2CI4 1,1,2,2Tetrachloroethane 46146R C1H1 s Heptane

26 C9H2o Nonane 466 C1H,.2 Pentyl Acetate C9H2o Nonane 46 C1H1s Heptane CHs2 Methyl Acetate 76 CHs Dimethyl Carbonate C Hs2 Methyl Acrylate 176 C.Ha2 Ethyl Acetate R Propyl Formate 285 C5Ha2 Methyl Methacrylate 7 CsH1o2 Propyl Acetate 61 CsH,o Diethyl Carbonate 77 c.h,22 Isobutyl Acetate 42 Propyl Propionate 4647 "T1 C1H,.2 Propyl Butyrate C,2H27 P Tributyl Phosphate c C2sH 2o. Dinonyl Phthalate 51 CaHa Methyl Salicylate C6H1. Diethyl Oxalate 887 :::J Ethyl benzene Methyl Acetate 77 Q. Butyl Acetate 4749 >< CaH,o C8H11N CHs2 c.h,2o2 mxylene CsH1o2 Isopropyl Acetate 8 oxylene CHs2 C.Ha2 c.h,2o2 Propyl Acetate 62 ro :::J Methyl Acetate 78 Ethyl Acetate 265 Butyl Acetate (/) C1H,.2 Pentyl Acetate pxylene CH4 1,Dioxolan2ne <ethylene Carbonate> 6 1 N,NDimethylaniline Methyl Acetate (X) 1 CHs2 79 en r+ en

27 ... CaH12s Vinyloxyethyl Methacrylate CsHa2 Methyl Methacrylate 8 "'T1 1 CO ) CaH1 2 Diethyl Maleate CsH1o2 Propyl Acetate 6 Diethyl Maleate CsHa2 Allyl Acetate 29 c CsH14 1ctyne CsH1 22 Butyl Acetate m ctyne CsH122 Butyl Acetate :::J C8H142 Butyl Methacrylate CaH1sOs 2Hydroxy2MethyiProp ionic Acid Butyl Ester C8H144 Dimethyl Adipate C1H124 Dimethyl Glutarate 441 >< Monomethyl Adipate 442 CaH1s 1ctene CsH1 22 Butyl Acetate 4242 :::J Isobutyl Acetate m C1H122 secbutylacrylate 44 CsH1s2 Hexyl Acetate CC14 Tetrachloromethane 469 (j) Isobutyl lsobutyrate C7HB Toluene 47 CaH1sOs 2Hydroxy2MethyiPropionic CsH142 Butyl Methacrylate Acid Butyl Ester CaH1s Octane CsHsOs Dimethyl Carbonate C/J C4Hs2 Methyl Acrylate 177 C Hs2 Ethyl Acetate Propyl Formate 286 CsHa2 Methyl Methacrylate 9 CsH1o2 Isopropyl Acetate 94 CsH1oOs Diethyl Carbonate 7879 C2sH424 Dinonyl Phthalate 51 1 C9HsN22 2,4Toluene Diisocyanate CsH122 Butyl Acetate 424 C/J C9H1 AlphaMethyl Styrene CsH122 Butyl Acetate C9H1o2 Benzyl Acetate C7HB Toluene 471 c14h122 Benzyl Benzoate 47247

28 ::::1 c.h,2 Isopropyl benzene CHs Dimethyl Carbonate C5H1 a2 Propyl Acetate 6467 CsH2o Nonane C Hs2 Vinyl Acetate 198 C.Ha2 Ethyl Acetate 269 Propyl Formate 287 C5He2 Methyl Methacrylate 1 CsH1 a2 Propyl Acetate 68 C6H122 Propyl Propionate 4849 C1H,.2 Pentyl Acetate Propyl Butyrate 466 C,oH12 C,oH,s C,oH22 C, H,a2 c,2h2s C,2H27 P c,h1 2 c,.h,2o2 C1H,.2 Pentyl Acetate 46 1,2,,4Tetrahydronaphthalene C4H82 Ethyl Acetate 27, Limonene Isobornyl Formate 474 "'"'I Decane CHs Dimethyl Carbonate 16 c C, H,a2 C Hs2 Methyl Acrylate 178 ::::1 Vinyl Acetate 199 Isobornyl Formate C1 H1 s Limonene 474 Dodecane Methyl Acetate 8 X Ethyl Acetate 271 Tributyl Phosphate Diphenylmethane Benzyl Benzoate CHs2 C He2 CCI4 Tetrachloromethane CHCI Chloroform Benzene < Heptane (/) GammaButyrolactone 17Q1 72 en.+ To luene 497 (11 Benzyl Acetate (X) en...! CsHs C1H1 s C4H62 C1He C.H,2

29 C,sH2sOa Butanoic Acid1,2, C2,Haa Hexanoic Acid 1,2,Propanetriyl Ester 498 n 1 ()) Propanetriyl Ester ()) """' C21HsoOa Octanoic Acid, 1,2,Propanetriyl Ester 499 c: C1aH224 Dibutyl Phthalate CH7NO N,NDimethylformamide (DMF) 5 ::::s C,aH4 Dibutyl Sebacate 51 C1 1H42 Methyl Palmitate C, eha2 Methyl Stearate 52 C, ah Dibutyl Sebacate C,aH22 Dibutyl Phthalate 51 >< C,aHa Octadecane C2aH.2o. Dinonyl Phthalate 512 ::::s C,eH2 Bis (lsoprophylphenyl) Methane C2oH42 Ethyl Stearate 54 OJ C1eHa2 Methyl Oleate C, eha2 Methyl Stearate 5 C,eHa2 Methyl Stearate C1 1H42 Methyl Palmitate 52 c,shao2 Methyl Oleate 5 (J) C2oH o2 Ethyl Stearate C, eh2 Bis (lsoprophylphenyl) Methane 54 (/).+ C2,Haa Hexanoic Acid 1,2, C,sH2aOa Butanoic Acid1,2,Propanetriyl Ester 498 Propanetriyl Ester c22h442 NButyl Octadecanoate C6H1 4 Hexane 5556 (/) C2aH.2o. Dinonyl Phthalate CsH12 Pentane 57 CaHa Benzene 58 < CaH1 2 Cyclohexane 59 C1H1a Heptane 51 CaH1 s Octane 51 1 C,aHa Octadecane 512 C21HsoOa Octanoic Acid, 1,2, Propanetriyl Ester C,sH2sOs Butanoic Acid1,2,Propanetriyl Ester 499

30 ::::1 CCI4 Tetrachloromethane C Ha2 Ethyl Acetate CaHs Benzene CaHsCI Chlorobenzene C Ha2 Ethyl Acetate 5658 CaHs Benzene CsHa2 Methyl Acetate 519 CH2CI2 Dichloromethane CsH12 Pentane CsHa2 Methyl Acetate 52 C2HsN Acetonitrile CsHa2 Methyl Acetate CH7Br Propyl Bromide C2H42 Methyl Formate CsHa2 Methyl Acetate C.H82 Propyl Formate 51 CsH1o2 Propyl Acetate 514 C Ha2 Propyl Formate CsH1o2 Propyl Acetate C2Hs2 Methyl Acetate C4H62 Vinyl Acetate CH7Br Propyl Bromide 52 CsHs2 Ethyl Formate CH7Br Propyl Bromide CsH1 2 Cyclohexane ::::1 Methyl Acetate CCI4 Tetrachloromethane CaHs Benzene 519 "T1 CH2CI2 Dichloromethane CsH1 2 Pentane 52 CsH7Br Propyl Bromide C2HN Acetonitrile CsHa2 Methyl Methacrylate c: C7Ha To luene C Hs2 Vinyl Acetate CH7Br Propyl Bromide 524 C7Ha To luene 5295 >< C Ha2 Propyl Formate C2H42 Methyl Formate CsH1o2 Propyl Acetate 51 C5H,o2 Propyl Acetate C2H42 Methyl Formate 514 CH7Br Propyl Bromide C2HsN Acetonitrile CsHa2 Methyl Acetate C2Hs2 Methyl Acetate C.H62 Vinyl Acetate 52 CsHs2 Methyl Acetate C Hs2 Vinyl Acetate 524 (/) CsHa2 Methyl Methacrylate CsHa2 Methyl Acetate CeH 12 roi (J) C Hs2 Vinyl Acetate (J) ( Cyclohexane CsHs2 Ethyl Formate (X)

31 C1Hs To luene CaHe2 Methyl Acetate , 1 <D...,. C He2 Vinyl Acetate 5455 C He2 Vinyl Acetate CH7Br Propyl Bromide C2He2 Methyl Acetate 52 c CaHe2 Methyl Acetate 524 CsHs2 Methyl Methacrylate 525 :::J C1Hs To luene 5455 >< C1Ha To luene CaHe2 Methyl Acetate 5295 C Hs2 Ethyl Acetate CCI4 Tetrachloromethane CeHsCI Chlorobenzene 5658 CsHs Benzene CCI4 Tetrachloromethane rof...,. CsH1 22 Butyl Acetate 548 :::J C1Hs To luene ,. CsH12 Cyclohexane CsHeN2 2Methyl Pyrazine (/) CeH1 Hexane CsHeN2 2Methyl Pyrazine Propyl Formate C2H 2 Methyl Formate CaHs2 Methyl Acetate 51 CsH1o2 Propyl Acetate C2H 2 Methyl Formate en CaHs2 Methyl Acetate 51 CsHsN2 2Methyl Pyrazine C Hs2 Ethyl Acetate CsH1 2 Cyclohexane CeH1 Hexane 547 CsHs2 Methyl Methacrylate CHs2 Methyl Acetate CH7Br Propyl Bromide C Hs2 Vinyl Acetate CH1Br Propyl Bromide 525 CsH1o2 Propyl Acetate C2H 2 Methyl Formate CaHs2 Methyl Acetate 514 C.H82 Propyl Formate CaHe2 Methyl Acetate C Hs2 Propyl Formate 51 CsH12 Pentane CaHe2 Methyl Acetate CH2CI2 Dichloromethane 52 CeH5CI Chlorobenzene C Hs2 Ethyl Acetate CCI4 Tetrachloromethane 5658 CsHe Benzene CCI4 Tetrachloromethane C.Hs2 Ethyl Acetate en...

32 CHs2 Methyl Acetate CC I. Tetrachloromethane 519 CsH122 Butyl Acetate C Ha2 Ethyl Acetate 548 C7H8 To luene C Ha2 Ethyl Acetate C6H1, Cyclohexane CHs2 Ethyl Formate CH7Br Propyl Bromide CsHsN2 2Methyl Pyrazine C Ha2 Ethyl Acetate Methylcyclopentane C, sh22 Dibutyl Phthalate C6H,. Hexane 558 CsH1 22 Butyl Acetate C.Ha2 Ethyl Acetate CsHs Benzene 548 CsH,. Hexane CsHsN2 2Methyl Pyrazine C Ha2 Ethyl Acetate 547 CsH1 2 Methylcyclopentane C,sH22 Dibutyl Phthalate 558 C7H8 To luene CHs2 Methyl Acetate CH7Br Propyl Bromide C Hs2 Vinyl Acetate 5295 "'T1 C4H62 Vinyl Acetate CH7Br Propyl Bromide 5455 C.H82 Ethyl Acetate CsHs Benzene C7H,.2 Pentyl Acetate C9H2o Nonane CaH1o oxylene c CaHa2 Methyl Benzoate CgH,o2 ptolyl Acid Methylester C, oh1o4 Dimethylterephthalate 557 CaH1o oxylene C7H,.2 Pentyl Acetate CgH2o Nonane :::l CgH,o2 pto lyl Acid Methylester C,oH,oO Dimethylterephthalate CsHa2 Methyl Benzoate 557 X C9H2o Nonane CsH1o oxylene C7H,.2 Pentyl Acetate C, oh,oo Dimethylterephthalate CsHa2 Methyl Benzoate C9H,2 ptolyl Acid Methylester 557 C,sH224 Dibutyl Phthalate CsH,. Hexane CsH1 2 Methylcyclopentane 558 DJ roi :::l DJ (/) CIJ... 1 c.o CIJ..

33 CI4Sn Tin Tetrachloride C4H5CI2 Ethyl Trichloroacetate )> Ethyl Acetate 222, 21 " :::J"' C5H12 Butyl Formate DJ C'" Ethyl Propinate 192 Ethyl Propionate 2122 (') DJ CsH1 22 Butyl Acetate 8891 CCI4 CH Br CHCI CH2CI2 Tetrachloromethane Tribromomethane (R2b) Chloroform Dichloromethane C4Ha2 C1H,42 Butyl Propionate ::J. lsopentyl Acetate >< CHs2 Ethyl Formate 7 CHs Dimethyl Carbonate 81 OJ Ethyl Acetate 226 ::J CaH1s2 Hexyl Acetate 469 DJ C,2H274P Tributyl Phosphate C4Ha2 Methyl Acetate 2728 CJ) (J) Methyl Acetate 294R C, 2H214P Tributyl Phosphate CHs2 CHs2 CHs2 Methyl Acetate 56 (J) 1 CO 1\) C4Hs2 Ethyl Acetate 2728 CH1 Methyl Iodide CHs2 Methyl Acetate 78R CHN2 Nitromethane CHs2 Methyl Acetate 9 C4Ha2 Ethyl Acetate Methyl Propionate 272 C5H,o2 Ethyl Propionate 18 Isopropyl Acetate Propyl Acetate 42

34 C2CIF 1,1,2Trichloro1,2,2 CHs2 Methyl Acetate 4 Trifluoroethane (R1 1) C2H BrCIF 1Bromo1Chloro CHs2 Methyl Acetate 41 2,2,2Trifluoroethane C2HCI5 Pentachloroethane CHs2 Methyl Acetate 42 C.H82 Ethyl Acetate 214 C2H2CI2 Trans1,2 CHs2 Methyl Acetate 4 Dichloroethylene C2H2CI4 1,1,2,2Tetrachloro CHs2 Ethyl Formate 8 Ethane C.Ha2 Ethyl Acetate Propyl Formate )> '" CsH,o2 Ethyl Propinate 224 Propyl Acetate 444 "'.+ c.h,2o2 Ethyl Butyrate 4294 Propyl Propionate ,1,2,2 C1H,.2 Propyl Butyrate R Tetrachloroethane C2HCI 1,1, 1Trichloroethane CHs Dimethyl Carbonate 8285R (R1 4a) >< C2HN Acetinitrile Acetonitrile C4H82 CHs2 C Ha2 (') :::J Ethyl Acetate 217 Ethyl Formate 9 OJ Methyl Acetate 44 :::J Ethyl Acetate R CsHa2 Methyl Methacrylate 294 en Acetonitrille Vinyl Acetate 179 (JJ.+ C2H.CI2 1,2Dichloroethane CHs Dimethyl Carbonate 8689R '1 Butyl Acetate 92 CO (JJ U) C Hs2 c.h,2o2

35 ..., C2H 2 C2H5N2 Methyl Formate Nitroethane.. Methyl Acetate 1 )> Propyl Formate 2 ""C ::r C5H1 2 Propyl Acetate er Methyl Acetate 45 CHs2 C.Ha2 CHs2 C.Ha2 C.Hs2 C Hs2 C5Ha2 Ethyl Acetate 22 () Methyl Propionate 27.. C5H1o2 Ethyl Propinate 25 :::J c.. Isopropyl Acetate 1 >< Propyl Acetate 45 C2H6S Dimethyl Sulfoxide Ethyl Acetate 221 CHN Acrylonitrile Vinyl Acetate 18 llj :::J Methyl Methacrylate 295 CH4 1,Dioxolan2ne CsHs Benzene 4 < <ethylene Carbonate> en C1Ha To luene 5 en CaH1o pxylene 6 CH5CI Chloro 1Propene Ethyl Acetate 222 en CH6CI2 1,2Dichloropropane C1H,2 1,2Propyleneglycol Diacetate C Hs '1 < CHe2 Ethyl Formate CCI4 Tetrachloromethane 7 C2H2C14 1,1,2,2Tetrachloro Ethane 8 C2HN Acetonitrile 9 CH1Br Propyl Bromide 1 C Hs2 Ethyl Acetate 11 C5H1 Diethyl Carbonate C6H5CI Chlorobenzene 15 CeHs Benzene 161 9

36 C6H, Diethyl Oxalate 222 CsH1 2 Cyclohexane 2 C1Ha To luene 2426 Methyl Acetate CH Br Tribromomethane (R2b) 2728 CHCI Chloroform 294R CH2CI2 Dichloromethane 56 CH 1 Methyl Iodide 7BR CHN2 Nitromethane 9 C2CisFs 1,1,2Trichloro1,2,2Trifluoroethane (R1 1) 4 C2H BrCIF 1Bromo1 Chloro2,2,2Trifluoroethane 41 C2HCI5 Pentachloroethane 42 ""C C2H2CI2 Trans1,2Dichloroethylene 4 ::J"' Q) C2HsN Acetonitrile 44 C".+ C2H42 Methyl Formate 1 (') C2HsN2 Nitroethane 45 Q) CH7Br Propyl Bromide 46 :::J Ethyl Acetate 5155R Methyl Acrylate X C.Hs2 C Ha2 Vinyl Acetate Propyl Formate 56 IJJ CsHa2 Methyl Methacrylate 57 :::J Q) 1Pentene 5859 CsH1o CsH1o2 Propyl Acetate 6 (/) C5H11CI 1Chloropentane 61 CsH1 2 CsH1N 47 )> CIJ.+ Pentane 6264 ()'1 Aniline 65 CO ()'1 CIJ

37 ..., CsH1oO Acetaldehyde Diacetate 66 )> CsH1 2 1Hexene 67 "' ::r Butyl Acetate 68 DJ " C6H1 CI 1Chlorohexane 69 CsH1 Hexane 7Q74 (") DJ C1He To luene 75 CsH1 22 C1H1s Heptane 76 :J CeH1o Ethyl benzene 77 >< oxylene 78 C8H11N N,NDimethylaniline c12h2s Dodecane 8 CsHsOs Dimethyl Carbonate CCI4 Tetrachloromethane 81 DJ.. C2HCI 1,1, 1Trichloroethane (R14a) 8285R C2H4CI2 1,2Dichloroethane 8689R (f) C.H6 Propylene Carbonate 9 C/J r+ C.H64 Dimethyl Oxalate 91 CsH1oOs Diethyl Carbonate 9298R C/J 79 OJ :J ()1 < (J) CsHsCI Chlorobenzene 991 CsHs Benzene 11114R CsH1o 1Hexyne Hexyne 12Q122 Hexyne CsH1 2 Cyclohexane Hexene CsH1 Hexane C1H142 lsopentyl Acetate 147

38 C1H1 s Heptane CeH1 e Octane CsH12 lsopropylbenzene C1oH22 Decane 16 CaH7Br Propyl Bromide CaHs2 Ethyl Formate 1 Methyl Acetate 46 C Hs2 Vinyl Acetate 181 CsHe2 Methyl Methacrylate 296 CsH1o2 Ethyl Propinate 2628 Methyl Butyrate 41 Propyl Acetate 4649R ""C CH7NO N,N C4H82 Ethyl Acetate Q) Dimethylformamide " (OM F).+ CsH1 22 Butyl Acetate 995R (') C1sH22o. Dibutyl Phthalate 5 Q) CaHsN Tri methylamine Ethyl Acetate 226 :::J C4H5Cia2 Ethyl Trichloroacetate CI4Sn Tin Tetrachloride c. 1,Butadiene Ethyl Acetate 227 X Ethyl Acetate CHs2 Methyl Acetate 5155R _.., C4H6 C Hs2 C He2 C He2 GammaButyrolactone CsHs Benzene OJ :::J Q) c1ah12 Diphenylmethane Methyl Acrylate CaHs2 Methyl Acetate CsH12 Pentane 17 (J) CsHs Benzene 174 en CsH14 Hexane )> <.+ '1 en C1H1 s Heptane 176 (..J

39 ::::r CaH,a C,oH22 Octane 177 )> Decane 178 Vinyl Acetate C2HN Acetonitrille 179 Q) "' CHN Acrylonitrile 18 CHs2 Methyl Acetate 485 (') CH7Br Propyl Bromide 181 Ethyl Acetate 182 :::J CsH1o2 Ethyl Propionate 18 >< Isopropyl Acetate 184 Propyl Acetate 185 C.Ha2 CsHs Benzene 186 CsH,oO Acetaldehyde Diacetate Q) CsH1 22 Butyl Acetate 189 C6H1 4 "" Q) (JJ :::J Isobutyl Acetate 19 (J) Hexane R (JJ To luene 196 C7H,.o2 Pentyl Acetate 197 (JJ C7H8 1 CO (X) CgH2o Nonane 198 C1 H22 De cane 199 C.Hs Propylene Carbonate CH6 Dimethyl Carbonate 9 C.H6 Dimethyl Oxalate CHs Dimethyl Carbonate 91 C Ha2 Ethyl Acetate CI4Sn Tin Tetrachloride 222, 21 CCI4 Tetrachloromethane 226 CH2CI2 Dichloromethane 2728 CHN2 Nitromethane C2HCI5 Pentachloroethane 214

40 :.. = ;;... C2H2CI4 1,1,2,2Tetrachloro Ethane C2HN Acetinitrile 217 Acetonitri le R C2H5N2 Nitroethane 22 C2H6S Dimethyl Sulfoxide 221 CHsCI Chloro1Propene 222 CHs2 Ethyl Formate 11 CH7NO N,NDimethylformamide (DMF) CH9N Trimethylamine 226 c.h. 1,Butadiene 227 C.H62 Vinyl Acetate 182 "'C C4H9CI Butyl Chloride 2282 :r Q) C.H,N Diethylamine 2122 " CsHsN Pyridine 226 (') C5H11CI 1Chloropentane 27 Q) C6H5CI Chlorobenzene 28 ::::J Benzene R C6H7N Aniline >< CsHs CsH1 2 2Methylpyridine 245 Cyclohexane 24625R (JJ CsH122 Butyl Acetate 251 ::::J CsH1 CI 1Chlorohexane 252 )> Q) CsH1 C1H1 4 Hexane 25 (/) Methylcyclohexane R C1H142 lsopentyl Acetate Pentyl Acetate 258 en en

41 .. C1H,a CaH, o CaH, a CsH2o C,oH,2 c,2h2s CHs2 Heptane R )> oxylene 265 "" '::!' Octane " Nonane ,2,,4Tetrahydronaphthalene 27 (") Dodecane 271 Methyl Propionate CHN2 Nitromethane 272 :::J C2HsN2 Nitroethane 27 >< C1H, 42 Butyl Propionate Propyl Formate C2H2CI4 1,1,2,2Tetrachloro Ethane C2H42 Methyl Formate 2 OJ :::J Methyl Acetate 56 CsH1o2 Propyl Acetate 278 CsHs C7H1e CsH1 s CaH2o Benzene (/) Heptane 285 en.+ Octane 286 Nonane 287 en > C4H9CI Butyl Chloride C4Ha2 Ethyl Acetate 2282 C4H9NO N,N C6H,22 Butyl Acetate 96 Dimethylacetamide C4H1o 2Methylpropane CeH, 22 tertbutyl Acetate 428 C4H11N Diethylamine C4Hs2 Ethyl Acetate 2122 CsHF12 Methyl Perfluorobutyrate CsHe Benzene C1F14 Perfluoromethylcyclohexane 29Q292R CsHsN Pyridine C4Hs2 Ethyl Acetate 226 CsH1o2 Propyl Acetate 5

42 c.h,2o2 Butyl Acetate 97 CsHa2 Allyl Acetate c.h,2o. Diethyl Maleate 29 Methyl Methacrylate C2HsN Acetonitrile 294 CHN Acrylonitrile 295 CHs2 Methyl Acetate 57 CsH1Br Propyl Bromide 296 CsH1o Cyclopentane 297 CsHs Benzene 298 CsH1 2 Cyclohexane 299R c.h,. Hexane 45 C1Hs C1H1 s To luene 6 " Heptane 7 Q) Vinyloxyethyl Methacrylate 8 " r+ Octane 9 C9H2o Nonane 1 (") Q) c.h,2s c.h,. Vinyl Propionate C6H1 2 Vinyl Butyrate 1 1 ::::l CsH1o Cyclopentane CsHa2 Methyl Methacrylate 297 CsH,o2 Isopropyl Acetate 2 >< 1Pentene CsHs2 Methyl Acetate 5859 ::::l CsH1o2 Butyl Formate CI4Sn Tin Tetrachloride 1214 OJ CsH1o2 Isobutyl Formate 1516 Q) To luene 17 Ethyl Propinate CI4Sn Tin Tetrachloride 192 (/) C1Hs C2H2CI4 1,1,2,2Tetrachloro Ethane 224 C2H5N2 Nitroethane 25 '> CH7Br Propyl Bromide 2628 )> ::J"'. (JJ r+ (JJ

43 .. Ethyl Propionate CI4Sn Tin Tetrachloride 2122 )>.. CHN2 Nitromethane 18 1J :::J"' C4Hs2 Vinyl Acetate 18 Q) C'" Isobutyl Formate CsH1o2 Butyl Formate C1Ha To luene 29 (") Isopropyl Acetate CHN2 Nitromethane C2HsN2 Nitroethane 1 :::J C4Ha2 Vinyl Acetate 184 X CsH1o Cyclopentane 2 CsH1 2 Cyclohexane 4 CsH,4 Hexane 57 CaH1o mxylene 8 Q) CsH1 a Octane 94 < Methyl Butyrate CH1Br Propyl Bromide 41 C/) en Propyl Acetate CHN2 Nitromethane ,1,2,2Tetrachloro Ethane 444 C2H2CI4 C2H42 Methyl Formate en Q) OJ :::J O'l 1\) C2H5N2 Nitroethane 45 CHs2 Methyl Acetate 6 CH1Br Propyl Bromide 4649R C4Hs2 Vinyl Acetate 185 C4Ha2 Propyl Formate 278 CsHsN Pyridine 5 CsHs Benzene 5154 CsH1 2 Cyclohexane 55, 57R C1H14 Methylcyclohexane 586R

44 C1H, s Heptane 61 CaH,o mxylene 62 CaH,2 Diethyl Maleate 6 C9H,2 Isopropyl benzene 6467 C9H2o Nonane 68 CsH,o Diethyl Carbonate CHs2 Ethyl Formate CHs Dimethyl Carbonate 9298R CsHs Benzene 69 CsH,o4 Diethyloxalate 772 C5H, CI CsH1 2 CsH,2D2 CsHsCI CsHs 1Chloropentane Pentane Propyl Acetate Chlorobenzene CsH1 2 CsHu C1H,s CaH,a CHs2 C4H82 CHs2 Cyclohexane 774 Hexane 7576 " =r Heptane 77 Octane 7879 ".+ Methyl Acetate 61 (') Ethyl Acetate 27 Methyl Acetate 6264 :::J Methyl Acrylate 17 C2sH 24 Dinonyl Phthalate 57 >< C.Hs2 CsH1 2 CHs2 Cyclohexane 56 Ethyl Formate CHs Dimethyl Carbonate 991 Ethyl Acetate 28 Benzene CH. 1,Dioxolan2ne <ethylene Carbonate> 4 en C Hs2 CHs2 CHsOs C Hs2 Ethyl Formate )> (JJ :::J CIJ.+ Dimethyl Carbonate R (J) GammaButyrolactone CIJ (..)

45 CsH1N Aniline 2Methylpyridine C.Ha2 Methyl Acrylate 174 )> Vinyl Acetate 186 "' :::J"' Ethyl Acetate R Ql "' Propyl Formate CsHF72 Methyl Pertluorobutyrate (') CsHs2 Methyl Methacrylate 298 Propyl Acetate 5154 :::J CsH1o Diethyl Carbonate 69 X CsH1o2 Epsilon Caprolactane 8 Epsilon Caprolactane CsH122 Butyl Acetate 98 OJ :::J C1 2H21 P Tri butyl Phosphate Ql C2sH 2o. Dinonyl Phthalate 58 CsH1o2 CHs2 Methyl Acetate 65 (/) C Hs2 Ethyl Acetate (/J Ethyl Acetate 245 C Hs2 CsH1o 1Hexyne CHs Dimethyl Carbonate (/J Ql > 2Hexyne CHs Dimethyl Carbonate 12Q1 22 Hexyne CHs Dimethyl Carbonate CsH1 2 Epsilon Caprolactane CsHs Benzene 8 Epsilon Caprolactane CsHs Benzene 8182 Vinyl Butyrate CsHs2 Vinyl Propionate 1 1 CsH1oO Acetaldehyde Diacetate CH62 Methyl Acetate 66 C4H62 Vinyl Acetate Diethyl Oxalate CHa2 Ethyl Formate 2Q22 CsHs Methyl Salicylate 887

46 .. Diethyloxalate CsH,o Diethyl Carbonate 772 CsH12 Cyclohexane CHs2 Ethyl Formate 2 CHs Dimethyl Carbonate C4H82 Ethyl Acetate 24625R C5Hs2 Methyl Methacrylate 299R CsH1o2 Isopropyl Acetate 4 Propyl Acetate 55, 57R C5H, Diethyl Carbonate 774 CsH,22 Propyl Acetate 56 C6H1 22 Butyl Acetate 994 C2sH424 Dinonyl Phthalate 59 " 1Hexene Methyl Acetate 67 CHs Dimethyl Carbonate " CsH,22 Butyl Acetate CI4Sn Tin Tetrachloride 8891 (') C2H4CI2 1,2Dichloroethane 92 CHs2 )> CHs2 Methyl Acetate 68 :J CH7NO N,NDimethylformamide (DMF) 995R Vinyl Acetate 189 >< C.H62 C.H82 Ethyl Acetate 251 c.h9no N, NDimethylacetamide 96 td :J CsHsN Pyridine 97 CsHs Benzene 98 CsH1 2 Cyclohexane 994 en C6H14 Hexane 41 C1Hs To luene 424R CJ) C7H14 Methylcyclohexane 4446R 1 """' (J) (J)

47 CsH,CI CsH1 Ethyl benzene 4749 )>.. oxylene '" ::::r CsH,. 1ctyne '" ctyne CaH,s 1ctene 4242 () CsHsN22 2,4Toluene Diisocyanate 424 AlphaMethyl Styrene ::::l tertbutyl Acetate C.H,o 2Methylpropane 428 X Ethyl Butyrate C2H2CI4 1,1,2,2Tetrachloro Ethane 4294 Isobutyl Acetate Vinyl Acetate 19 """'" OJ To luene 41 ::::l C1H1s Heptane 42 1ctene 4 < CsH,o C Hs2 C1Hs CaH,s Propyl Propionate C2H2CI. 1,1,2,2Tetrachloro Ethane 4445 (f) C1H1s Heptane 4647 en.. 1Chlorohexane CeH2o Nonane 4849 CHs2 Methyl Acetate 69 en > > C Hs2 Ethyl Acetate 252 C6H1 4 Hexane CHs2 Methyl Acetate 7Q74 CHs Dimethyl Carbonate c.hs2 Methyl Acrylate 175 Vinyl Acetate R C.H82 Ethyl Acetate 25 C5Hs2 Methyl Methacrylate 45 CsH,o2 Isopropyl Acetate 57 C5H,o Diethyl Carbonate 7576

48 C6H,22 Butyl Acetate 41 c22h442 NButyl Octadecanoate 5556 C7F,. Perfluoromethylcyclo C5HF12 Methyl Perfluorobutyrate 29292R hexane C1Ha To luene CH4 1,Dioxolan2ne <ethylene Carbonate> 5 CH52 Ethyl Formate 2426 Methyl Acetate 75 c.h6o2 Vinyl Acetate 196 CsHa2 Methyl Methacrylate 6 C5H,a2 c.h,6o2 Butyl Formate 17 Isobutyl Formate 29 )> ""C C6H122 Butyl Acetate 424R :::r Isobutyl Acetate 41 tu " Isobutyl lsobutyrate CeH1o2 Benzyl Acetate 471 (') tu Benzyl Benzoate 497 C1H,22 secbutylacrylate 1ctene 44 :::J Q. C1H,24 Dimethyl Glutarate c.h,.o. Dimethyl Adipate 441 >< Monomethyl Adipate c.h,.o. Dimethyl Adipate 442 1,2Propyleneglycol CH6CI2 1,2Dichloropropane Diacetate (JJ Methylcyclohexane Ethyl Acetate R :::J C7H,. c,.h,2o2 CaH,6 C Hs2 CsH1 a2 Propyl Acetate 586R Butyl Acetate 4446R (/) C1H,.2 Butyl Propionate CI4Sn Tin Tetrachloride C/J C4H82 Methyl Propionate C5H1 22 m lsopentyl Acetate CI4Sn Tin Tetrachloride J tu ""'I C/J

49 ..., C1H,.2 C1H1 s Pentyl Acetate Propyl Butyrate Pentyl Acetate Heptane CHs Dimethyl Carbonate 147 )> c.ha2 C Hs2 C4H82 CaH1o CsH2o C2H2CI4 C1H1 s CsH2o CsH2o CHs2 Ethyl Acetate 257 "'C ::r Vinyl Acetate 197 " Ethyl Acetate axylene (") Nonane ,1,2,2Tetrachloroethane 46146R ::J Heptane >< Nonane 466 Nonane 46 Methyl Acetate 76 OJ ::J CHs Dimethyl Carbonate c.h.o2 Methyl Acrylate , "< C.Hs2 Ethyl Acetate R (/) "< Propyl Formate 285 (/).+ CsHa2 Methyl Methacrylate 7 CsH1o2 Propyl Acetate 61 (/) > (X) C5H,o Diethyl Carbonate 77 c.h,2o2 Isobutyl Acetate 42 Propyl Propionate 4647 C1H,.o2 Propyl Butyrate C,2H214P Tri butyl Phosphate c2.h.2o. Dinonyl Phthalate 51 C8Ha Methyl Salicylate C.H,oO Diethyl Oxalate 887 CsH1 Ethyl benzene CH62 Methyl Acetate 77 c.h,2o2 Butyl Acetate 4749

50 mxylene CsH1 o2 Isopropyl Acetate 8 Propyl Acetate 62 axylene CHs2 Methyl Acetate 78 C Ha2 Ethyl Acetate 265 CsH1 22 Butyl Acetate 41()41 1 C7H,.2 Pentyl Acetate pxylene CH4 1,Dioxolan2ne <ethylene Carbonate> 6 CaH,N N,NDimethylaniline CHs2 Methyl Acetate 79 c.h,2o Vinyloxyethyl CsHa2 Methyl Methacrylate 8 Methacrylate c.h,2o. Diethyl Maleate CsH1 o2 Propyl Acetate 6 "'C Diethyl Maleate CsHa2 Allyl Acetate 29 =r c.h,. 1ctyne CsH1 22 Butyl Acetate C'" ctyne CsH122 Butyl Acetate r+ (") c.h,.o2 Butyl Methacrylate CaH,s 2Hydroxy2MethyiPropionic Acid Butyl Ester c.h,.o. Dimethyl Adipate C7H,2 Dimethyl Glutarate 441 :::J Monomethyl Adipate 442 c. CaH,s 1ctene CsH,22 Butyl Acetate 4242 X Isobutyl Acetate 4 C7H1 22 secbutyl acrylate 44 CaH,s2 Hexyl Acetate CCI4 Tetrachloromethane 469 :::J Isobutyl lsobutyrate C7Ha To luene 47 C8H,6 2Hydroxy2Methyl CaH,.o2 Butyl Methacrylate Propionic Acid Butyl Ester CaH,a Octane CHs Dimethyl Carbonate Methyl Acrylate 177 ) CJ) < C Hs2 )> IJJ, CJ) CJ) r+

51 :::r C.H82 Ethyl Acetate )> Propyl Formate 286 CsHa2 Methyl Methacrylate 9 " CsH1o2 Isopropyl Acetate 94 ro+ CsH1o Diethyl Carbonate 7879 (') c2sh 2o. Dinonyl Phthalate 51 1 C9H6N22 2,4Toluene Diisocya CsH1 22 Butyl Acetate 424 :J nate AlphaMethyl Styrene CsH1 22 Butyl Acetate >< C9H1o C9H,o2 C9H12 C9H2o Benzyl Acetate C1Ha c,.h,2o2 To luene 471 Benzyl Benzoate OJ Isopropyl benzene CHs Dimethyl Carbonate :J CsH1o2 Propyl Acetate 6467 Nonane C.H62 C Ha2 Vinyl Acetate 198 Ethyl Acetate 269 Propyl Formate 287 CsHa2 Methyl Methacrylate 1 (J) CsH12 Propyl Acetate 68 "' en (J) ro+ CJ).. CsH1 22 Propyl Propionate 4849 C1H,.2 Pentyl Acetate Propyl Butyrate 466 C1H,.2 Pentyl Acetate 46 C,oH1 2 1,2,,4 Tetrahydronaphthalene C4H82 Ethyl Acetate 27 C,oH1s Limonene C,,H,82 Isobornyl Formate 474 C,oH22 Decane CHs Dimethyl Carbonate 16 C.Hs2 Methyl Acrylate 178

52 :::1.... C, H,a2 Isobornyl Formate C,oH,s Vinyl Acetate 199 Limonene 474 c,2h2s Dodecane CHs2 Methyl Acetate 8 C Ha2 Ethyl Acetate 271 C,2H27 P Tributyl Phosphate CCI4 Tetrachloromethane CHCI Chloroform CsHs Benzene C1H1 s Heptane 49D496 c,h12 Diphenylmethane C Hs2 GammaButyrolactone 17D1 72 c,.h,2o2 Benzyl Benzoate C1Ha To luene 497 )> C9H,2 Benzyl Acetate "" ::::r C1 sh2sos Butanoic Acid1,2, C2,Has Hexanoic Acid 1,2,Propanetriyl Ester 498 Propanetriyl Ester " C21HsoOs Octanoic Acid, 1,2,Propanetriyl Ester C,sH22 Dibutyl Phthalate CH1NO N,NDimethylformamide (DMF) 5 C,aH44 Dibutyl Sebacate 51 c, 7H.o2 Methyl Palmitate C,9Ha2 Methyl Stearate 52.. C,aH Dibutyl Sebacate C, sh22 Dibutyl Phthalate 51 >< C,aHa Octadecane C2sH.2o. Dinonyl Phthalate 512 c,9h2 Bis (lsoprophylphenyl) C2oH o2 Ethyl Stearate 54 ID Methane :::1 C,9Hs2 Methyl Oleate C,9Ha2 Methyl Stearate 5 C,9Ha2 Methyl Stearate c,7h.o2 Methyl Palmitate 52 < C,9Hs2 Methyl Oleate 5 (J) C2oH4o2 Ethyl Stearate c,9h2 Bis (lsoprophylphenyl) Methane 54.+ C2, Has Hexanoic Acid 1,2, C, sh2sos Butanoic Acid1,2,Propanetriyl Ester 498 Propanetriyl Ester (') (/) '> (J)..

53 ... c22h.. o2 NButy_l Octadecanoate CsH,. C2sH.2o. Dinonyl Phthalate CsH1 2 Hexane 5556 )> Pentane 57 Benzene 58 C"' CsH12 Cyclohexane 59 CsHs C1H,s c.h,. C,aHa C21HsoOs Octanoic Acid, 1,2, C,sH2sOs Propanetriyl Ester "'C :r Heptane 51 (') Octane 51 1 Octadecane 512 :::l Butanoic Acid1,2,Propanetriyl Ester 499 X r+ h :::l.. (/) (/J r+ (/J > 1\)

54 .. Acetonitrile C2HsN Methyl Acetate CsHs2 Propyl Bromide CsH7Br Benzene CsHs Butyl Acetate CsH122 Ethyl Acetate C4Hs2 548 Methyl Acetate CsHs2 Tetrachloromethane CCI4 519 Tetrachloromethane CC14 Ethyl Acetate C4Ha To luene C7Hs Ethyl Acetate C4Hs Butyl Acetate C6H122 Ethyl Acetate C4Hs2 Benzene CsHs 548 Chlorobenzene C6H5CI Ethyl Acetate C4Ha2 Tetrachloromethane CC Cyclohexane CsH12 Ethyl Formate CHs2 Propyl Bromide CsH?Br Methyl Pyrazine C5HsN2 Ethyl Acetate C4Hs Dibutyl Phthalate C1sH22o4 Hexane CsH14 Methylcyclopentane CsH )> ""C Dichloromethane CH2CI2 Pentane C5H12 Methyl Acetate CsHs2 52 ::::r Dimethylterephthalate C1oH1 o4 Methyl Benzoate CaHa2 ptolyl Acid Methylester CaH1 o2 '" 557 Ethyl Acetate C4Hs2 Benzene CsHs Butyl Acetate CsH r+ Tetrachloromethane CC (") To luene C7Hs Cyclohexane CsH12 2Methyl Pyrazine C5HsN :::J. Hexane CsH14 2Methyl Pyrazine C5HsN2 547 >< Tetrachloromethane CC14 Chlorobenzene CsH5CI 5658 Ethyl Formate CsHs2 Propyl Bromide CsH7Br Cyclohexane CsH Hexane CsH14 2Methyl Pyrazine C5HsN2 Ethyl Acetate C4Hs2 roof 547 Methylcyclopentane CsH12 Dibutyl Phthalate C1sH22o4 558 :::J m Methyl Acetate C2Hs2 Vinyl Acetate C4Hs2 Propyl Bromide CsH?Br 52 CsHs2 Dichloromethane CH2CI2 Pentane C5H (/) Propyl Acetate C5H1 o2 Methyl Formate C2H Propyl Bromide CsH7Br Acetonitrile C2HsN en r+ Methyl Methacrylate C5Hs >.. en (,.)

55 .. To luene C7Ha )> "' Propyl Formate Methyl Formate C2H 2 51 ::::r Propyl Acetate CsH1o2 51 DJ " Tetrachloromethane cc1. Benzene CaHs 519 "* C.H82 Vinyl Acetate C.Ha2 Propyl Bromide C,H7Br 524 (") DJ To luene C7Ha 5295 Methyl Benzoate CaHa2 pto lyl Acid Methylester C.H,o2 Dimethylterephthalate C1oH,o4 557 :J Methyl Formate C2H42 Methyl Acetate CsHs2 Propyl Acetate CsH1o X Propyl Formate C Ha2 51 Propyl Formate C Hs2 Propyl Acetate C5H,o _., Methyl Methacrylate CsHa2 Methyl Acetate CsHs2 Propyl Bromide C,H7Br roi...,. Vinyl Acetate C4H62 Propyl Bromide CH7Br 525 :J DJ 2Methyl Pyrazine C5HaN2 Ethyl Acetate C4H82 Cyclohexane CsH Hexane CaH,. 547 (/) Methylcyclopentane CsH12 Dibutyl Phthalate C, sh22 Hexane C6H,4 558 (JJ "* Nonane CgH2o axylene CaH,o Pentyl Acetate C7H, Pentane CsH12 Methyl Acetate C,Hs2 Dichloromethane CH2CI2 52 (JJ Pentyl Acetate C7H,.2 Nonane C H2o axylene CsH1o < > Propyl Acetate CsH1o2 Methyl Acetate CsHs2 Propyl Formate C.H82 51 Methyl Formate C2H 2 Methyl Acetate C,Hs2 514 Propyl Formate Propyl Bromide C,H7Br Acetonitrile C2HsN Methyl Acetate Cyclohexane CsH12 Ethyl Formate Methyl Acetate C2Hs2 Vinyl Acetate C Ha2 C,H62 C,Hs2 C Hs C,Hs2 Vinyl Acetate C Hs2 524 Methyl Methacrylate C5Hs2 Methyl Acetate CHs