This document displays summary values for each pesticide or other organic residue found in FDA s Total Diet Study, Market Baskets (36

Transcription

1 and Drug Administration Total Diet Study Summary of Residues Found Ordered by Market Baskets June 2003 This document displays summary values for each pesticide or other organic residue found in FDA s Total Diet Study, Market Baskets (36 baskets). Note that only positive values were used; i.e., levels of 0.0 were not included in the calculations, except in cases where the laboratory indicated the presence of a trace level but did not enter a value.

2 Total Diet Study Summary by 001 whole milk, fluid benzene chloroform DDE, p,p' dieldrin endosulfan sulfate heptachlor epoxide methoxychlor, p,p' permethrin, cis permethrin, trans styrene tetrachloroethylene toluene lowfat (2% fat) milk, fluid DDE, p,p' dieldrin endosulfan sulfate methoxychlor, p,p' chocolate milk, fluid DDE, p,p' skim milk, fluid DDE, p,p' plain yogurt, lowfat DDE, p,p' endosulfan II chocolate milk shake, fast-food chlorpyrifos DDE, p,p' dieldrin evaporated milk, canned BHC, alpha chlordane, cis DDE, p,p' dieldrin endrin heptachlor epoxide lindane toluene American, processed cheese 1,1,1-trichloroethane ,2,4-trimethylbenzene benzene bromodichloromethane June 2003 Page 1

3 Total Diet Study Summary by chlorobenzene chloroform DDE, p,p' dichlorobenzene, p dieldrin diphenyl 2-ethylhexyl phosphate endosulfan sulfate ethyl benzene heptachlor epoxide hexachlorobenzene lindane styrene tetrachloroethylene toluene trichloroethylene xylene, m- and/or p xylene, o cottage cheese, 4% milkfat DDE, p,p' dieldrin cheddar cheese 1,1,1-trichloroethane ,2,4-trimethylbenzene ,2-dichloroethene, trans azinphos-methyl benzene chlordane, trans chlorobenzene chloroform DDE, p,p' dichlorobenzene, p dieldrin diphenyl 2-ethylhexyl phosphate endosulfan sulfate ethyl benzene heptachlor epoxide hexachlorobenzene methoxychlor, p,p' octachlor epoxide permethrin, cis permethrin, trans styrene tetrachloroethylene toluene trichloroethylene xylene, m- and/or p June 2003 Page 2

4 Total Diet Study Summary by 013 ground beef, pan-cooked 1,1,1-trichloroethane ,2,4-trimethylbenzene benzene BHC, alpha chloroform chlorotoluene, o chlorpyrifos DDE, p,p' DDT, p,p' dichlorobenzene, p dieldrin diphenyl 2-ethylhexyl phosphate ethyl benzene heptachlor epoxide hexachlorobenzene lindane octachlor epoxide styrene tetrachloroethylene toluene trichloroethylene xylene, m- and/or p xylene, o beef chuck roast, baked 1,1,1-trichloroethane benzene chloroform chlorpropham DDE, p,p' dichlorobenzene, p dieldrin ethyl benzene heptachlor epoxide hexachlorobenzene polychlorinated biphenyls styrene toluene trichloroethylene xylene, m- and/or p xylene, o beef steak, loin, pan-cooked chloroform DDE, p,p' DDT, p,p' diazinon dieldrin June 2003 Page 3

5 Total Diet Study Summary by heptachlor epoxide octachlor epoxide polychlorinated biphenyls toluene ham, baked DDE, p,p' DDT, p,p' pentachlorophenol permethrin, cis permethrin, trans toluene pork chop, pan-cooked chlordane, cis chlordane, trans chlorpyrifos DDE, p,p' DDT, o,p' DDT, p,p' diazinon dieldrin heptachlor epoxide hexachlorobenzene lindane nonachlor, trans polychlorinated biphenyls TDE, p,p' toluene pork sausage, pan-cooked 2-chloroethyl linoleate chloroethyl myristate chloroethyl palmitate chloroethyl stearate BHC, alpha DDE, p,p' DDT, p,p' dieldrin ethion heptachlor epoxide hexachlorobenzene lindane octachlor epoxide phosalone styrene TDE, p,p' toluene xylene, m- and/or p June 2003 Page 4

6 Total Diet Study Summary by 020 pork bacon, pan-cooked 1,1,1-trichloroethane ,2,4-trimethylbenzene benzene chloroform DDE, p,p' DDT, p,p' dichlorobenzene, p dieldrin ethyl benzene hexachlorobenzene nonachlor, trans styrene TDE, p,p' tetrachloroethylene toluene trichloroethylene xylene, m- and/or p xylene, o pork roast, baked benzene butylbenzene, n chloroform DDE, p,p' dicloran heptachlor epoxide lindane permethrin, cis permethrin, trans polychlorinated biphenyls toluene lamb chop, pan-cooked chloroform chlorpyrifos DDE, p,p' DDT, p,p' diazinon dieldrin endosulfan sulfate heptachlor epoxide hexachlorobenzene octachlor epoxide polychlorinated biphenyls propetamphos styrene TDE, p,p' toluene June 2003 Page 5

7 Total Diet Study Summary by 024 chicken, fried (breast, leg, and thigh) homemade chloroform DDE, p,p' dieldrin lindane polychlorinated biphenyls toluene xylene, m- and/or p turkey breast, roasted benzene chloroform DDE, p,p' dicloran dieldrin diphenyl 2-ethylhexyl phosphate styrene toluene liver, beef, fried 1,2,4-trimethylbenzene chloroform DDE, p,p' dieldrin endosulfan sulfate ethyl benzene heptachlor epoxide toluene xylene, m- and/or p xylene, o frankfurters, beef, boiled 1,1,1-trichloroethane ,2,4-trimethylbenzene ,2-dichloroethene, trans chloroethyl linoleate chloroethyl myristate chloroethyl palmitate benzene bromodichloromethane butylbenzene, n carbon tetrachloride chlorobenzene chloroform DDE, p,p' DDT, p,p' dichlorobenzene, o dieldrin ethyl benzene heptachlor epoxide June 2003 Page 6

8 Total Diet Study Summary by hexachlorobenzene lindane propylbenzene, n styrene tetrachloroethylene toluene trichloroethylene xylene, m- and/or p xylene, o bologna, sliced 030 salami, sliced 1,1,1-trichloroethane ,2,4-trimethylbenzene chloroethyl linoleate chloroethyl myristate chloroethyl palmitate benzene bromodichloromethane butylbenzene, n carbon tetrachloride chlorobenzene chloroform DDE, p,p' DDT, p,p' dieldrin ethyl benzene heptachlor epoxide lindane styrene tetrachloroethylene toluene trichloroethylene xylene, m- and/or p xylene, o ,1,1-trichloroethane chloroethyl linoleate chloroethyl myristate chloroethyl palmitate benzene BHC, alpha bromodichloromethane carbon tetrachloride chlorobenzene chloroform DDE, p,p' DDT, p,p' dieldrin ethyl benzene June 2003 Page 7

9 Total Diet Study Summary by propylbenzene, n styrene tetrachloroethylene toluene trichloroethylene xylene, m- and/or p xylene, o tuna, canned in oil 1,1,1-trichloroethane ,2,4-trimethylbenzene benzene BHC, alpha carbon tetrachloride chloroform DDE, p,p' dichlorobenzene, p dieldrin ethyl benzene hexachlorobenzene polychlorinated biphenyls propylbenzene, n styrene tetrachloroethylene toluene trichloroethylene xylene, m- and/or p xylene, o fish sticks, frozen, heated 1,1,1-trichloroethane ,2,4-trimethylbenzene benzene butylbenzene, n carbon tetrachloride chloroform chlorpyrifos chlorpyrifos-methyl cumene (isopropyl benzene) DDE, p,p' DDT, p,p' dichlorobenzene, p ethyl benzene malathion methoxychlor, p,p' pirimiphos-methyl propylbenzene, n styrene tetrachloroethylene toluene June 2003 Page 8

10 Total Diet Study Summary by trichloroethylene xylene, m- and/or p xylene, o eggs, scrambled 036 eggs, fried 037 eggs, boiled 1,1,1-trichloroethane ,2,4-trimethylbenzene benzene butylbenzene, n chloroform chlorpropham cumene (isopropyl benzene) DDE, p,p' dichlorobenzene, p dieldrin ethyl benzene propylbenzene, n styrene tetrachloroethylene toluene xylene, m- and/or p bromodichloromethane chloroform DDE, p,p' dieldrin permethrin, cis permethrin, trans polychlorinated biphenyls chloroform DDE, p,p' dieldrin toluene pinto beans, dry, boiled iprodione metabolite isomer pork and beans, canned 2-chloroethyl linoleate chloroethyl myristate chloroethyl palmitate bromodichloromethane chloroform chlorpyrifos toluene xylene, m- and/or p June 2003 Page 9

11 Total Diet Study Summary by 042 lima beans, immature, frozen, boiled acephate chloroform DCPA DDE, p,p' dicofol, p,p' dieldrin dimethoate endosulfan sulfate iprodione iprodione metabolite isomer lindane methamidophos omethoate green peas, fresh/frozen, boiled chloroform DDE, p,p' diazinon dieldrin dimethoate methoxychlor, p,p' omethoate parathion pentachloroaniline peanut butter, smooth 1,1,1-trichloroethane ,2,4-trimethylbenzene benzene BHC, beta bromodichloromethane butylbenzene, n carbon tetrachloride chloroform chlorpyrifos cumene (isopropyl benzene) DDE, p,p' dichlorobenzene, p dicloran dieldrin endosulfan II endosulfan sulfate ethyl benzene fenitrothion hexachlorobenzene malathion methoxychlor, p,p' pentachloroaniline pentachlorobenzene June 2003 Page 10

12 Total Diet Study Summary by pentachlorophenyl methyl ether pentachlorophenyl methyl sulfide pirimiphos-methyl propylbenzene, n quintozene styrene tetrachloroethylene toluene toxaphene trichloroethylene xylene, m- and/or p xylene, o peanuts, dry roasted 1,1,1-trichloroethane chloroethyl linoleate chloroethyl palmitate chloroethyl stearate BHC, beta carbon tetrachloride chloroform chlorpropham chlorpyrifos DDE, p,p' dieldrin endosulfan II endosulfan sulfate fonofos hexachlorobenzene lindane malathion pentachloroaniline pentachlorobenzene pentachlorophenyl methyl ether pentachlorophenyl methyl sulfide permethrin, cis permethrin, trans pirimiphos-methyl quintozene styrene toluene toxaphene xylene, m- and/or p white rice, cooked 2,4,5-T diphenyl 2-ethylhexyl phosphate iprodione iprodione metabolite isomer June 2003 Page 11

13 Total Diet Study Summary by malathion methoxychlor, p,p' quinclorac tributyl phosphate oatmeal, quick (1-3 min), cooked 1,2,4-trimethylbenzene chlorpyrifos chlorpyrifos-methyl endosulfan II endosulfan sulfate malathion tributyl phosphate tris(2-butoxyethyl)phosphate tris(beta-chloroethyl) phosphate xylene, m- and/or p wheat cereal, farina, quick (1-3min), cooked chloroform chlorpyrifos-methyl dicloran malathion tributyl phosphate corngrits, regular, cooked benzene dicloran malathion pirimiphos-methyl polychlorinated biphenyls corn, fresh/frozen, boiled chloroform diazinon cream style corn, canned acephate benzene chloroform dimethoate tetrachloroethylene toluene popcorn, popped in oil 1,1,1,2-tetrachloroethane ,1,1-trichloroethane ,2,4-trimethylbenzene benzene bromodichloromethane butylbenzene, n June 2003 Page 12

14 Total Diet Study Summary by butylbenzene, sec chlordane chlordane, cis chlordane, trans chloroform chlorpyrifos DDE, p,p' diazinon dichlorobenzene, p dieldrin endosulfan sulfate ethyl benzene lindane malathion methoxychlor, p,p' permethrin, cis permethrin, trans pirimiphos-methyl polychlorinated biphenyls propylbenzene, n styrene tetrachloroethylene toluene toxaphene trichloroethylene xylene, m- and/or p xylene, o white bread 1,1,1-trichloroethane ,2,4-trimethylbenzene ,4-D benzene BHC, alpha chloroform chlorpropham chlorpyrifos chlorpyrifos-methyl cumene (isopropyl benzene) diazinon dicamba dichlorobenzene, p diphenyl 2-ethylhexyl phosphate ethyl benzene ethylenethiourea iprodione malathion pirimiphos-methyl propylbenzene, n June 2003 Page 13

15 Total Diet Study Summary by styrene toluene trichloroethylene xylene, m- and/or p xylene, o white roll 1,1,2-trichloroethane ,2,4-trimethylbenzene BHC, alpha chlorpropham chlorpyrifos chlorpyrifos-methyl DDT, p,p' diazinon diphenyl 2-ethylhexyl phosphate fenitrothion malathion methoxychlor, p,p' parathion pirimiphos-methyl toluene triphenyl phosphate tris(beta-chloroethyl) phosphate cornbread, homemade 1,1,1,2-tetrachloroethane ,1,1-trichloroethane benzene bromodichloromethane chlorpyrifos chlorpyrifos-methyl DDE, p,p' DDT, p,p' diazinon dieldrin heptachlor malathion pirimiphos-methyl polychlorinated biphenyls toluene xylene, m- and/or p biscuit, from refrigerated dough, baked 1,1,1,2-tetrachloroethane chloroform chlorpyrifos chlorpyrifos-methyl diazinon malathion June 2003 Page 14

16 Total Diet Study Summary by methoxychlor, p,p' pirimiphos-methyl polychlorinated biphenyls toluene whole wheat bread 1,1,1-trichloroethane ,2,4-trimethylbenzene chlorpyrifos chlorpyrifos-methyl diazinon diphenyl 2-ethylhexyl phosphate lindane malathion parathion pirimiphos-methyl toluene xylene, m- and/or p tortilla, flour 064 rye bread chlorpyrifos chlorpyrifos-methyl diphenyl 2-ethylhexyl phosphate malathion methoxychlor, p,p' pirimiphos-methyl toluene xylene, m- and/or p chloroethyl linoleate chloroethyl palmitate benzene BHC, alpha bromophos-ethyl chlorpyrifos chlorpyrifos-methyl DDT, p,p' diazinon diphenyl 2-ethylhexyl phosphate hexachlorobenzene lindane malathion methoxychlor, p,p' parathion permethrin, cis permethrin, trans pirimiphos-methyl toluene xylene, m- and/or p June 2003 Page 15

17 Total Diet Study Summary by 065 blueberry muffin, commercial 1,1,1-trichloroethane ,2,4-trimethylbenzene azinphos-methyl benzene chloroform chlorothalonil chlorpyrifos chlorpyrifos-methyl cumene (isopropyl benzene) DDE, p,p' diazinon dichlorobenzene, o dichlorobenzene, p ethyl benzene malathion methoxychlor, p,p' phosmet pirimiphos-methyl propylbenzene, n styrene tetrachloroethylene toluene trichloroethylene xylene, m- and/or p xylene, o saltine crackers 067 corn chips 1,2,4-trimethylbenzene chlorpyrifos chlorpyrifos-methyl diazinon malathion methoxychlor, p,p' pirimiphos-methyl toluene xylene, m- and/or p ,1,1-trichloroethane ,2,4-trimethylbenzene benzene butylbenzene, n carbon tetrachloride chlorobenzene chloroform chlorpropham chlorpyrifos dichlorobenzene, p ethyl benzene June 2003 Page 16

18 Total Diet Study Summary by malathion methoxychlor olefin methoxychlor, o,p' methoxychlor, p,p' pirimiphos-methyl styrene tetrachloroethylene toluene trichloroethylene xylene, m- and/or p xylene, o pancake from mix benzene chlorpropham chlorpyrifos chlorpyrifos-methyl DDE, p,p' diazinon malathion methoxychlor, p,p' polychlorinated biphenyls toluene xylene, m- and/or p egg noodles, boiled chlorpyrifos chlorpyrifos-methyl diazinon diphenyl 2-ethylhexyl phosphate endosulfan sulfate malathion toluene xylene, m- and/or p macaroni, boiled 071 corn flakes chlorpyrifos chlorpyrifos-methyl lindane malathion methoxychlor, p,p' pirimiphos-methyl benzene methoxychlor, p,p' pirimiphos-methyl tributyl phosphate xylene, m- and/or p June 2003 Page 17

19 Total Diet Study Summary by 072 fruit-flavored, sweetened cereal 1,2,4-trimethylbenzene benzene chloroform chlorotoluene, o chlorpyrifos chlorpyrifos-methyl cumene (isopropyl benzene) diazinon dicamba dicofol, p,p' ethion ethion oxygen analog ethyl benzene ethylene dichloride malathion mecarbam methidathion propylbenzene, n styrene tetradifon toluene tributyl phosphate trichloroethylene xylene, m- and/or p shredded wheat cereal 1,2,4-trimethylbenzene ,4-D chlorpyrifos chlorpyrifos-methyl clopyralid diazinon malathion methoxychlor, p,p' toluene tributyl phosphate xylene, m- and/or p raisin bran cereal 1,2,4-trimethylbenzene ,4-D captan chlorpyrifos chlorpyrifos-methyl clopyralid DDE, p,p' dicamba dicloran dicofol, o,p' June 2003 Page 18

20 Total Diet Study Summary by dicofol, p,p' dimethoate endosulfan I endosulfan II endosulfan sulfate iprodione iprodione metabolite isomer malathion pirimiphos-methyl propargite crisped rice cereal malathion quinclorac toluene granola cereal 077 oat ring cereal 078 apple, red, raw 1,1,1-trichloroethane chlorpyrifos chlorpyrifos-methyl DDE, p,p' diazinon dicofol, o,p' dicofol, p,p' iprodione malathion methoxychlor, p,p' procymidone styrene tecnazene toluene xylene, m- and/or p ,2,4-trimethylbenzene ,4-D chlorpyrifos chlorpyrifos-methyl clopyralid dicamba malathion toluene azinphos-methyl benomyl benzene captan carbaryl chloroform June 2003 Page 19

21 Total Diet Study Summary by chlorpyrifos DDE, p,p' diazinon dichlorobenzene, p dicloran dicofol, o,p' dicofol, p,p' dimethoate endosulfan I endosulfan II endosulfan sulfate ethion ethion oxygen analog ethyl benzene fenarimol iprodione iprodione metabolite isomer methomyl methoxychlor olefin methoxychlor, o,p' methoxychlor, p,p' omethoate parathion parathion-methyl phosalone phosmet phosphamidon propargite thiabendazole toluene trichloroethylene tris(chloropropyl) phosphate xylene, m- and/or p orange, raw benzene bromodichloromethane captan carbaryl chloroform chlorpyrifos dicloran dicofol, p,p' dimethoate endosulfan I endosulfan sulfate ethion iprodione methidathion omethoate June 2003 Page 20

22 Total Diet Study Summary by styrene thiabendazole toluene trichloroethylene xylene, m- and/or p banana, raw 081 watermelon, raw 083 peach, raw benzene chloroform ethyl benzene pentachlorophenyl methyl ether styrene thiabendazole toluene trichloroethylene xylene, m- and/or p acephate carbaryl dicloran dieldrin dimethoate endosulfan II endosulfan sulfate heptachlor epoxide hexachlorobenzene methamidophos methomyl omethoate pentachloroaniline ,4-dichloro-6-nitrobenzenamine azinphos-methyl benomyl benzene captan carbaryl chlorpyrifos DDE, p,p' diazinon dicloran dicofol, o,p' dicofol, p,p' dieldrin dimethoate endosulfan I endosulfan II endosulfan sulfate June 2003 Page 21

23 Total Diet Study Summary by fenvalerate iprodione iprodione metabolite isomer methamidophos parathion parathion-methyl permethrin, cis permethrin, trans phosalone phosmet propargite toluene xylene, m- and/or p applesauce, bottled acephate azinphos-methyl benomyl captan carbaryl chloroform chlorpyrifos dimethoate endosulfan I endosulfan II endosulfan sulfate ethylenethiourea methamidophos omethoate parathion parathion-methyl phosmet phosphamidon propargite thiabendazole tributyl phosphate xylene, m- and/or p pear, raw azinphos-methyl benomyl benzene captan carbaryl chloroform chlorpropham chlorpyrifos diazinon dicloran dicofol, o,p' June 2003 Page 22

24 Total Diet Study Summary by dicofol, p,p' endosulfan I endosulfan II endosulfan sulfate iprodione iprodione metabolite isomer omethoate parathion-methyl pentachlorophenyl methyl ether permethrin, cis permethrin, trans phosmet thiabendazole toluene tris(chloropropyl) phosphate xylene, m- and/or p strawberries, raw anilazine azinphos-methyl benomyl benzene BHC, beta bifenthrin bromodichloromethane captan carbaryl carbofuran chlordane, cis chlordane, trans DDE, p,p' diazinon dicofol, p,p' dieldrin dimethoate diphenyl 2-ethylhexyl phosphate endosulfan I endosulfan II endosulfan sulfate fenhexamid folpet iprodione iprodione metabolite isomer malathion methamidophos methiocarb methomyl mevinphos, (e) mevinphos, (z) omethoate June 2003 Page 23

25 Total Diet Study Summary by parathion-methyl propargite styrene tetrachloroethylene toluene toxaphene vinclozolin xylene, m- and/or p fruit cocktail, canned in heavy syrup carbaryl chlorpyrifos dicofol, o,p' dicofol, p,p' endosulfan II endosulfan sulfate iprodione iprodione metabolite isomer permethrin, cis permethrin, trans propargite toluene xylene, m- and/or p grapes, red/green, seedless, raw azinphos-methyl benomyl benzene bifenthrin captan carbaryl chlorpyrifos cyprodinil DDE, p,p' diazinon dicloran dicofol, o,p' dicofol, p,p' dieldrin dimethoate endosulfan I endosulfan II endosulfan sulfate fenarimol fenhexamid fenvalerate folpet iprodione iprodione metabolite isomer June 2003 Page 24

26 Total Diet Study Summary by methomyl omethoate phosmet propargite vinclozolin cantaloupe, raw 091 plums, raw acephate benomyl benzene carbaryl chlorpyrifos DCPA DDE, p,p' dicofol, p,p' dieldrin dimethoate endosulfan I endosulfan II endosulfan sulfate endrin heptachlor epoxide methamidophos methomyl omethoate pentachloroaniline permethrin, cis thiabendazole toxaphene ,4-dichloro-6-nitrobenzenamine azinphos-methyl benomyl benzene captan carbaryl chlorpropham chlorpyrifos diazinon dicloran dicofol, o,p' dicofol, p,p' endosulfan I endosulfan sulfate iprodione iprodione metabolite isomer omethoate June 2003 Page 25

27 Total Diet Study Summary by parathion-methyl pentachlorophenyl methyl ether phosmet propargite thiabendazole grapefruit, raw carbaryl diazinon dicofol, o,p' dicofol, p,p' ethion methidathion thiabendazole pineapple, canned in juice bromodichloromethane diphenyl 2-ethylhexyl phosphate endosulfan I iprodione methoxychlor, p,p' toluene sweet cherries, raw acephate azinphos-methyl benomyl benzene captan carbaryl chloroform chlorpyrifos DDE, p,p' diazinon dimethoate diphenyl 2-ethylhexyl phosphate endosulfan I endosulfan II endosulfan sulfate esfenvalerate fenarimol fenvalerate iprodione iprodione metabolite isomer malathion methoxychlor, o,p' methoxychlor, p,p' omethoate parathion-methyl June 2003 Page 26

28 Total Diet Study Summary by permethrin, cis permethrin, trans phosmet toluene vinclozolin raisins, dried 096 prunes, dried 1,2,4-trimethylbenzene benzene carbaryl chloroform chlorpyrifos DDE, p,p' DDT, p,p' diazinon dicofol, o,p' dicofol, p,p' dimethoate endosulfan I endosulfan II endosulfan sulfate fenarimol iprodione iprodione metabolite isomer malathion parathion-methyl phosmet polychlorinated biphenyls propargite styrene tetrachloroethylene toluene trichloroethylene xylene, m- and/or p azinphos-methyl carbaryl chlorpyrifos DDE, p,p' dicloran dicofol, o,p' dicofol, p,p' endosulfan I endosulfan II endosulfan sulfate June 2003 Page 27

29 Total Diet Study Summary by iprodione iprodione metabolite isomer malathion permethrin, cis permethrin, trans propargite toluene tris(chloropropyl) phosphate avocado, raw 1,1,1-trichloroethane benzene chlorobenzene chloroform dichlorobenzene, p malathion styrene tetrachloroethylene toluene trichloroethylene xylene, m- and/or p orange juice, from frozen concentrate benzene carbaryl chloroform chlorpyrifos DDE, p,p' dicofol, p,p' ethion ethion oxygen analog ethyl benzene methidathion styrene toluene tributyl phosphate xylene, m- and/or p xylene, o apple juice, bottled acephate benzene bromodichloromethane carbaryl chloroform dimethoate ethylenethiourea methamidophos omethoate phosmet June 2003 Page 28